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A kind of preparation method of steel biomimetic multi-scale superhydrophobic functional surface

A super-hydrophobic, multi-scale technology, which is applied in the direction of surface coating liquid devices, special surfaces, coatings, etc., to achieve the effect of simple operation process, low requirements for experimental conditions, and not easy to freeze

Inactive Publication Date: 2014-10-29
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these methods can obtain hydrophobic and oleophobic properties, they often require expensive equipment and the operation process is cumbersome, which increases the manufacturing cost and limits its popularization and application.

Method used

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  • A kind of preparation method of steel biomimetic multi-scale superhydrophobic functional surface
  • A kind of preparation method of steel biomimetic multi-scale superhydrophobic functional surface

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0025] The surface of the X70 pipeline steel sample is shot peened by an industrial shot peening machine, the particle size of the steel shot is 0.9 mm, and the shot peening time is 2 minutes.

[0026] Prepare a hydrochloric acid solution with a concentration of 6mol / L, put the shot blasted X70 pipeline steel sample into the hydrochloric acid solution for chemical etching, the etching time is 320 minutes, take it out after the reaction, put it in deionized water, and clean it with ultrasonic waves Clean the instrument and dry it with a hair dryer. After the above treatment, a large number of "coral" structures with a diameter of about 1 μm were formed on the surface of the sample. On each "coral" structure, nano-scale fine layered and worm-like structures were evenly distributed. Together form a micro-nano multi-scale structure, such as figure 1 As shown, the steel surface has the micro-nano structure required to form a hydrophobic surface.

[0027] Prepare a myristic acid ...

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Abstract

The invention relates to a preparation method of a steel bionic multiscale dewatering function surface, which belongs to the technical field of metal material surface modification. The existing preparation method of the metal material dewatering function surface is mostly expensive in equipment, complex in operation and limited in popularization and application. The preparation method comprises conducting shot blasting treatment on steel surface to form coarse surface, and simultaneously refining surface grains and increasing grain boundary and microdefects; then adopting hydrochloric acid solution to conduct chemical corrosion on the surface, and further refining microcosmic details of surface topography through preferential corrosion of acid liquor on the grain boundary and the microdefects; and finally conducting lower-energy decoration on the surface, and obtaining the bionic multiscale dewatering function on the material surface. A contact angle formed by the fact that water is dropped on the bionic surface is 150 degrees, and superhydrophobicity degree is achieved. The preparation method is simple in process, easy in operation, free of limitation of substrate shapes and apt to conduct industrial production.

Description

technical field [0001] The invention belongs to the technical field of surface modification of metal materials, and in particular relates to a method for performing shot peening treatment, chemical etching and low-energy modification on the surface of steel materials, so that the surface of steel materials can obtain bionic multi-scale hydrophobic functions. [0002] Background technique [0003] Hydrophobic surfaces have broad application prospects. Studies have shown that applying hydrophobic surfaces to building materials such as glass, ceramics, and concrete can make the material self-cleaning. Applying hydrophobic surface to textiles can produce waterproof, anti-fouling and self-cleaning effects; applying hydrophobic surface to metal materials can produce effects of self-cleaning, anti-corrosion, and reducing friction coefficient; applying hydrophobic surface to the shell of ships and ships Or the inner wall of the pipe, which can reduce the frictional resistance betwe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21D7/06C23F1/28C23F1/00B05D5/08
Inventor 于思荣王晓龙王位
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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