31results about How to "Reversible color change" patented technology

The invention relates to the technical field of supramolecular chemistry, and discloses a preparation method of self-repairing multi-photoresponse double-layer supramolecular hydrogel, which comprisesthe following steps: (1) reacting N-isopropylacrylamide, cyclodextrin monomer and graphene oxide aqueous dispersion to obtain a hydrogel layer 1; (2) carrying out a reaction on N-isopropylacrylamide,a cyclodextrin monomer and acryloyloxyethyl trimethyl ammonium chloride to obtain a prepolymer solution of the hydrogel layer 2; and (3) injecting the prepolymer solution into a mold to obtain double-layer hydrogel, and soaking the double-layer hydrogel in an ammonium molybdate tetrahydrate solution to finally obtain the double-layer supramolecular hydrogel. According to the hydrogel, physical crosslinking is realized by utilizing host-guest interaction between cyclodextrin and N-isopropylacrylamide isopropyl, tight connection between double-layer hydrogel is also realized through host-guestinteraction, the double-layer bonding strength is high, and the hydrogel has good self-repairing performance, multiple photoresponse deformation discoloration performance and injectable performance.

The present invention provides a composition for forming a polymer dispersed liquid crystal, a polymer dispersed liquid crystal coating and a self-luminescent light-adjusting film. According to the present invention, the composition comprises a binder, an inorganic electroluminescence material, a liquid crystal material and a photo-initiator; the polymer dispersed liquid crystal coating formed from the composition can occur stable and reversible color change and the reversible change of the lights with different colors and the transparency are presented in appearance, such that the polymer dispersed liquid crystal coating formed from the composition achieves the color change in the true sense; and compared with the dye, the influence of the inorganic electroluminescence material on the curing rate and the curing degree on the binder polymer is low, and under the ultraviolet light irradiation, the formed liquid crystal droplet separated from the binder polymer and liquid crystal mixture has the good separation moldability and can form the droplet having the large pore size, such that the polymer dispersed liquid crystal coating formed from the composition has characteristics of low driving voltage and high on-state transmittance.

The invention provides an acid-base responsive electrochromic film and a preparation method and application thereof and an electrochromic device. The acid-base responsive electrochromic film comprisesan electrochromic layer, and the electrochromic layer is prepared from, by weight, 30-50 parts of polymethyl methacrylate, 8-20 parts of acid-responsive dye, 8-20 parts of base-responsive dye, 15-30parts of plasticizer and 10-25 parts of electrolyte, wherein the acid-responsive dye is the combination of electrochromic acid and an acid-responsive material, and the base-responsive dye is the combination of electrochromic base and a base-responsive material. The acid-base responsive electrochromic film can generate stable and reversible color changes under the action of an external electric field, and has the electrochromic performance.

The invention provides triarylated amine polyschiff base, a preparation method thereof taking triphenylamine as a raw material and an application, which relates to a preparation method of a polyschiff base and an application. The invention can solve the problems that solubility of the exiting polyschiff base in an organic solvent is low, expensive raw materials and rigorous and complex synthesis route are needed by light-emitting display polymers, and color change is not easy to regulate and control in the prior art. The method comprises the following steps: adding the organic solvent of a dialdehyde base compound into 4'-bisamino-4''-N-carbazolyl triphenylamine by three times, controlling the temperature to be 160 DEG C, reacting for 10-14 hours under the condition of nitrogen protection, depositing the polymer, extracting, drying, and obtaining the triarylated amine polyschiff base. The polyschiff base of the invention has the advantage of heat resistance and can be dissolved in the organic solvent. Under the action of acidity or voltage, the color of the polyschiff base is changed reversibly.

The invention discloses a preparation method of temperature sensing color change luminous polyurethane synthetic leather. According to the method, firstly, a long afterglow luminous material is modified; groups capable of reacting with isocyanate are introduced to the surface of the luminous material; then, the modified long afterglow luminous material and a temperature sensing color change material are simultaneously introduced into a polyurethane coating; the problems that the matching of the blended compound long afterglow luminous material and polyurethane is poor, migration and precipitation easily occur, the distribution is nonuniform, and the like are solved; good temperature sensing color change luminous characteristics are given to the polyurethane coating. The polyurethane synthetic leather can absorb ultraviolet light and visible light; during visible light irradiation, the reversible color change is shown along with the temperature change; light energy is stored, and is released in a luminous form at night; the luminous color can change along the temperature change; the defects that the color of the existing luminous material is concentrated in the narrow wavelength range, the colors are single, and the aesthetic feeling is lacked are overcome; new designs and varieties are given to the synthetic leather product; the functionality of the synthetic leather is improved; the application field of the synthetic leather is expanded.

