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Preparation method of high-substituted-ratio carboxyl methyl guar printing gum

A technology of carboxymethyl guar gum and printing paste, which is applied in the field of preparation of high-substitution carboxymethyl guar gum printing paste, can solve the problems of skyrocketing price of sodium alginate, hard fabric feel and long beating time And other problems, to improve the fabric feel, save time and effort to block the net, improve the effect of uniformity

Active Publication Date: 2013-12-11
无锡金鑫科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the further development and utilization of sodium alginate, especially in the food field, the price of sodium alginate began to skyrocket exponentially, which made printing and dyeing enterprises feel huge cost pressure. There are also shortcomings such as long beating time, strong fluidity, and easy leakage. Domestic printing and dyeing auxiliaries manufacturers have tried to modify various vegetable gums with carboxymethyl, but they have not been able to solve the problem due to the grafting group. The fabric feels hard due to unevenness, so no mature domestic alternative products have been launched so far
At the same time, the solvent method, that is, the wet process, was mostly used for the modification of vegetable gums in the past, which caused serious waste of solvents and polluted the environment.

Method used

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  • Preparation method of high-substituted-ratio carboxyl methyl guar printing gum

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The preparation method of the high degree of substitution carboxymethyl guar gum printing paste of the present invention adopts the following process steps:

[0026] Atomize and spray 30Kg of alcoholic solution containing 8.5Kg of sodium hydroxide into 100Kg of guar collagen powder, alkalinize at 20°C for 30min; 25Kg of etherifying agent sodium chloroacetate, heated to 50°C, reacted for 3h, cooled after the reaction, neutralized with 1.5Kg of acetic acid for 30min, and controlled the pH value of the final product between 5-8. The neutralized crude product enters the airflow dryer and is dried at 105°C for 5 minutes with a moisture content of 10%. The intermediate product after drying and dehumidification is milled by a pulverizer and the fineness reaches 200 mesh, and is sieved by a vibrating sieve , to obtain a high degree of substitution of carboxymethyl guar gum printing paste (gua I).

Embodiment 2

[0028] The preparation method of the high degree of substitution carboxymethyl guar gum printing paste of the present invention adopts the following process steps:

[0029] Atomize and spray 40Kg of alcohol solution containing 13.0Kg sodium hydroxide into 100Kg of guar collagen powder, alkalinize at 30°C for 30 minutes; then atomize and spray 9Kg of hydrogen peroxide solution, oxidize at 30°C for 30 minutes; then add 35Kg The etherification agent sodium chloroacetate was heated to 70°C, reacted for 2.5 hours, cooled after the reaction, and neutralized with 2.0Kg acetic acid for 30 minutes, and the pH value of the final product was controlled between 5-8. The neutralized crude product enters the airflow dryer and is dried at 110°C for 6 minutes with a moisture content of 9%. The intermediate product after drying and dehumidification is milled by a pulverizer and the fineness reaches 200 mesh, and is sieved by a vibrating sieve , to obtain a high degree of substitution of carbox...

Embodiment 3

[0031] The preparation method of the high degree of substitution carboxymethyl guar gum printing paste of the present invention adopts the following process steps:

[0032] Atomize and spray 50Kg of alcoholic solution containing 16.0Kg of sodium hydroxide into 100Kg of guar collagen powder, alkalinize at 30°C for 30 minutes; then atomize and spray into 10Kg of hydrogen peroxide solution, oxidize at 30°C for 40 minutes; then add 45Kg The etherification agent sodium chloroacetate was heated to 80°C, reacted for 2.0 hours, cooled after the reaction, and neutralized with 3.0Kg acetic acid for 30 minutes, and the pH value of the final product was controlled between 5-8. The neutralized crude product enters the airflow dryer and is dried at 120°C for 8 minutes with a moisture content of 10%. The intermediate product after drying and dehumidification is milled by a pulverizer and the fineness reaches 200 mesh, and is screened by a vibrating sieve , to obtain high degree of substituti...

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Abstract

The invention discloses a preparation method of high-substituted-ratio carboxyl methyl guar printing gum, which belongs to the technical field of modified guar. The preparation method comprises the steps of performing the procedures of atomizing alkalization, atomizing oxidization, etherification, cooling neutralization, drying, crushing screening and packaging on raw guar powders to obtain the high-substituted-ratio carboxyl methyl guar printing gum. According to the preparation method, the uniformity of a grafting group is ensured by virtue of high-efficiency atomizing and spraying; the high substituted ratio of a final product is ensured by virtue of semi-dry etherification, so that the difficulties of poor uniformity and low substituted ratio of the conventional carboxyl methyl vegetable glue are solved; and simultaneously, compared with the conventional wet processing, the preparation method is more environment-friendly and more economical. The product, namely the high-substituted-ratio carboxyl methyl guar printing gum, disclosed by the invention can partly or wholly replace sodium alga acid to be applied to printing of activated dyes and the printing process of other anionic dyes, and is equivalent to the sodium alga acid in the aspect of application effects of water solubility, color fastness, color yield, vividness, handfeeling and the like, thus serving as a good substitute of the sodium alga acid.

Description

technical field [0001] The invention relates to a method for preparing a high degree of substitution carboxymethyl guar gum printing paste, which belongs to the technical field of modified guar gum and can replace sodium alginate and be used in the fabric printing process of reactive and other anionic dyes. Background technique [0002] Printing paste is an important part of printing paste. It does not react during the printing process and mainly acts as a transfer medium. Its performance directly affects the quality and cost of printed products. At present, with the development of printing and dyeing technology, various synthetic thickeners with excellent performance have been widely used in actual production, but sodium alginate is still the most widely used as a traditional paste for reactive dye printing. However, with the further development and utilization of sodium alginate, especially in the food field, the price of sodium alginate began to skyrocket exponentially, w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/48D06P1/38C08B37/00
Inventor 谈玉琴许超徐渭春刘海水钱伯良
Owner 无锡金鑫科技有限公司
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