Fluorocarbon modified styrene-acrylic coating, and preparation method thereof

A technology of fluorocarbon modification and styrene-acrylic, which is applied in the direction of anti-corrosion coatings and coatings, and can solve the problems of high weather resistance, high chemical corrosion resistance, water resistance, scrub resistance and poor artificial aging resistance

Inactive Publication Date: 2013-12-04
JIANGSU UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, styrene-acrylic building exterior wall coatings still have disadvantages such as high weather resistance, high chemical corrosion resistance, water resistance, scrub resistance and artificial aging resistance.

Method used

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  • Fluorocarbon modified styrene-acrylic coating, and preparation method thereof
  • Fluorocarbon modified styrene-acrylic coating, and preparation method thereof
  • Fluorocarbon modified styrene-acrylic coating, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] 1. Formula by mass percentage

[0017]

[0018] 2. Preparation method

[0019] Step 1. Add GHT-1 styrene-acrylic emulsion into a four-necked bottle, stir and raise the temperature to 73°C, slowly add GHSF-25 fluorocarbon emulsion, and at the same time slowly add γ-aminopropyltriethoxysilane, until the γ- -After aminopropyltriethoxysilane, add polyethylene glycol octylphenyl ether, hydroxyl silicone oil modified polyacrylate, polyether modified polysiloxane, and Cathone respectively, and the temperature is controlled at 76°C for reaction Half an hour later, the temperature was lowered and the material was discharged to obtain a fluorocarbon modified styrene-acrylic emulsion.

[0020] Step 2. Add water into the mixing tank, start the mixer, add rutile titanium dioxide and stir evenly; then add the fluorocarbon modified styrene-acrylic emulsion modified in step 1 and stir evenly, then add talcum powder, mica powder, and calcite respectively The powder is stirred evenl...

Embodiment 2

[0026] 1. Formula by mass percentage

[0027]

[0028]

[0029] 2. Preparation method

[0030] Step 1. Add GHT-1 styrene-acrylic emulsion into a four-necked bottle, stir and raise the temperature to 74°C, slowly add GHSF-25 fluorocarbon emulsion, and at the same time slowly add γ-aminopropyltriethoxysilane, until the γ- -After aminopropyltriethoxysilane, add polyethylene glycol octylphenyl ether, hydroxyl silicone oil modified polyacrylate, polyether modified polysiloxane, and Cathone respectively, and the temperature is controlled at 77°C for reaction Half an hour later, the temperature was lowered and the material was discharged to obtain a fluorocarbon modified styrene-acrylic emulsion.

[0031] Step 2. Add water into the mixing tank, start the mixer, add rutile titanium dioxide and stir evenly; then add the fluorocarbon modified styrene-acrylic emulsion modified in step 1 and stir evenly, then add talcum powder, mica powder, and calcite respectively The powder is s...

Embodiment 3

[0037] 1. Formula by mass percentage

[0038]

[0039] 2. Preparation method

[0040] Step 1. Add GHT-1 styrene-acrylic emulsion into a four-necked bottle, stir and raise the temperature to 75°C, slowly add GHSF-25 fluorocarbon emulsion, and at the same time slowly add γ-aminopropyltriethoxysilane, until the addition of γ -After aminopropyltriethoxysilane, add polyethylene glycol octylphenyl ether, hydroxyl silicone oil modified polyacrylate, polyether modified polysiloxane, and Cathone respectively, and the temperature is controlled at 78°C for reaction Half an hour later, the temperature was lowered and the material was discharged to obtain a fluorocarbon modified styrene-acrylic emulsion.

[0041] Step 2. Add water into the mixing tank, start the mixer, add rutile titanium dioxide and stir evenly; then add the fluorocarbon modified styrene-acrylic emulsion modified in step 1 and stir evenly, then add talcum powder, mica powder, and calcite respectively The powder is st...

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PUM

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Abstract

The invention discloses a fluorocarbon modified styrene-acrylic coating. The fluorocarbon modified styrene-acrylic coating consists of the following components in percentage by mass: 34 to 42.5 percent of GHT-1 styrene-acrylic emulsion, 5.2 to 6.5 percent of GHSF-25 fluorocarbon emulsion, 0.4 to 0.5 percent of gamma-aminopropyltriethoxysilan, 0.4 to 0.5 percent of polyethylene glycol phenyl ether, 18 to 22 percent of rutile type titanium dioxide, 8 to 10 percent of talcpowder, 8 to 10 percent of mica powder, 8 to 11 percent of calcite in powder, 0.1 to 0.15 percent of hydroxy silicone oil modified polyacrylate, 0.01 to 0.02 percent of polyether modified polysiloxane, 0.01 to 0.02 percent of kazon and the balance of water. A preparation method comprises the following steps of: modifying the styrene-acrylic emulsion by using the fluorocarbon emulsion, the gamma-aminopropyltriethoxysilan, and the polyethylene glycol phenyl ether at the temperature of between 76 and 80 DEG C, and preparing by using the modified fluorocarbon modified styrene-acrylic emulsion to obtain the fluorocarbon modified styrene-acrylic coating. The preparation process is simple, and low in investment and cost; and a product has the advantages of high weather fastness, chemical resistance, and water resistance, scrubbing resistance, and artificial aging resistance.

Description

technical field [0001] The invention belongs to the technical field of architectural coatings, and relates to a coating, in particular to a fluorocarbon-modified styrene-acrylic coating and a preparation method thereof, which are mainly used in the field of architectural exterior wall coatings. Background technique [0002] In recent years, the research on styrene-acrylic coatings has achieved certain results, but there are still many problems to be solved. For example, styrene-acrylic building exterior wall coatings still have disadvantages such as high weather resistance, high chemical corrosion resistance, water resistance, scrub resistance and relatively poor artificial aging resistance. Using fluorocarbon emulsion modified styrene-acrylic emulsion to develop fluorocarbon-modified styrene-acrylic coating can overcome the existing shortcomings and meet the technical performance index requirements. Because fluorine-containing coatings have the advantages of high weather r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D125/14C09D127/12C09D7/12C09D5/08
Inventor 郭文录张秀荣
Owner JIANGSU UNIV OF SCI & TECH
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