The invention discloses a polyaniline derivative, a preparation method of reduced polySchiff base thereof and an application of the polyaniline derivative, which relate to a polyaniline material and a preparation method and an application thereof and are used for solving the technical problem of low dissolubility in an organic solvent and difficulty in processing into a film existing in the conventional polyaniline. The structural formula of the polyaniline derivative disclosed by the invention is shown in the specifications. The preparation method comprises the following steps of: adding conjugate polySchiff base, a solvent and sodium borohydride into a three-neck flask; raising the temperature to 10-70 DEG C, stirring and refluxing for 10-72 hours; cooling and pouring into methanol; and filtering and drying to obtain the polyaniline derivative. The polyaniline derivative is applied as a photoelectric material, and comprises an electrochromic material, a fluorescent sensing material, an acid-based sensing material, a hole transport material, a three-order nonlinear material, an anti-counterfeiting material, a camouflage material, an automobile rearview mirror material or a display material.

The invention discloses an electrochromatically and photochromatically responsive portable allochroic makeup mirror. A local area of the outer back surface of a flip-up cover of the mirror is respectively covered with a photochromic layer and an electrochromic layer so that the electrochromic layer and the photochromic layer respectively form patterned covering layers to control color and transparency of electrochromic devices in the electrochromic layer, set voltage is applied to the electrochromic devices to change the transparency and color of the electrochromic devices in the electrochromic layer as required, and the photochromic layer and the electrochromic layer jointly form a series of pattern combinations, color combinations or transparency combinations so that a picture shape with allochroic enameled appearance is formed on the upper surface of the mirror. The mirror changes the color significantly under different conditions, the color changing effect is significant, the color is bright and is dynamically presented and has varying sense of beauty, user experience of the mirror is improved, and more personal needs of a user are met.

The invention relates to a method for preparing a reversible discolouring membrane made from polyaniline composite nanofiber, which is characterized by comprising the following steps: dissolving an eigenstate polyaniline raw material in a stirred tank at room temperature to obtain polyaniline solution with a mass fraction of 0.2-15%; adding blending polymer to polyaniline solution at room temperature, evenly blending the mixture to obtain solution with the mass fraction of the blending polymer being 0.5-30%; inputting the solution to a spinning nozzle of an electrostatic spinning device at a flow velocity of 0.1-4mL / h at room temperature and a relative humidity of 20-60% for carrying out electrostatic spinning to prepare the nanometer composite fibre; and drying the nanofiber membrane obtained from a receiving device for 1-12h at 25-80 DEG C to obtain the reversible discolouring membrane made from polyaniline composite nanofiber. The invention features simple preparation process, low cost and good mechanical property, high flexibility, good corrosion resistance and uniform colour of the polyaniline composite nanofiber.

The invention discloses a preparation method of temperature sensing color change luminous polyurethane synthetic leather. According to the method, firstly, a long afterglow luminous material is modified; groups capable of reacting with isocyanate are introduced to the surface of the luminous material; then, the modified long afterglow luminous material and a temperature sensing color change material are simultaneously introduced into a polyurethane coating; the problems that the matching of the blended compound long afterglow luminous material and polyurethane is poor, migration and precipitation easily occur, the distribution is nonuniform, and the like are solved; good temperature sensing color change luminous characteristics are given to the polyurethane coating. The polyurethane synthetic leather can absorb ultraviolet light and visible light; during visible light irradiation, the reversible color change is shown along with the temperature change; light energy is stored, and is released in a luminous form at night; the luminous color can change along the temperature change; the defects that the color of the existing luminous material is concentrated in the narrow wavelength range, the colors are single, and the aesthetic feeling is lacked are overcome; new designs and varieties are given to the synthetic leather product; the functionality of the synthetic leather is improved; the application field of the synthetic leather is expanded.

