Fireproof material of furnace bottom of blast furnace hearth and preparation method of fireproof material

A technology of refractory materials and blast furnace furnaces, applied in the field of refractory materials, can solve the problems of increasing the complexity of blast furnace masonry construction, reducing, and unfavorable production costs of blast furnaces, and achieve enhanced corrosion resistance of molten iron, high thermal conductivity, and resistance to molten iron The effect of excellent corrosion performance

Active Publication Date: 2013-08-21
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If these products are combined with ceramic cups to form a ceramic material-carbon material composite structure, it will inevitably increase the complexity of blast furnace masonry construction, and it will not be conducive to the reduction of blast furnace production costs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A refractory material for the hearth bottom of a blast furnace and a preparation method thereof. The raw materials and contents of the refractory materials are: 32-36wt% for artificial graphite, 22-26wt% for corundum, 6-10wt% for electric calcined anthracite, 5-10wt% for flake graphite, α-Al 2 o 3 Micro powder is 4~6wt%, elemental silicon powder is 7~10wt%, metal aluminum powder is 2~3wt%, ferrocene is 0.1~0.3wt%, and thermosetting phenolic resin is 15~18wt%.

[0016] The preparation process of the refractory material is as follows: except that the thermosetting phenolic resin is added twice, the other raw materials are firstly added flake graphite, α-Al 2 o 3 Micropowder, elemental silicon powder, metal aluminum powder and ferrocene are pre-mixed evenly to obtain a pre-mixed powder; then artificial graphite, corundum, and electric calcined anthracite are mixed for 2 to 5 minutes, and 13 to 15 wt% of thermosetting phenolic resin is added for Mix and grind for 5-10 mi...

Embodiment 2

[0020] A refractory material for the hearth bottom of a blast furnace and a preparation method thereof. The raw materials and contents of the refractory materials are: 36-42wt% of artificial graphite, 20-24wt% of corundum, 3-8wt% of electric calcined anthracite, 4-7wt% of flake graphite, α-Al 2 o 3 Micro powder is 5~9wt%, elemental silicon powder is 6~8wt%, metal aluminum powder is 3~4wt%, ferrocene is 0.2~0.4wt%, and thermosetting phenolic resin is 16~19wt%.

[0021] The preparation process of the refractory material is as follows: except that the thermosetting phenolic resin is added twice, the other raw materials are firstly added flake graphite, α-Al 2 o 3 Micropowder, elemental silicon powder, metal aluminum powder and ferrocene are pre-mixed evenly to obtain pre-mixed powder; then artificial graphite, corundum, and electric calcined anthracite are mixed for 2-5 minutes, and 14-16wt% of thermosetting phenolic resin is added for mixing. Grinding, the mixing time is 5-10...

Embodiment 3

[0025]A refractory material for the hearth bottom of a blast furnace and a preparation method thereof. The raw materials and contents of the refractory materials are: 35-40wt% of artificial graphite, 25-30wt% of corundum, 2-4wt% of electric calcined anthracite, 4-9wt% of flake graphite, α-Al 2 o 3 Micro powder is 4~6wt%, elemental silicon powder is 6~8wt%, metal aluminum powder is 2~3wt%, ferrocene is 0.2~0.4wt%, and thermosetting phenolic resin is 15~18wt%.

[0026] The preparation process of the refractory material is as follows: except that the thermosetting phenolic resin is added twice, the other raw materials are firstly added flake graphite, α-Al 2 o 3 Micropowder, elemental silicon powder, metal aluminum powder and ferrocene are pre-mixed evenly to obtain pre-mixed powder; then artificial graphite, corundum, and electric calcined anthracite are mixed for 2-5 minutes, and 13-15wt% of thermosetting phenolic resin is added for mixing. Grinding, the mixing time is 5-10 ...

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Abstract

The invention relates to a fireproof material of a furnace bottom of a blast furnace hearth and a preparation method of the fireproof material. The fireproof material comprises the following ingredients in percentage by mass: 32 to 45 percent of artificial graphite, 20 to 30 percent of corundum, 2 to 10 percent of electrically calcined anthracite, 3 to 10 percent of crystalline flake graphite, 4 to 10 percent of Alpha-Al2O3 micro powder, 6 to 10 percent of single-substance silicon powder, 2 to 4 percent of metal aluminum powder, 0.1 to 0.5 percent of ferrocene and 15 to 20 percent of thermosetting phenol resin. A preparation process of the fireproof material comprises the steps that: except that the thermosetting phenol resin is added in twice, the rest ingredients such as the crystallineflake graphite, the Alpha-Al2O3 micro powder, the single-substance silicon powder, the metal aluminum powder and the ferrocene are uniformly premixed according to the proportion, and the premixed powder is prepared; next, the artificial graphite, the corundum, the electrically calcined anthracite, the premixed powder and the thermosetting phenol resin are mixed and milled uniformly and are formed, and the drying is carried out under the condition of 180 to 220 DEG C; and finally, the fireproof material is fired in buried carbon atmosphere under the condition of 1100 to 1450 DEG C. The preparation process of the fireproof material is simple, and the prepared fireproof material has the characteristics that the molten iron corrosion resistance performance is excellent, the heat conductivity is high, the micropore rate is high, and the intensity is high.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a refractory material for the hearth bottom of a blast furnace and a preparation method thereof. Background technique [0002] The blast furnace is the main equipment for ironmaking. With the progress of the steel industry in various countries in the world, the blast furnace is developing in the direction of large-scale, high-efficiency and long-life. In the ironmaking process of the blast furnace, the working conditions of the hearth bottom are particularly harsh, and its erosion and damage are the result of the joint action of chemistry, fluid dynamics and thermal deformation; and this part cannot be repaired during the production process like other parts of the blast furnace . Therefore, it is generally believed that the refractory material for the hearth bottom is the main link that restricts the longevity of the blast furnace. [0003] At present,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66C04B35/622C04B35/65
Inventor 桑绍柏李亚伟李亦韦李远兵赵雷金胜利李淑静
Owner WUHAN UNIV OF SCI & TECH
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