Lithographic printing plate precursor and lithographic printing method
A technology of lithographic printing plate and original plate, applied in the field of plate making of lithographic printing plate original plate, to achieve the effect of high on-machine developability
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Embodiment 1 to 6 and comparative example 1 to 3
[0263] [Preparation of lithographic printing plate precursors (1) to (9)]
[0264] (Preparation of Support (No. 1))
[0265] An aluminum plate having a thickness of 0.3 mm according to JIS A1050 was processed by sequentially performing the steps (a) to (k) given below.
[0266] (a) Mechanical surface roughening
[0267] Mechanical surface roughening of the aluminum plates was performed by means of rotating roller nylon brushes while a suspension of abrasive (silica sand) in water (with a specific gravity of 1.12) was supplied as an abrasive slurry to the surface of the aluminum plates. The abrasive has an average particle size of 8 μm and a maximum particle size of 50 μm. The material of the nylon brush is 6.10 nylon, and the brush has a hair length of 50 mm and a hair diameter of 0.3 mm. Nylon brushes were fabricated by making holes in a stainless steel cylinder with a diameter of 300 mm and densely inserting bristles. Use three rotating nylon brushes. Two support rolls ...
Embodiment 7 to 15
[0318] [Preparation of lithographic printing plate precursors (10) to (18)]
[0319] (formation of undercoat layer)
[0320] A methanol solution of the polymer compound (1) (weight average molecular weight (Mw): 35,000) shown above was coated on the aluminum support described above by a wire bar and dried at 80° C. for 60 seconds to form an undercoat layer . The coating weight is 0.02g / m 2 .
[0321] (Formation of image recording layer)
[0322] The coating solution (2) for the image forming layer was coated on the support with the undercoat layer using a bar and dried in an oven at 100° C. for 60 seconds to form a film having a thickness of 1.0 g / m 2 The dry coating amount of the image-recording layer. The coating liquid (2) for the image-recording layer was prepared by mixing the photosensitive liquid (1) given below with the microcapsule solution (2) given below just before coating, followed by stirring.
[0323]
[0324]
[0325] Radical polymerization initiator...
Embodiment 16 to 56 and comparative example 4 to 7
[0352] [Preparation of lithographic printing plate precursors (19) to (63)]
[0353] (Preparation of Support (No. 2))
[0354] An aluminum plate (material: JIS A 1050) having a thickness of 0.3 mm was subjected to a degreasing treatment at 50° C. for 30 seconds using a 10% by weight aqueous solution of sodium aluminate to remove rolling oil on its surface, and then three plants with a diameter of 0.3 mm were used. A nylon brush with nylon bristle bundles and an aqueous suspension of pumice with a median particle size of 25 μm (specific gravity: 1.1 g / cm 3 ) to grain its surface, followed by thorough washing with water. The plate was etched by immersing it in a 25% by weight aqueous sodium hydroxide solution at 45°C for 9 seconds, washed with water, then immersed in a 20% by weight aqueous nitric acid solution at 60°C for 20 seconds, and washed with water. The erosion amount of the grained surface is about 3g / m 2 .
[0355] Next, electrochemical roughening treatment was con...
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