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Method of preparing high-performance glass-fiber reinforced polyamide conductive composite

A conductive composite material and glass fiber technology, applied in the field of nylon composite materials, can solve the problems of limited improvement of material strength modulus, unsatisfactory effect of modified polymers, difficult dispersion of carbon nanotubes, etc., to achieve excellent mechanical properties and The effect of electrical conductivity, simple and easy preparation method, and improvement of mechanical properties

Active Publication Date: 2014-04-30
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the real potential of carbon nanotubes has not been fully reflected in the macro-scale materials, and the improvement of the strength modulus of the material is limited, which is far lower than that of traditional reinforcement materials. This is mainly due to the fact that carbon nanotubes are difficult to disperse. And the problem of poor interface bonding, so the application in the high-end field of structural parts and alternative metal materials is limited
Overall, the effect of carbon nanotube-modified polymers alone is not ideal, making the application of carbon nanotubes as a reinforcing and conductive filler limited.

Method used

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  • Method of preparing high-performance glass-fiber reinforced polyamide conductive composite
  • Method of preparing high-performance glass-fiber reinforced polyamide conductive composite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Preparation carbon nanotube concentration is 2g / L, ethylene / maleic anhydride copolymer concentration is the suspension of 1g / L, adds the glass fiber of concentration 200g / L after ultrasonic treatment, utilizes the positive charge on glass fiber surface and carbon nanotube and Electrostatic adsorption between negative charges on the surface of ethylene / maleic anhydride copolymer to obtain multidimensional hybrid reinforced glass fiber reinforcement; mix carbon nanotubes / nylon masterbatch and nylon resin evenly, and then pass through the above glass fiber reinforcement The process of extrusion molding is combined to obtain a high-performance glass fiber reinforced nylon conductive composite material, which contains 30% glass fiber reinforcement and 6.7% carbon nanotube / nylon masterbatch.

[0028] Step (1): In a 5L beaker, add 3g of ethylene / maleic anhydride copolymer and 3L of deionized water, and stir for 12 hours to obtain an aqueous solution of ethylene / maleic anhydride...

Embodiment 2

[0039] Prepare a suspension with a carbon nanotube concentration of 2g / L and an ethylene / maleic anhydride copolymer concentration of 1.5g / L, add glass fibers with a concentration of 200g / L after ultrasonic treatment, and use the positive charge on the surface of the glass fiber to interact with the carbon nanotubes. And the electrostatic adsorption between the negative charges on the surface of ethylene / maleic anhydride copolymer to obtain a multi-dimensional hybrid reinforced glass fiber reinforcement; mix carbon nanotubes / nylon masterbatch and nylon resin evenly, and then mix with the above glass fiber reinforcement Composite through the process of extrusion molding to obtain high-performance glass fiber reinforced nylon conductive composite material. The composite material contains 30% glass fiber reinforcement and 6.7% carbon nanotube / nylon masterbatch.

[0040] Step (1): In a 5L beaker, add 4.5g of ethylene / maleic anhydride copolymer and 3L of deionized water, and stir fo...

Embodiment 3

[0050] Preparation carbon nanotube concentration is 2g / L, ethylene / maleic anhydride copolymer concentration is the suspension of 2g / L, adds the glass fiber of concentration 200g / L after ultrasonic treatment, utilizes the positive charge on glass fiber surface and carbon nanotube and Electrostatic adsorption between negative charges on the surface of ethylene / maleic anhydride copolymer to obtain multidimensional hybrid reinforced glass fiber reinforcement; mix carbon nanotubes / nylon masterbatch and nylon resin evenly, and then pass through the above glass fiber reinforcement The process of extrusion molding is combined to obtain a high-performance glass fiber reinforced nylon conductive composite material, which contains 30% glass fiber reinforcement and 6.7% carbon nanotube / nylon masterbatch.

[0051] Step (1): In a 5L beaker, add 6g of ethylene / maleic anhydride copolymer and 3L of deionized water, and stir for 12 hours to obtain an aqueous solution of ethylene / maleic anhydride...

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Abstract

The invention relates to a method of preparing a high-performance glass-fiber reinforced polyamide conductive composite. The method comprises the following steps that by the role of electrostatic force between opposite charges, a carbon nano tube and an ethylene / maleic anhydride copolymer are coated on the surface of glass fiber to form a multi-fiber mixed reinforcement structure; and the carbon nano tube / nylon masterbatch and nylon resin are uniformly mixed and then are compounded with the glass fiber reinforcement through an extrusion molding process, so as to obtain a high-performance glass-fiber reinforced nylon conductive composite. The reaction steps of the method are simple, the obtained composite has a good mechanical property and a good conductivity property and can be applied to the fields of automobile industry, electron and electricity, machinery and the like, and the range of application of the glass-fiber reinforced nylon composite is widened.

Description

technical field [0001] The invention relates to a nylon composite material, in particular to a preparation method of a high-performance glass fiber reinforced polyamide conductive composite material. Background technique [0002] As the engineering plastic with the largest output and widest application range in the world, nylon has the advantages of high mechanical strength; excellent self-lubrication and wear resistance; wear resistance and chemical resistance; excellent processing performance and easy processing and molding. . Widely used in the automotive industry, electrical and electronic, machinery and other fields. [0003] As the automotive, electronic appliances, communications, machinery and other industries have increasingly strong requirements for high-performance products, it is necessary to modify nylon through certain methods to make it develop from ordinary engineering plastics to high-performance engineering plastics and functional plastics. The modificati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L77/06C08K13/06C08K9/10C08K9/06C08K7/14C08K7/00C08K3/04C08J5/08
Inventor 李春忠张玲金杰陈卫
Owner EAST CHINA UNIV OF SCI & TECH
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