Activated carbon coating/foam silicon carbide structural catalyst and preparation method thereof

A foamed silicon carbide, structural catalyst technology, applied in catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem of discontinuous opening, separation of catalyst and reaction product, poor heat and mass transfer effect and other problems, to achieve the effects of good oxidation resistance, reduced loss and improved ease of use

Active Publication Date: 2012-12-12
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
View PDF3 Cites 29 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the deficiencies of the prior art, the object of the present invention is to provide a "activated carbon coating / foamed silicon carbide" catalyst with a three-dimensional interconnected structure and its preparation method, which solves the problems of discontinuous openings, Separation of catalyst and reaction product, poor heat and mass transfer effect, etc.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Activated carbon coating/foam silicon carbide structural catalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] a. Soak silicon carbide foam ceramics with an average pore diameter of 1mm in NaOH or KOH solution with a concentration of 3 mol / L for 8 minutes to improve the surface roughness and remove oil and other impurities on the surface, then wash with water, and then store at 120°C Dry in air atmosphere for 3 hours;

[0038] b. In terms of weight ratio, the ratio of aminophenol-formaldehyde resin:activated carbon:curing agent:alcohol=100:50:2:100 was used to prepare suspension, and ball milled for 1 hour to obtain slurry. Wherein, the curing agent is hexamethylenetetramine.

[0039] c. Fully soak the foamed silicon carbide ceramics obtained in step a in the slurry in step b for 5 minutes, then take it out, blow off excess slurry with compressed air or centrifuge, and dry it in an air atmosphere at 100°C.

[0040] d. Repeat step c for the dried sample until the loading of the coating reaches 200g / L.

[0041]e. Put the sample obtained in step d into a muffle furnace or a vacuu...

Embodiment 2

[0046] The difference from Example 1 is that the weight ratio of the coating slurry in step b is phenolic resin:activated carbon:curing agent:alcohol=100:100:2:100. Wherein, curing agent is oxalic acid.

Embodiment 3

[0048] The difference from Example 1 is that the weight ratio of the coating slurry in step b is epoxy-modified phenolic resin:activated carbon:curing agent:alcohol=100:150:2:100. Wherein, curing agent is citric acid.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention relates to the field of structural catalysts, in particular to an activated carbon coating / foam silicon carbide catalyst with a three-dimensional communicated structure and a preparation method for the catalyst. The invention aims to solve the problems that hole opening is discontinuous, the catalyst and reaction products are separated, a heat transfer and mass transfer effect is poor and the like in the prior art. By taking foam silicon carbide as a catalyst carrier, an activated carbon coating covers on the surface of the foam silicon carbide, wherein the activated carbon coating is between 0.1 micron and 500 microns thick, and a metal catalysis active component is loaded on the activated carbon coating. The activated carbon coating is prepared on the surface of the foam silicon carbide with the three-dimensional communicated structure, then, the metal catalysis active component is loaded, and activating treatment is performed on the metal catalysis active component to obtain the catalyst. According to the activated carbon coating / foam silicon carbide catalyst, holes in the catalyst carrier are totally communicated, thus, an enclosure space does not exist, and a heat transfer and mass transfer process of the chemical reaction can be strengthened. The activated carbon coating / foam silicon carbide catalyst has the characteristics that the temperature field distribution of the catalytic reaction is uniform, the heat inactivation rate is low, the pressure drop is low and the like.

Description

technical field [0001] The invention relates to the field of structural catalysts, in particular to an "activated carbon coating / foamed silicon carbide" catalyst with a three-dimensional connected structure and a preparation method thereof. Background technique [0002] Activated carbon has the characteristics of large specific surface area, unique pore structure, stable surface chemical functional groups, resistance to acid and alkali corrosion, and hydrophobicity. Therefore, it is an excellent adsorbent, catalyst and catalyst carrier, and is widely used in the fields of chemical industry and environmental protection. [0003] The research, production and application of activated carbon have developed rapidly. At present, it is widely used in the form of powder, granular activated carbon and activated carbon fiber. The above-mentioned activated carbon has the following disadvantages in the application: ① The thermal conductivity of activated carbon itself is low, and it can...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/224B01J35/00B01J37/025
Inventor 杨振明张劲松矫义来田冲曹小明
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products