Positive radiation-sensitive composition, interlayer insulating film for display element, and method for forming same
A radiation-sensitive composition technology, applied in the field of positive-type radiation-sensitive compositions, to achieve high dry etching resistance and good heat resistance
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[0235]
[0236] The positive radiation-sensitive composition is mixed with the above-mentioned [A] polymer, [B] siloxane polymer and [C] photoacid generator, appropriate components as needed, and other optional components in a solvent. It is prepared in a dissolved or dispersed state. For example, the positive radiation sensitive composition can be prepared by mixing in a solvent at a specified ratio.
[0237] As the solvent, a solvent that can uniformly dissolve or disperse each component without reacting with each component can be suitably used. Examples of solvents include alcohols, ethers, alcohol ethers, glycol alkyl ether acetates, diethylene glycol alkyl ethers, propylene glycol monoalkyl ethers, and propylene glycol monoalkyl ether acetates. , Propylene glycol monoalkyl ether propionate, aromatic hydrocarbons, ketones, other esters, etc. These solvents can be used alone or in combination of two or more kinds.
[0238] As alcohols, for example methanol, ethanol, benzyl al...
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[0272] Hereinafter, the present invention will be described in detail based on examples, but the present invention is not limited by the description of the examples.
[0273]
Synthetic example 1
[0275] In a flask equipped with a condenser and a stirrer, 7 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts by mass of diethylene glycol ethyl methyl ether were added. Next, 5 parts by mass of methacrylic acid, 40 parts by mass of 1-ethoxyethyl methacrylate, 5 parts by mass of styrene, 40 parts by mass of glycidyl methacrylate, and 10 parts by mass of methacrylic acid were added. After nitrogen substitution of 2-hydroxyethyl acrylate and 3 parts by mass of α-methylstyrene dimer, stirring was started slowly. The temperature of the solution was raised to 70°C, and the temperature was maintained for 5 hours to obtain a polymer solution containing the polymer (A-1). The Mw of the polymer (A-1) was 9,000. The solid content concentration of the polymer solution was 32.1% by mass.
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