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Preparation method of intelligent temperature control glue and film

An intelligent temperature control and glue technology, which is applied in the direction of film/sheet adhesives, adhesives, non-polymer adhesive additives, etc., can solve the problems of increasing film cost, complicated process, and limited application range, etc., and achieves easy The effects of transfer use, simple preparation process and wide application range

Active Publication Date: 2013-04-10
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the commonly used methods for preparing coatings containing vanadium dioxide mainly include magnetron sputtering, chemical vapor deposition, sol-gel methods, etc. These methods all have expensive equipment, high cost, complicated process, and small film-forming area. It is not suitable for mass production and other limitations. In addition, the above method directly manufactures energy-saving glass and cannot be applied to energy-saving transformation of existing ordinary glass
Patents CN102399072A, CN102120615A, CN102464354A, and CN102336528A all mention the method of dispersing vanadium dioxide powder and coating film, but because the dispersion system used in these methods does not have good cohesiveness on the substrate, it can only be used in specific Coating on the substrate, which greatly limits its scope of use
Even coatings applied on flexible substrates still require a layer of mounting glue before they can be used, which not only increases the complexity of the film process, but also increases the cost of the film

Method used

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  • Preparation method of intelligent temperature control glue and film
  • Preparation method of intelligent temperature control glue and film
  • Preparation method of intelligent temperature control glue and film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Get 0.5g of undoped vanadium dioxide powder; VO 2 The particle size of the particles is 100nm;

[0028] (2) preparing massfraction with ethanol is the vanadium dioxide dispersion liquid of 0.5%;

[0029] (3) Add the vanadium dioxide dispersion into a certain amount of PET glue, and stir to form a temperature-controlled glue with a vanadium dioxide content of 0.01g / L;

[0030] (4) Apply the glue on the PET film to get the intelligent temperature control film.

[0031] The thermal color performance of the test coating is as follows:

[0032] figure 1 It is the high and low temperature transmission spectrum of the glue coated on the PET film. It can be seen from the figure that the highest visible light transmittance of the glue coated on the PET film is 66%, and the transmittance at 550nm is 59%, indicating that the film has good visible light transmittance. The high and low temperature transmittance difference is 31%, indicating that the film has good thermochro...

Embodiment 2

[0034] (1) Get 0.5g vanadium dioxide powder with a tungsten molar content of 0.5%; VO 2 The particle size of the particles is 20nm;

[0035] (2) prepare the vanadium dioxide dispersion liquid that mass percent concentration is 1% with hexane;

[0036] (3) Add the dispersion of vanadium dioxide into the ABS glue, and form a temperature-controlled glue with a vanadium dioxide content of 10g / L after stirring;

[0037] (4) Apply the glue on the PET film to get the intelligent temperature control film.

Embodiment 3

[0039] (1) get 0.5g tungsten content to be the vanadium dioxide powder of 1%; VO 2 The particle size of the particles is 50nm;

[0040] (2) prepare the massfraction with dimethylbenzene as the vanadium dioxide dispersion liquid of 2%;

[0041] (3) Add the dispersion of vanadium dioxide into the PVC glue, and form a temperature-controlled glue with a vanadium dioxide content of 1g / L after stirring;

[0042] (4) Apply the glue on the PVC film to get the intelligent temperature control film.

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Abstract

The invention relates to a preparation method of intelligent temperature control glue and film, comprising the following steps of: (a) dispersing R-phase or M-phase vanadium dioxide (VO2) particles with phase change function into a dispersing agent; (b) dispersing the vanadium dioxide particles dispersed in the solvent into self-bonding glue, and forming a glue with intelligent temperature control performance based on the intelligent temperature control property of the vanadium dioxide nano particles; and (c) spreading the glue with intelligent temperature control performance on a flexible base material, forming a coating based on the self-bonding property of the glue, wherein the coating can be combined with a releasing film layer without a mounting glue so as to form the intelligent temperature control film. In comparison with the conventional film, the film provided by the invention not only has the intelligent temperature control effect, but also is simplified in technology, thus, cost is lowered, and the film can be widely used in various aspects, such as energy saving for buildings, heat insulation for car windows, and surface protection.

Description

technical field [0001] The invention relates to the technology in the field of chemical engineering and materials, in particular to a method for preparing an intelligent temperature-control glue and a film. technical background [0002] In the context of increasingly severe energy supply, energy saving and consumption reduction is the common goal of people all over the world. At present, building energy consumption has been tied with industrial energy consumption and transportation energy consumption, and has become the three "big energy consumers" in my country's energy consumption. Building energy consumption accounts for about 30% of the total energy consumption of the whole society, the most important of which is heating and air conditioning, accounting for 20%. Among the four major enclosure components of a building, the heat lost through doors and windows accounts for more than 50% of the heating and air conditioning energy consumption of the entire building. Western...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/02C09J11/04
Inventor 徐刚苗蕾程浩亮肖秀娣
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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