Nanometer noble metal/POSS hybridized polymer micro sphere and preparation method thereof
A technology for hybridizing microspheres and precious metals, which is applied in the field of nano-precious metal/POSS-containing polymer hybrid microspheres and their preparation, and achieves the effects of high catalytic efficiency, good dispersibility and controllable content.
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Embodiment 1
[0038] (1) Preparation of POSS-containing amphiphilic polymer (POSS-MA-PEG-DPA)
[0039] The 5gPOSS (5.7×10 -3 mol), 0.56g (5.7×10 -3 mol) maleic anhydride (MA), 0.028g hydroquinone and 40mL toluene were uniformly miscible, nitrogen gas was passed, and POSS-MA was separated and purified after reaction at 90°C for 24 hours; 1g (1.03×10 -5 mol) POSS-MA, 2.05g (1.03×10 -5 mol) PEG1000, 0.015g of p-toluenesulfonic acid, 0.0255g of hydroquinone and 40mL of toluene were uniformly mixed, nitrogen gas was passed, and POSS-MA-PEG1000 was obtained after reaction at 135°C for 36 hours; 2g (6.77×10 -4 mol) POSS-MA-PEG1000, 0.1711g (6.77×10 -4 mol) 2,6-pyridinedicarboxylic acid (DPA), 0.0064g p-toluenesulfonic acid, 0.0106g hydroquinone and 40mL 1,4-dioxane are uniformly miscible, separated and purified after reacting at 125°C for 36 hours Contains POSS amphiphilic polymer POSS-MA-PEG1000-DPA.
[0040] (2) Nano-noble metal / POSS-containing polymer hybrid microspheres
[0041]First, di...
Embodiment 2~4
[0045] The same process as in Example 1, changing the feeding volumes of the chloroauric acid aqueous solution and the sodium borohydride aqueous solution in (2) to 0.05mL and 0.08mL, 0.12mL and 0.18mL, and 0.15mL and 0.23mL, respectively. The results are shown in Table 1.
Embodiment 5~7
[0047] With the process of Example 1, the types of noble metal acid compounds in (2) were changed to silver nitrate, chloroplatinic acid, and chloropalladium acid to obtain different types of nano-noble metal / POSS-containing polymer hybrid microspheres, and the results are shown in Table 2. .
[0048] Table 1
[0049]
[0050] Table 2
[0051]
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