Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Polyaniline derivative, preparation method of reduced polySchiff base thereof and application of polyaniline derivative

A polySchiff base and polyaniline technology, which is used in the preparation of polyaniline derivatives and its reduced polySchiff base and its application fields, can solve the problems of low solubility, single structure and function of polyaniline, and difficult to process into Film and other problems, to achieve the effect of increasing solubility, fast response time, and improved solubility

Inactive Publication Date: 2012-07-18
HEILONGJIANG UNIV
View PDF2 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention aims to solve the technical problems that the existing polyaniline has a single structure and function, low solubility in organic solvents, and is difficult to process into a film, and provides a preparation method of polyaniline derivatives and its reduced polySchiff base and its Applications

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polyaniline derivative, preparation method of reduced polySchiff base thereof and application of polyaniline derivative
  • Polyaniline derivative, preparation method of reduced polySchiff base thereof and application of polyaniline derivative
  • Polyaniline derivative, preparation method of reduced polySchiff base thereof and application of polyaniline derivative

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0045] Specific embodiment one: the structural formula of the polyaniline derivative of the present embodiment is as follows:

[0046] In the formula, n is a positive integer, and Ar is

[0047] The polyaniline derivatives of this embodiment use propeller-type triarylamine as a monomer, which can effectively reduce the strong force between polymer molecular chains and increase the solubility of the polymer. At the same time, triarylamine is easy to form cationic radicals and presents a Different from the triarylamine in the neutral state, and because the structure contains two monomer units, the polyaniline derivatives have color tunability due to the joint action; on the other hand, the synthesis of the usual light-emitting or color-changing polymers requires expensive raw materials , harsh synthesis conditions, and the present invention further increases its solubility by reducing the poly-Schiff base, and at the same time has the characteristics of the original poly-S...

specific Embodiment approach 2

[0048] Embodiment 2: This embodiment is different from Embodiment 1 in that n is a positive integer ranging from 3 to 10. Others are the same as in the first embodiment.

specific Embodiment approach 3

[0049] Specific embodiment three: the preparation method of the reduced polySchiff base of the polyaniline derivative of the present embodiment is carried out according to the following steps:

[0050] One, according to the mass volume ratio of conjugated polySchiff base and solvent is 1g: 5 ~ 30mL, the mole of C=N bond and sodium borohydride in the conjugated polySchiff base is 1: 3 ~ 10 and weighs a total of Conjugated polySchiff base, solvent and sodium borohydride;

[0051] 2. First add the conjugated polySchiff base and solvent weighed in step 1 into the three-necked flask with reflux device, then add the sodium borohydride weighed in step 1 into the three-necked flask, heat up to 10-70°C and stir Reflux for 10-72 hours, pour into methanol after cooling, filter, and vacuum-dry the obtained solid phase to obtain polyaniline derivatives.

[0052] The polyaniline derivatives prepared in this embodiment use propeller-type triarylamine as a monomer, which can effectively redu...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a polyaniline derivative, a preparation method of reduced polySchiff base thereof and an application of the polyaniline derivative, which relate to a polyaniline material and a preparation method and an application thereof and are used for solving the technical problem of low dissolubility in an organic solvent and difficulty in processing into a film existing in the conventional polyaniline. The structural formula of the polyaniline derivative disclosed by the invention is shown in the specifications. The preparation method comprises the following steps of: adding conjugate polySchiff base, a solvent and sodium borohydride into a three-neck flask; raising the temperature to 10-70 DEG C, stirring and refluxing for 10-72 hours; cooling and pouring into methanol; and filtering and drying to obtain the polyaniline derivative. The polyaniline derivative is applied as a photoelectric material, and comprises an electrochromic material, a fluorescent sensing material, an acid-based sensing material, a hole transport material, a three-order nonlinear material, an anti-counterfeiting material, a camouflage material, an automobile rearview mirror material or a display material.

Description

technical field [0001] The invention relates to a polyaniline material and its preparation method and application. Background technique [0002] Entering the information age, organic electronics, as an emerging subject, has achieved rapid development. The combination of organic electronics, organic chemistry, and materials science has produced a number of new materials with excellent optoelectronic properties, covering many fields including display materials, military camouflage materials, information storage materials, sensing materials, and smart materials. Polyaniline and its derivatives with electrochromic properties have shown outstanding advantages and broad development and application prospects in the fields of display and sensing. Existing polyaniline has low solubility in organic solvents, and it is difficult to form a film by solution method, and most of the benzene rings are connected by N atoms, so the structure variety is limited and the function is single. C...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C07C211/54C07C211/58C07D209/86C07C209/52C08G73/02C09K9/02C09K11/06G01N21/64
Inventor 牛海军才继伟马丽娜
Owner HEILONGJIANG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com