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Method for extracting iron by utilizing nickel slag and preparing fibers

A technology of nickel slag and fiber, which is applied in the field of iron extraction and fiber preparation by using nickel slag, can solve the problems that have not yet been achieved, it is difficult to achieve iron oxide enrichment, and there are not many methods, so as to achieve the effect of reducing energy consumption

Active Publication Date: 2013-06-12
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the research on nickel slag at home and abroad focuses on the extraction and recovery of Fe. The iron oxide in nickel slag is mainly composed of FeO SiO 2 It exists in the form of iron oxides, and it is difficult to enrich iron oxides by conventional beneficiation methods
At present, there are some high-temperature reduction processes and methods, which can efficiently extract useful iron and nickel, but the utilization of high-temperature silicate slag after iron extraction is currently less researched, and there are not many methods, and nickel has not yet been used. Process of making inorganic fiber from slag

Method used

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  • Method for extracting iron by utilizing nickel slag and preparing fibers
  • Method for extracting iron by utilizing nickel slag and preparing fibers

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The thermal nickel slag produced in the nickel smelting process is analyzed by XRF (X-ray fluorescence spectrometry) method, among which SiO 2 The content is 45.3%, Fe 2 o 3 39.1%, MgO content is 2.0%, CaO is 4.5%, Al 2 o 3 It is 6.4%, and the rest is a small amount of Cu, Ni, S, etc.

[0026] Put the newly discharged nickel slag in the slag bag for heat preservation. The slag bag transports the hot nickel slag to the production workshop and enters the electric furnace. Iron oxide, while adding 10% mass fraction of CaO and so on. The reduced molten iron is separated and cast into ingots. Add mass fraction 8% bauxite (containing Al 2 o 3 41%), the mixture is added to the temperature-adjusting furnace, and the temperature is controlled to 1300°C. Using the high-speed air injection method and spraying under the pressure of 1.5MPa, the inorganic nickel slag fiber is obtained. The average diameter of the fiber is 5.0μm, and the aspect ratio is 1000-2000. The microsco...

Embodiment 2

[0028] The thermal nickel slag produced in the nickel smelting process is analyzed by XRF (X-ray fluorescence spectrometry) method, among which SiO 2 The content is 44.3%, Fe 2 o 3 29.7%, MgO content is 9.7%, CaO is 5.0%, Al 2 o 3 It is 5.8%, and the rest is a small amount of Cu, Ni, S, etc.

[0029] Put the hot nickel slag discharged from the nickel smelting process into the slag car for heat preservation. The slag car transports the hot nickel slag to the production workshop and enters the electric furnace. Reducing iron oxides in nickel slag and adding 30% CaO etc. at the same time. The reduced molten iron is separated and cast into ingots. Add 8% bauxite (containing Al 2 o 3 50%), the mixture is added into the tempering furnace, and the temperature is controlled to 1500°C. The inorganic nickel slag fiber is obtained by blowing under a pressure of 1.25 MPa by a high-speed air blowing method, the average diameter of the fiber is 5.4 μm, and the length-to-diameter rat...

Embodiment 3

[0031] The thermal nickel slag produced in the nickel smelting process is analyzed by XRF (X-ray fluorescence spectrometry) method, among which SiO 2 The content is 48.3%, Fe 2 o 3 39.7%, MgO content is 3.7%, CaO is 3.5%, Al 2 o 3 It is 2.8%, and the rest is a small amount of Cu, Ni, S.

[0032] The hot nickel slag discharged from the nickel smelting process is placed in a slag bag for heat preservation. The slag bag transports the hot nickel slag to the production workshop and enters the electric furnace. powder to reduce iron oxides in nickel slag, and at the same time add 20% CaO and so on. The reduced molten iron is separated and cast into ingots. Add 30% kaolinite (containing Al 2 o 3 30%, SiO 2 50%), the mixture is added into the tempering furnace, and the temperature is controlled to 1300°C. Fibers were obtained by centrifugal spinning method, and the spinning roll speed was 2000r / min. The obtained fiber has an average diameter of 5.9 μm and an aspect ratio of...

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Abstract

The invention provides a method for extracting iron by utilizing nickel slag and preparing fibers. The method comprises the following steps of: adding a reducing agent and auxiliary materials to nickel slag discharged in a nickel smelting process to reduce oxides of iron in the nickel slag into iron; after the iron is separated, adding an additive to the remaining molten nickel slag; and blowing or throwing the molten mixture with the additive through high-speed air or a centrifugation throwing machine to prepare inorganic fibers. According to the method, on the basis of melting and reducing the thermal nickel slag for refining the iron, the remaining slag is used as a main raw material to prepare the inorganic slag fibers, and the waste nickel slag is changed into valuable materials and recycled, so that the sensible heat of the thermal nickel slag is sufficiently utilized, and the energy consumption in the processes of refining the iron from the nickel slag and producing the fibers is reduced. The main components of the prepared inorganic nickel slag fibers are SiO2, Al2O3 and the like, and the prepared inorganic nickel slag fibers belong to high-temperature inorganic fibers andcan be widely applied to the fields of pipe warm preservation, industrial fire resistance and warm preservation and the like.

Description

technical field [0001] The invention belongs to the field of comprehensive utilization of industrial waste residues, in particular to a method for extracting iron and preparing fibers by using nickel slag. Background technique [0002] Nickel slag is a kind of industrial waste discharged in the process of smelting nickel metal. Nickel slag with Fe 2 o 3 , SiO 2 It is the main component, which is the granulated slag formed after the melt is quenched by water, and some enterprises directly discharge it without water quenching. The temperature of hot nickel slag is 1100-1300°C, which contains a lot of sensible heat. [0003] With the development of my country's economy, my country's nickel production has increased rapidly in recent years. It was only 40,000 tons in 1997, 67,000 tons in 2004, and nearly 90,000 tons in 2010. To produce 1 ton of nickel by flash furnace smelting method, 6 to 16 tons of nickel slag need to be discharged. At present, about 900,000 tons of nicke...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B15/00C03B37/00
Inventor 王习东赵大伟张作泰刘丽丽
Owner PEKING UNIV
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