Preparation method of anode pole piece of lithium iron phosphate lithium ion battery for large-capacity vehicle

A lithium-ion battery and lithium iron phosphate technology, which is applied in electrode manufacturing, battery electrodes, circuits, etc., can solve the problems of easy short circuit of the pole piece lamination, material loss of the positive electrode plate, etc., achieve good stability and improve the material loss situation Effect

Active Publication Date: 2013-04-03
上海三玖电气设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, in the prior art, there is a problem that the produced pole piece stacks are easy to short circuit after being produced due to material loss of the positive pole piece produced in the early stage.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] (1) Put 86% lithium iron phosphate, 2% conductive graphite KS-6, 3% PVDF and the balance of nitrogen methyl pyrrolidone in a stirrer according to weight percentages, vacuum and fully stir to make a slurry ;

[0036] The preparation process of the slurry is specifically as follows:

[0037] ①First, bake lithium iron phosphate, conductive agent and PVDF;

[0038] ②Add PVDF to the solvent, vacuum and stir in a stirrer at a speed of 2300 revolutions / min and 19 revolutions / min to obtain a binding liquid system;

[0039] ③Add the conductive agent to the above-mentioned bonding liquid system, and vacuum and stir at a speed of 1600 revolutions / min and 16 revolutions / min;

[0040] ④Put the lithium iron phosphate into the agitator three times, vacuum and stir at a speed of 1900 revolutions / min and 17 revolutions / min;

[0041] ⑤ Vacuum and stir at the speed of 500 revolutions / min and 7 revolutions / min, and the vacuum degree is less than -0.095Mpa;

[0042] ⑥ Use a 120 mesh sieve to filter tw...

Embodiment 2

[0048] (1) Place 92% of lithium iron phosphate, 3% of conductive graphite KS-6, 4% of PVDF and the remainder of nitrogen methyl pyrrolidone in a stirrer according to weight percentages, vacuum and fully stir to make a slurry ;

[0049] The preparation process of the slurry is specifically as follows:

[0050] ①First, bake lithium iron phosphate, conductive agent and PVDF;

[0051] ②Add PVDF to the solvent, vacuum and stir in a stirrer at a speed of 2500 revolutions / min and 21 revolutions / min to obtain a binding liquid system;

[0052] ③Add the conductive agent to the above-mentioned bonding liquid system, and vacuum and stir at a speed of 1800 revolutions / min and 18 revolutions / min;

[0053] ④Put lithium iron phosphate into the agitator three times, and vacuum and stir at a speed of 2100 revolutions / min and 19 revolutions / min;

[0054] ⑤ Vacuum and stir at the speed of 700 revolutions / min and 9 revolutions / min, and the vacuum degree is less than -0.095Mpa;

[0055] ⑥ Use a 120 mesh sieve...

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Abstract

The invention relates to a preparation method of an anode pole piece of a lithium iron phosphate lithium ion battery for a large-capacity vehicle. The preparation method comprises the following steps of: (1) placing 86-92% of lithium iron phosphate, 2-4% of a conductive agent, 3-4% of PVDF (polyvinylidene fluoride) and the residual amount of solvent according to weight percentage into a stirrer; and vacuumizing and sufficiently stirring to obtain slurry; (2) coating the slurry on an anode current collection body according to a surface density of 310-320 g/m<2>, and drying to obtain a pole piece; (3) roasting the pole piece and then rolling the pole piece to a certain thickness according to process requirements; (4) splitting the rolled pole piece by using an automatic splitting machine, so as to obtain the pole piece with a desired width; and (5) carrying out die-cutting on the split pole piece, so as to obtain the desired pole piece. The slurry prepared by the invention has good rheological property, consistency and stability; the blanking condition of the pole piece can be greatly improved; the short-circuit condition, the cycle life and the security of the battery can be greatly improved; and the preparation method provided by the invention has a good application prospect.

Description

Technical field [0001] The invention belongs to the field of preparation of lithium iron phosphate lithium ion batteries, and particularly relates to a method for preparing a large-capacity lithium iron phosphate lithium ion battery positive pole piece for automobiles. Background technique [0002] With the increasing shortage of petroleum resources and the increasingly serious environmental pollution, the harmonious development of energy, resources, environment, and human society has increasingly become the focus of social attention. It seeks to develop alternative energy sources for traditional petrochemical energy, realize the development of harmless resource industries, and seek cooperation between people and people. The harmony of the environment is particularly urgent. In modern society, people's demand for large-capacity, high-power batteries is becoming stronger, especially for electric tools, electric bicycles, motorcycles, automobile power sources and backup power batte...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/1397H01M4/04
CPCY02E60/10
Inventor 赖兴强帅鸿元
Owner 上海三玖电气设备有限公司
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