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Amorphous alloy strip with composition gradient and manufacturing method thereof

A composition gradient and amorphous alloy technology, which is applied in the field of manufacturing amorphous nanocrystalline alloy thin strips, can solve the problems of complex manufacturing process, no gradient functional materials, and no C element concentration gradient, so as to achieve low production cost and expand Field of application, large size effect

Active Publication Date: 2014-08-13
ADVANCED TECHNOLOGY & MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this material is obtained by additional heat treatment on the basis of ordinary uniform amorphous alloy strips, and the manufacturing process is relatively complicated.
[0005] Chinese patent CN200510066862.5, named "Fe-based amorphous alloy ribbon", introduces a Fe-based amorphous alloy ribbon, in which the C concentration distribution has a peak in the range of 2-20nm; but the The patent only states that the amorphous ribbon invented by it has composition changes in the thickness direction, but does not form a C element concentration gradient, so it does not have the characteristics of a gradient functional material

Method used

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  • Amorphous alloy strip with composition gradient and manufacturing method thereof
  • Amorphous alloy strip with composition gradient and manufacturing method thereof
  • Amorphous alloy strip with composition gradient and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0081] First set the composition to Fe 76 Si 9 B 13 C 2 The alloy is melted in a high-frequency electric furnace. After the melting is completed and the composition is uniform, the molten high-temperature molten steel is sprayed onto the cooling roll rotating at a high speed of 30m / s through a nozzle with a size of 0.4×50mm. The flow rate blows CO gas to the upstream side of the molten pool (see Table 1 for specific process parameters). The CO gas is heated and decomposed around the molten pool, and the following chemical reactions occur:

[0082] 2CO→CO 2 +[C] (1)

[0083] CO → 1 2 O 2 + [ C ] - - - ( 2 )

[0084] The active [C] atoms formed by the decomposition of CO will penetrate into the surface layer of the high-temperature melt after contacting the hi...

Embodiment 2

[0087] This embodiment chooses B 2 h 6 For gas, the specific process parameters are shown in Table 1. When the superalloy melt flows through the nozzle opening with a size of 0.4×50mm to form a molten pool, blow the gas to the downstream of the molten pool with a flow rate of 3L / min. B 2 h 6 When the gas contacts the superalloy melt, it is heated and decomposed into active boron atoms, which are dissolved into the molten steel in the molten pool, and finally form an iron-based amorphous alloy strip with a concentration gradient of B element. The change of B element content along the thickness direction of the iron-based amorphous alloy strip roll surface is as follows: image 3 As shown, it is a diagram of the variation of the composition of the iron-based amorphous alloy strip with B composition gradient along the thickness of the strip. It can be seen that the content of component B on the surface of the amorphous alloy strip is relatively high, and it is close to the eq...

Embodiment 3

[0089] This embodiment chooses NH 3 For gas, the specific process parameters are shown in Table 1. When the superalloy melt flows through the nozzle opening with a size of 0.4×50mm to form a molten pool, the gas is blown upstream of the molten pool with a flow rate of 3L / min. NH 3 When the gas contacts the superalloy melt, it is heated and decomposed into active nitrogen atoms (2NH 3 →3H 2 +2[N]), and dissolve into the molten steel in the molten pool, and finally form an iron-based amorphous alloy strip with a concentration gradient of N element. The change of N element content along the thickness direction of the iron-based amorphous alloy strip roll surface is as follows: Figure 4 As shown, it is a diagram of the change of the composition of the iron-based amorphous alloy strip with N composition gradient along the thickness of the strip. It can be seen that the content of N on the surface of the amorphous alloy strip is relatively high, and it is close to the equilibri...

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Abstract

The invention relates to the field of amorphous nanocrystalline alloy thin strip manufacturing, in particular to an amorphous alloy strip with a composition gradient and a manufacturing method thereof. Within a 0-200nm depth range from the surface to the interior of the amorphous alloy strip, content of composition gradient elements gradually reduces. The composition gradient elements are at least one of [B], [C], [N], [Si], [P] and [S]. Gas capable of being decomposed into active atoms under high temperature is decomposed into the active atoms such as [B], [C], [N], [Si], [P] and [S] under the surrounding temperature of a molten pool, and the active atoms are infiltrated into a molten body to form a concentration gradient, and the amorphous alloy strip with the composition gradient is formed after solidification. By controlling the category and concentration of injection gas, element category and depth and element content of a strip composition gradient layer can be adjusted.

Description

technical field [0001] The invention relates to an amorphous alloy strip with composition gradient and a manufacturing method thereof, belonging to the field of manufacturing amorphous nanocrystalline alloy thin strips. Background technique [0002] There are continuous changes in the content of certain elements from the surface to the interior of the gradient material, and its preparation methods can be divided into dry and wet methods, such as the method of plasma spraying on the surface of the material, electrolytic deposition, powder metallurgy, etc. Because the composition and performance of this kind of material change in a gradient, it has very important application value and has great application prospects in aerospace, nuclear industry, electronics, chemical industry, biomedicine and other fields. [0003] As a magnetic functional material, amorphous alloy strips have been widely used in the electric power and electronics industries, but the usual amorphous alloy st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22D11/06B22D11/18
Inventor 丁力栋李泉王建张志英王畅马跃
Owner ADVANCED TECHNOLOGY & MATERIALS CO LTD