Polishing solution for silicon carbide substrate

A silicon carbide substrate and polishing liquid technology, which is applied to polishing compositions containing abrasives, electrical components, circuits, etc., can solve the problems that cannot meet the requirements, do not provide SiC substrate surface polishing liquid and preparation methods, etc., and achieve Low cost, low processing stress, and less damage

Inactive Publication Date: 2012-07-04
上海上硅中试基地科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, none of the chemical mechanical polishing fluids produced in China are designed for SiC single crystals. The chemical inertness of SiC determines that the general chemical mechanical polishing fluids cannot meet the requirements.
[0004] The published patent literature and non-patent literature do not provide the polishing liquid and preparation method for successfully obtaining the SiC substrate surface

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment 1: Prepare 5 kg of chemical mechanical polishing fluid for silicon carbide substrates:

[0065] Water glass is used as raw material, polysilicate solution is obtained through ion exchange reaction, polysilicate solution is gradually crystallized after adding stabilizer, and mother liquor is formed, and polysilicate solution is added to mother liquor at a certain speed, SiO 2 The crystal grains gradually grow up regularly, and a silica sol with a particle size of 70nm and uniform distribution is obtained. After concentration and purification steps to reach a concentration of 50% (wt) silica sol finished product, the specific preparation method is as follows:

[0066] Take the modulus as 3(Na 2 O 3SiO 2 ) of water glass solution 5500g (concentration 41%) is diluted with deionized water to content to contain SiO 2 25%, Na 2 O 1%, the solution is passed through the height 1.1 meters that Shanghai Mingxing Kaicheng Co., Ltd. provides, and the diameter is the c...

Embodiment 2

[0070] Embodiment 2: Prepare 5kg of chemical mechanical polishing fluid for silicon carbide substrate:

[0071] 1500 g of silica sol was prepared by catalytic hydrolysis of silica powder, the particle size was 20 nm, and the concentration of silica sol was 50%. Under strong agitation, gradually add 100g ethylenediaminetetraacetic acid as a chelating agent; add cetyltrimethylammonium bromide 100g as a surfactant; slowly add polyethylene glycol (PEG600, with an average molecular weight of 570-630, Sinopharm Group Chemical Reagent Co., Ltd.) 100g as a dispersant, then add 100g of sodium hypochlorite solution, add deionized water to 5kg, and stir to prepare 5kg of the SiC substrate chemical mechanical polishing solution of the present invention.

[0072] Test detection: the pH value of the polishing solution is 10.3, and the particle size is 15-55 nm.

[0073] Test: Polishing test of SiC wafer with prepared polishing solution, chemical mechanical polishing test of 8 pieces of 2-i...

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Abstract

The invention relates to a chemically mechanical polishing solution for a silicon carbide substrate. The chemically mechanism polishing solution comprises the following components in percentage by weight: 1-50 percent of grinding material, 0.01-8 percent of chelant, 0.01-10 percent of surfactant, 0.01-10 percent of dispersing agent, 0.1-20 percent of oxidant and the balance of deionized water. The polishing solution has little damage to the surface of the silicon carbide substrate; the silicon carbide substrate has low roughness degree value and can reach the roughness Ra of being less than 0.5nm; no scratch and corrosion pit defect exists on the surface of the silicon carbide substrate; and the chemically mechanical polishing solution has high removing speed of scratch and corrosion pit, is easy to clean, does not corrode processing equipment and pollute the environment, and is low is price of raw materials, low in cost and easy to store. The chemically mechanical polishing solution is mainly used for chemically mechanical polishing of a silicon carbide wafer for the substrate.

Description

technical field [0001] The invention belongs to a special chemical mechanical polishing liquid, in particular to the surface treatment of silicon carbide materials for epitaxial substrates. Background technique [0002] The application of wide bandgap semiconductor SiC crystal material requires ultra-smooth wafer surface, no defect, no damage, and the quality and precision of SiC crystal processing directly affect the performance of the device. However, due to the extremely high hardness of SiC crystals, with a Mohs hardness of 9.2, second only to diamond, it is extremely difficult to process the surface, and it is difficult to obtain a high-quality surface with low roughness, which greatly limits its wide application. To prepare high-quality epitaxial wafers, the requirements for the substrate are not only low warpage, low curvature, and small total thickness deviation, but also special requirements for the surface of the substrate: low obvious surface defects, low subsurfa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/02H01L21/306
Inventor 储耀卿施尔畏
Owner 上海上硅中试基地科技有限公司
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