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Conductive particles, insulating-coated conductive particles, and anisotropic conductive adhesives

A technology of conductive particles and adhesives, applied in the direction of conductive adhesives, conductive connections, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problems of easy aggregation of particles and achieve less pinholes and low resistance value Effect

Active Publication Date: 2018-02-06
RESONAC CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is known that in the process of producing conductive particles with copper plating formed on the surface of plastic particles, the particles tend to agglomerate when electroless copper plating is being performed.

Method used

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  • Conductive particles, insulating-coated conductive particles, and anisotropic conductive adhesives
  • Conductive particles, insulating-coated conductive particles, and anisotropic conductive adhesives
  • Conductive particles, insulating-coated conductive particles, and anisotropic conductive adhesives

Examples

Experimental program
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Embodiment

[0112] Hereinafter, an Example and a comparative example are given, and the content of this invention is demonstrated more concretely. In addition, this invention is not limited to the following Examples.

[0113]

[0114] (Process a) (Pretreatment process)

[0115] 2 g of cross-linked polystyrene particles with an average particle diameter of 3.8 μm was added to 100 mL of a palladium catalyst solution containing 8% by weight of Atotech Neogant 834 (Atotech Neogant 834) (manufactured by Atotech Japan Co., Ltd., trade name) as a palladium catalyst. , was stirred at 30° C. for 30 minutes, filtered through a φ3 μm membrane filter (manufactured by Millipore Corporation), and washed with water. Thereafter, the resin particles were added to a 0.5% by weight dimethylamine borane solution adjusted to pH 6.0 to obtain resin particles with activated surfaces. Thereafter, the surface-activated resin particles were immersed in 20 mL of distilled water and ultrasonically dispersed.

...

Embodiment 2

[0133] In the plating process of the (step b) of embodiment 1, the build-up bath liquid is changed to the build-up bath liquid shown in Table 1, and the supplementary liquid A and B not containing nickel are respectively changed to 830mL, in addition, All were carried out in the same manner as in Example 1. In the same manner as in Example 1, the measurement results of the film thickness are shown in Table 2, and the measurement results of the resistance value (Ω) relative to the compressibility and the calculation results of the pinhole generation rate (%) after crushing are shown in Table 2. 5 in.

Embodiment 3

[0135] In the plating process of the (step b) of embodiment 1, the build-up bath solution is changed to the build-up bath solution shown in Table 1, and the supplementary solutions A and B not containing nickel are respectively changed to 800mL, in addition, All were carried out in the same manner as in Example 1. In the same manner as in Example 1, the measurement results of the film thickness are shown in Table 2, and the measurement results of the resistance value (Ω) relative to the compressibility and the calculation results of the pinhole generation rate (%) after crushing are shown in Table 2. 5 in.

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Abstract

The invention provides a conductive particle, an insulating coated conductive particle, and an anisotropic conductive adhesive. The conductive particle has resin particles and a metal layer arranged on surface of the resin particle, wherein the metal particle comprises nickel and copper, and has a part with a copper ratio, relative to nickel, which increases as the part becomes away from the surface of the resin particle.

Description

technical field [0001] The present invention relates to a conductive particle, an insulating-coated conductive particle, an anisotropic conductive adhesive, a connection structure of circuit components, and a method for producing the same. Background technique [0002] The methods of mounting liquid crystal driving ICs on glass panels for liquid crystal displays can be roughly divided into COG (Chip-on-Glass) mounting and COF (Chip-on-Flex) mounting. In COG mounting, ICs for liquid crystals are directly bonded to glass panels using anisotropic conductive adhesives. On the other hand, in COF mounting, ICs for driving liquid crystals are bonded to a flexible tape having metal wiring, and these are bonded to a glass panel using an anisotropic conductive adhesive. The term "anisotropy" as used herein means conduction in the pressurized direction and insulation in the non-pressurized direction. [0003] Conventionally, as an anisotropic conductive adhesive, an adhesive containi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J11/04C09J9/02H01B5/14H01B1/02H01R4/04H05K3/32
CPCC09J9/02C23C18/1651C23C18/1683C23C18/50H01B1/026H01B1/22H01R4/04H01R11/01
Inventor 江尻芳则中川昌之高井健次赤井邦彦渡边靖榎本奈奈松泽光晴山村泰三
Owner RESONAC CORPORATION