Steam action-based metal material surface modification method and device therefor

A metal material and surface modification technology, which is applied in the direction of metal material coating process, coating, solid-state diffusion coating, etc., can solve the problems of product quality stability, process window narrowing, health and environmental safety hazards, etc. Achieve the effects of eliminating potential hazards to the ecological environment and human health, high treatment efficiency, and reduced water consumption

Inactive Publication Date: 2013-05-01
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, the existing surface modification technology of metal materials, especially the surface modification technology based on the chemical and electrochemical reactions between materials / electrolyte, has two major shortcomings: First, the traditional "immersion" mode is the main method, that is, The surface of the workpiece to be treated needs to be completely submerged in the solution to complete the reaction process; second, excessive reliance on the use of various chemicals
The biggest drawback of the traditional "immersion" model is the massive consumption of resources, especially water resources, and the subsequent surge in sewage treatment / discharge
As the volume or surface area of ​​a single workpiece increases, especially for large-volume and large-area workpieces, the above defects are more prominent
In addition, due to the influence of the solution temperature, the temperature window of the "immersion" mode is narrow (generally not higher than 100°C under normal pressure)
The main problems brought about by the addition of a large number of chemicals include: 1) The cost of raw materials increases; 2) The process, especially the optimization of the formula, is more difficult; 3) The process window is narrowed, and the requirements for the comprehensive quality of operators are increased; 4) Electrolyte 5) The composition and structure of the modified layer are complicated; 6) The stability of product quality is seriously affected; 7) The hidden dangers of health and environmental safety and their secondary hazards are significantly increased. Large; 8) Waste liquid treatment is complicated, etc.
The above problems eventually lead to a significant increase in production costs, especially social costs

Method used

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  • Steam action-based metal material surface modification method and device therefor
  • Steam action-based metal material surface modification method and device therefor
  • Steam action-based metal material surface modification method and device therefor

Examples

Experimental program
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Effect test

Embodiment 1

[0036] Taking as-cast high-purity magnesium and magnesium alloy AZ91 as the test objects, wire-cutting processed them into samples with a size of 25mm×25mm×5mm. After metallographic polishing, they were ultrasonically cleaned with absolute ethanol, and after drying, they were clamped with fixtures and fixed on the carrier. On the rod 10, the airtight reaction chamber 3 is closed. Using deionized water as feed water (raw material), start steam generator 1 to produce steam. Start the driving motor 6 to make the sample rotate at a constant speed, open the intake valve 7, and introduce the saturated steam generated by the steam generator 1 into the chamber of the reaction chamber 3 through the intake valve 7, and adjust the exhaust valve 11 and the intake valve 7 The opening degree is controlled to control the temperature of saturated steam at 150, 200 and 250°C (corresponding pressures are 0.48, 1.54 and 3.77MPa, respectively). After 1 hour, the inlet valve 7 was closed, and aft...

Embodiment 2

[0038] Except that the deionized water in the steam generator is changed into tap water, other is the same as embodiment 1. Results The surface of all samples was covered with a layer of complete, uniform, smooth and dense film.

Embodiment 3

[0040] Except that the deionized water in the steam generator is changed into distilled water, other are the same as embodiment 1. Results The surface of all samples was covered with a layer of complete, uniform, smooth and dense film.

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Abstract

The invention relates to a steam action-based metal material surface modification method and a device therefor. The steam action-based metal material surface modification method is characterized in that according to chemical characteristics of reactions between H2O and a metal material such as Al, Mg and Ti, in the presence of saturated steam or superheated steam as an interaction medium, a functional film is in-situ synthesized on the surface of a base. The steam action-based metal material surface modification method has the obvious effects of water saving, emission reduction, environmental protection and high efficiency, utilizes water as main even only raw material, and has the advantages of zero involvement and zero discharge. The device comprises a steam generator, a steam distributor, a reaction tank, a liquid storage tank, a workpiece table and a driving motor and has the advantages of safety, reliability, simple structure, and use convenience. Through the steam action-based metal material surface modification method and the device therefor, in metal material surface modification, high-level treatment effects are obtained and potential damage produced by the prior art on the ecological environment and human health is eliminated thoroughly and cleaner production is realized really.

Description

technical field [0001] The invention belongs to the technical field of material processing engineering, and in particular relates to a method and equipment for modifying the surface of metal materials based on steam action. Background technique [0002] Surface modification is one of the important application technologies of materials, which plays a huge role in saving the cost of material manufacturing, improving the service performance of materials, and expanding the application fields of materials. Taking metal materials as an example, from traditional carbon steel to modern new materials represented by magnesium, aluminum, titanium, etc., their applications are all closely related to the development of surface modification technology. [0003] However, the existing surface modification technology of metal materials, especially the surface modification technology based on the chemical and electrochemical reactions between materials / electrolyte, has two major shortcomings:...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/16
Inventor 张永君夏兰梅沈军贾书功
Owner SOUTH CHINA UNIV OF TECH
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