The invention provides an electrochromic film, its preparation method and application, and an electrochromic device. The electrochromic film includes an electrochromic layer, and the raw materials of the electrochromic layer include the following components in parts by weight 30-50 parts by weight of polymethyl methacrylate; 18-22 parts by weight of acid response dye; 20-30 parts by weight of plasticizer; 10-20 parts by weight of electrolyte; wherein, the acid response dye is electroacid and A combination of acid responsive materials. The electrochromic thin film provided by the invention can undergo stable and reversible color changes under the action of an external electric field, and has electrochromic properties.

The invention provides triarylated amine polyschiff base, a preparation method thereof taking triphenylamine as a raw material and an application, which relates to a preparation method of a polyschiff base and an application. The invention can solve the problems that solubility of the exiting polyschiff base in an organic solvent is low, expensive raw materials and rigorous and complex synthesis route are needed by light-emitting display polymers, and color change is not easy to regulate and control in the prior art. The method comprises the following steps: adding the organic solvent of a dialdehyde base compound into 4'-bisamino-4''-N-carbazolyl triphenylamine by three times, controlling the temperature to be 160 DEG C, reacting for 10-14 hours under the condition of nitrogen protection, depositing the polymer, extracting, drying, and obtaining the triarylated amine polyschiff base. The polyschiff base of the invention has the advantage of heat resistance and can be dissolved in theorganic solvent. Under the action of acidity or voltage, the color of the polyschiff base is changed reversibly.

The invention discloses a polyaniline derivative, a preparation method of reduced polySchiff base thereof and an application of the polyaniline derivative, which relate to a polyaniline material and a preparation method and an application thereof and are used for solving the technical problem of low dissolubility in an organic solvent and difficulty in processing into a film existing in the conventional polyaniline. The structural formula of the polyaniline derivative disclosed by the invention is shown in the specifications. The preparation method comprises the following steps of: adding conjugate polySchiff base, a solvent and sodium borohydride into a three-neck flask; raising the temperature to 10-70 DEG C, stirring and refluxing for 10-72 hours; cooling and pouring into methanol; and filtering and drying to obtain the polyaniline derivative. The polyaniline derivative is applied as a photoelectric material, and comprises an electrochromic material, a fluorescent sensing material, an acid-based sensing material, a hole transport material, a three-order nonlinear material, an anti-counterfeiting material, a camouflage material, an automobile rearview mirror material or a display material.

The invention discloses an electric control dimming film, which comprises an upper electrode layer, a polymer dispersion liquid crystal layer, an electrochromic layer and a lower electrode layer from top to bottom, wherein the electric control dimming film simultaneously comprises the polymer dispersion liquid crystal layer and the electrochromic layer. Compared with the prior art adopting a measure of adding dye into the polymer dispersion liquid crystal layer, the electric control dimming film has the advantages that the polymer dispersion liquid crystal layer and the electrochromic layer are respectively adopted, and the problems of too high driving voltage and too low on-state transmission rate due to dye introduction into the polymer dispersion liquid crystal layer can be solved. Meanwhile, the electrochromic layer is applied to the electric control dimming film, the stable and invertible color change can occur under the effect of an extra electric field, and the electric control dimming film can show the colored and transparent invertible change on the appearance. On the basis of the special color change mechanisms of the electrochromic layer, the electric control dimming film provided by the invention realizes the true sense of electric control color change.

The invention provides an alkali-responsive electrochromic film and its preparation method and application. The alkali-responsive electrochromic film includes an electrochromic layer, and the electrochromic layer includes the following components in parts by weight: 25-60 parts by weight of polymethyl methacrylate; 15-25 parts by weight of alkali response dye; 15-30 parts by weight of plasticizer; 10-25 parts by weight of electrolyte; Composition of responsive materials. The alkali-responsive electrochromic thin film provided by the invention has the characteristic of electrochromism, the electrochromic response time is short, 0.01-10s, and the color stability time is long.

The invention discloses a perylene imide derivative self-assembled thin film and its application in the preparation of electrochromic film devices. The structural formula of the peryleneimide derivative self-assembled film is shown in formula (I), wherein n in formula (I) represents the number of self-assembled layers, and n is 4-16. Compared with other existing electrochromic materials, the electrochromic material prepared by the invention has the advantages of reversible color change, high color contrast, faster response time and the like. It can display color changes from red to purple, the optical contrast can reach 61.1%, and the response time is 1.23s, which is a potential electrochromic material. In formula (I), n represents the number of self-assembled layers, and n is 4-16 layers.

