High-solid content calcium stearate lubricant for paper coating and preparation method thereof

A calcium stearate lubricant, high solid content technology, used in papermaking, textiles and papermaking, fiber raw material processing and other directions, can solve the problem that the solid content cannot meet the use requirements of high-speed paper machines, the structure design is not reasonable, and the lubrication effect is not good. and other problems, to achieve the effect of low cost, reasonable design and good lubrication effect

Active Publication Date: 2013-07-10
ZHEJIANG KESIKE CHEM NEW MATERIAL CO LTD
View PDF6 Cites 11 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above scheme has improved the complex and cumbersome manufacturing process of paper coating lubricants and the large amount of waste water to a certain extent, but the scheme still exists: the structural design is not reasonable enough, the cost is high, the rheological performance is poor, and the lubrication effect is not good. , the solid content cannot meet the requirements of high-speed paper machines, etc.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0024] The preparation method of the high solid content calcium stearate lubricant for papermaking coating comprises the following steps:

[0025] A. Calcium hydroxide is added to deionized water to prepare the first suspension. In the first suspension, the weight of calcium hydroxide accounts for 30-40% of the weight of the first suspension; adding 0.5-2% of the weight of the first suspension % emulsifier, warming up to 30-50°C, emulsifying for 30-60 minutes, and preparing a calcium hydroxide suspension for subsequent use;

[0026] B, add deionized water in stearic acid, be mixed with the second suspension, stearic acid weight accounts for 50-60% of the first suspension weight in this second suspension; Add and account for the second suspension weight 0.8-60% 2% compounded emulsifier, stirred, heated up to 80-85°C, and prepared stearic acid emulsion for subsequent use;

[0027] C. Quickly add the prepared calcium hydroxide suspension to the stearic acid emulsion. The amount ...

specific Embodiment 1

[0033] Add 53.3g of calcium hydroxide to 78g of water, add 1.3g of MOA-7 emulsifier, stir and heat up to 35°C, emulsify with high-shear emulsifier for 30 minutes, and set aside. 170.4g of water was added into a 1000ml four-necked flask equipped with a stirrer and a thermometer. Stir, add 170.4g of stearic acid, 1.12g of MOA-7, 1.6g of nonylphenol polyoxyethylene ether (10) sodium sulfate, raise the temperature to 83°C, and add the emulsified calcium hydroxide emulsion dropwise to the hard disk in about 12 minutes. In the fatty acid emulsion, the temperature of the material rises sharply during the dropping process, and the viscosity of the material increases. When the temperature of the material reaches 95-98°C, the viscosity of the material decreases after 5 minutes of reaction. When the temperature is kept above 90°C for 30 minutes, the material is a milky white uniform emulsion. Cool the material to 60°C, add 2.8g of PEG4008 and 60g of urea, stir well, cool down and dischar...

specific Embodiment 2

[0034] Add 55.5g of calcium hydroxide to 83g of water, add 2g of MOA-3 emulsifier, stir and raise the temperature to 35°C, emulsify with high-shear emulsifier for 45 minutes, and set aside. 116g of water was added into a 1000ml four-necked flask equipped with a stirrer and a thermometer. Stir, add 142g stearic acid, 1.0g MOA-3, 1.5g sodium nonylphenol polyoxyethylene ether (10) sulfonate, raise the temperature to 83°C, add the emulsified calcium hydroxide emulsion dropwise to the hard In the fatty acid emulsion, the temperature of the material rises sharply during the dropping process, and the viscosity of the material increases. When the temperature of the material reaches 95-98°C, the viscosity of the material decreases after 4 minutes of reaction. When the temperature is kept above 90°C for 30 minutes, the material is a milky white uniform emulsion. Cool the material to 60°C, add 32.3g of PEG1000 and 80g of urea, stir well, cool down and discharge. Its solid content is 62%...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the technical field of lubricants, relates to a paper coating lubricant, in particular to a high-solid content calcium stearate lubricant for a paper coating and a preparation method of the lubricant, and solves the technical problems of low solid content, poor lubrication effect, complex preparation technology and the like of the existing papermaking lubricant. The method provided by the invention comprises the following steps of: mainly emulsifying a calcium hydroxide suspension by using a non-ionic emulsifier in a high-shear emulsifying machine, emulsifying the stearic acid by using the compounded non-ionic and anionic emulsifier, dropping the calcium hydroxide suspension into the stearic acid emulsion to prepare a calcium stearate emulsion, and at last preparing the high-solid content calcium stearate lubricant for the paper coating by compounding the aqueous solution of the lubricant. The high-solid content calcium stearate lubricant for the paper coating and the preparation method of the lubricant have the advantages of reasonable design, simple technology, low cost, capability of improving the rheological property of the coating, high solid content, good lubrication effect, low viscosity, and no need of dilution during application.

Description

technical field [0001] The invention belongs to the technical field of lubricants, and relates to a paper coating lubricant, in particular to a high-solid-content calcium stearate lubricant used for paper-making coatings and a preparation method thereof. Background technique [0002] With the continuous expansion of the production scale of the domestic paper industry, the demand for coated paper continues to increase, and the speed of the coated paper machine is getting faster and faster, which makes the requirements for the lubricating performance of the coating more and more high. Adding a lubricant, the lubricant can reduce the friction coefficient of the coating, improve the rheology of the coating, and then improve the smoothness of the coating and the gloss of the finished paper. However, in order to reduce production costs, paper mills continue to increase the solid content of coatings, while the highest solid content of lubricants on the market can only reach 50%, wh...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): D21H21/14
Inventor尹传猛
OwnerZHEJIANG KESIKE CHEM NEW MATERIAL CO LTD