Reactive dye salt-free dyeing method

A reactive dye and salt-free dyeing technology, applied in dyeing, textiles and papermaking, etc., can solve the problems of cationic reagent level dyeing and penetrability decrease, increase the amount and cost of dye, and it is difficult to enter the fiber, etc., to achieve Industrial promotion is easy to implement, improves dyeing rate and color fixation rate, and has the effect of simple process

Inactive Publication Date: 2013-08-14
DONGHUA UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Low-salt reactive dyes mainly improve the affinity of dyes and fibers by increasing the molecular weight and coplanarity of dyes, reducing the number of sulfonic acid groups, and introducing cationic groups to reduce the amount of salt. The problem with this method is that it is necessary to develop new types of dyes , The chromatogram is not easy to match, it is easy to dye unevenly, and it will increase the amount and cost of dyes
Substitute salts include sodium formate, potassium phthalate, EDTA, sodium citrate, polycarboxylate sodium salt, etc. The main problem is that it will increase the cost of dyeing,

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] In a 50mL beaker, add 10mL of 4g / L Reactive Brilliant Red M-3BE (CI Reactive Red 195) aqueous solution, 2g of pre-swollen cotton fabric with a liquid rate of 70%, and heat at 3℃ / min to 40℃ and keep it for 20min, then add 20mL After ethanol is heated to 60°C at 2°C / min and kept for 10 minutes, add 2mL of 100g / L soda ash and then heat up to 78°C at 1°C / min and keep for 60 minutes. Take out the fabric, wash, soap, and wash to get cotton fabric dyed Finished product. The dye uptake rate can reach 97%, and the fixation rate is 85%.

Embodiment 2

[0025] Add 20mL2g / L Reactive Turquoise Blue KM-GB (CI Reactive Blue 231) in a 50mL Erlenmeyer flask, the solvent is water with a volume ratio of 1:1 and a solution of ethyl acetate-acetone (volume ratio of 1:1) and 2g of pre-swollen cotton fabric with 80% liquid rate, heated at 3℃ / min to 50℃ and kept for 10min, add 10mL of ethyl acetate-acetone co-solvent with a volume ratio of 1:1 and heated to 60℃ at 2℃ / min And keep the temperature for 20min, add 0.2g of soda ash, heat it to reflux state at 1℃ / min and keep it for 60min, take out the fabric, wash, soap and wash to get cotton fabric dyed finished product. The dye uptake rate is 93%, and the fixation rate is 80%.

Embodiment 3

[0027] In a 50mL beaker, add 10mL4g / L Reactive Black KN-B (CI Reactive Black 5), a solution of water and isopropanol with a volume ratio of 3:2, and 2g of pre-swollen cotton fabric with a liquid rate of 100%. 3°C / min to 60°C and keep for 10min, add 10mL isopropanol, then increase to 80°C at 2°C / min and keep for 15min, add 2mL100g / L soda ash, then increase to 100°C at 1°C / min and keep for 30min, The fabric is taken out, washed, soaped, and washed to obtain a finished cotton fabric dyed. The dye uptake rate is 97%, and the fixation rate is 83%.

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Abstract

The invention relates to a reactive dye salt-free dyeing method which comprises the following steps of: soaking pre-swelled cotton fabric into reactive dye liquor, heating up to a primary dyeing temperature of 40-100 DEG C and keeping the temperature for 0-20 minutes, adding an organic solvent, heating up to a dyeing temperature of 60-100 DEG C and keeping the temperature for 0-20 minutes, adding soda ash, heating up to a fixation temperature of 40-100 DEG C and keeping the temperature for 30-60 minutes, cooling to room temperature, and carrying out washing, soaping and washing on the cotton fabric. The method is simple and easy to industrialize, is capable of obtaining dye-uptake and fixation rate higher than a traditional reactive dye dyeing process, has relatively good leveling property and is capable of realizing salt-free low-alkaline dyeing.

Description

Technical field [0001] The invention belongs to the field of reactive dye dyeing, and particularly relates to a reactive dye salt-free dyeing method. Background technique [0002] Reactive dyes have bright colors, complete chromatograms, and excellent wet processing fastness. They are the most important type of dyes for cellulose fiber dyeing. However, in order to improve the dye uptake and fixation rate, a large amount of inorganic salts are often used during the dyeing process. Salt is difficult to remove through simple physical, chemical and biochemical treatments, which brings a great burden to the environment. At present, the development of low-salt and salt-free reactive dyes is mainly centered on the synthesis of new dyes, the research and development of dyeing auxiliaries, fiber modification and the formulation of reasonable low-salt dyeing processes. [0003] Low-salt reactive dyes mainly reduce the amount of salt by increasing the molecular weight and coplanarity of the ...

Claims

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Application Information

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IPC IPC(8): D06P1/90D06P1/38D06P3/66D06P5/02
Inventor 何瑾馨杭彩云董霞周浩
Owner DONGHUA UNIV
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