The invention relates to a polyaniline derivative, a preparation method of reductive poly Schiff base of the polyaniline derivative and application of the polyaniline derivative, in particular relates to a polyaniline material as well as a preparation method and application thereof, and is mainly used for solving the technical problems that the existing polyaniline has poor dissolubility in an organic solvent and is difficultly processed into a film. The structure formula of the polyaniline derivative is shown in the specification. The preparation method of the polyaniline derivative comprises the following steps: adding conjugated poly Schiff base, a solvent and sodium borohydride in a three-neck flask, heating to 10-70 DEG C, and stirring and refluxing for 10-72 hours; cooling, pouring a product obtained from the former step into methanol; and filtering and drying to obtain the polyaniline derivative. The polyaniline derivative can be used as photoelectric materials including an electrochromic material, a fluorescent sense material, an acidic sense material, a cavity transmission material, a three-order non-linear material, an anti-counterfeiting material, a camouflage material and an automobile rearview mirror material, and can also be used for proton detection.

The invention discloses a TiO 2 Nanoparticle-adsorbed peryleneimide derivative films and their application as electrochromic materials, the TiO 2 Nanoparticle Adsorbed Peryleneimide Derivative Films Composed of N,N’-Bis(2-Phosphoethyl)-3,4,9,10-Perylenetetracarboxylic Diimide (PPDI) and TiO 2 Nanoparticles are obtained by chemisorption. Compared with other existing electrochromic materials, the electrochromic material prepared by the invention has the advantages of reversible color change, high color contrast, faster response time and the like. It can display the color change from red to purple, the optical contrast can reach 30.05%, and the coloring time is 1.62s, which is a potential electrochromic material.

The invention provides a composition for forming polymer-dispersed liquid crystals, a polymer-dispersed liquid crystal coating and a self-illuminating dimming film. The composition includes adhesive, inorganic electroluminescent material, liquid crystal material and photoinitiator. The polymer-dispersed liquid crystal coating formed by the above composition can undergo stable and reversible color changes, and is manifested as reversible changes in light of different colors and transparency in appearance, so that the polymer-dispersed liquid crystal coating formed by the composition realizes a real sense of color change. Compared with dyes, inorganic electroluminescent materials have little effect on the curing speed and degree of curing of the binder polymer, and at the same time, under the irradiation of ultraviolet light, the liquid crystal microparticles formed by separating from the mixture of the binder polymer and liquid crystal The drop separation formability is good, and liquid crystal microdroplets with larger apertures can be formed, so that the polymer dispersed liquid crystal coating formed by the composition has the advantages of low driving voltage and high open-state transmittance.

The invention provides an acid-base responsive electrochromic film, its preparation method and application, and an electrochromic device. The acid-base responsive electrochromic film includes an electrochromic layer, and the electrochromic layer is The parts include the following components: 30-50 parts by weight of polymethyl methacrylate; 8-20 parts by weight of acid response dye; 8-20 parts by weight of base response dye; 15-30 parts by weight of plasticizer; 10-25 parts by weight of electrolyte parts by weight; wherein, the acid-responsive dye is a combination of an electroacid and an acid-responsive material, and the base-responsive dye is a combination of an electro-acid and a base-responsive material. The acid-base responsive electrochromic film provided by the invention can undergo stable and reversible color changes under the action of an external electric field, and has electrochromic properties.

The invention relates to electrochromatic materials and preparation methods thereof, particularly relates to an electrochromatic material made of isocyanate-triphenylamine and a method for preparing the electrochromatic material, and aims to solve the problem that films made of existing electrochromatic materials are prone to shed during test and poor in resistance to solvent corrosion. The structural formula of the electrochromatic material made of isocyanate-triphenylamine is shown as follows. The method includes: adding diisocyanate- triphenylamine or triisocyanate- triphenylamine into anhydrous dichloroethane, stirring under the shielding of nitrogen to enable the diisocyanate- triphenylamine or triisocyanate- triphenylamine to be completely dissolved and well mixed, heating the obtained mixture, adding dihydroxyl monomer, performing condensation backflow reaction at the temperature after heating, then cooling to the room temperature, and finally drying the solid reaction product obtained after filtering separation to constant weight to obtain the electrochromatic material. The method is mainly used for electrochromatic materials made of isocyanate-triphenylamine.