The application discloses the technical field of organic
silicon material, and relates to a high-temperature-resistant organic
silicon polymer and a preparation method and application thereof. The high-temperature-resistant organic
silicon polymer is formed by a ladder-shaped polysiloxane and a linear polysiloxane. The ladder-shaped polysiloxane is dehydrated and condensed and ring-closed with a double functional
silanol group on one side end of the ladder-shaped polysiloxane and an alkenyl
boronic acid, and is further chain-extended by a silicon
hydrogen addition reaction with a linear polysiloxane with a terminal
hydrogen group, so that a ladder-linear
block structure organic silicon
polymer bridged by a borate group is finally obtained. The block organic silicon polymer contains the ladder-shaped molecule which is heat-resistant in nature, and the borate bridging group can further strengthen the heat-resistant property of the material. The block organic silicon polymer disclosed by the application has a heat-resistant temperature (according to the
weight loss of 1.0% when initial
decomposition) of 435 DEG C. The preparation method of the high-temperature-resistant organic silicon polymer is simple in process, simple in equipment, and easy in
raw material acquisition, and is suitable for large-scale industrial production. The prepared organic silicon material is a
thermoplastic polymer, has good film-forming property, can be hot-pressed into a film, and has a wide application prospect as a high-temperature-resistant elastic
film material.