Adhesive-layer-quipped transparent surface material, display device, and methods for producing same
A technology for a display device and an adhesive layer, which is applied in the directions of lamination devices, adhesive products, identification devices, etc., can solve the problems of complicated lamination of display panels and protective plates, and achieve the effect of not easy to leave gaps and easy lamination.
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[0314] In the following, an example of implementation will be shown to confirm the effectiveness of the present invention, but it should not be construed as being limited thereto.
[0315] (number average molecular weight)
[0316] The number average molecular weight of the oligomer was calculated as the number average molecular weight in terms of polystyrene using a GPC (gel permeation chromatography) measuring device (manufactured by Tosoh Corporation, HLC-8020).
[0317] (viscosity)
[0318] The viscosity of the photocurable resin composition was measured with an E-type viscometer (manufactured by Toki Sangyo Co., Ltd. (Toki Sangyo Co., Ltd.), RE-85U).
[0319] (haze value)
[0320] The haze value was measured according to ASTM D1003 using Haze-gard II manufactured by Toyo Seiki Seisakusho Co., Ltd. (Toyo Seiki Seisakusho Co., Ltd.).
[0321] (shear modulus of elasticity)
[0322] The shear elastic modulus of the layered part of the adhesive layer after curing was measu...
example 1~20
[0325] (transparent surface material)
[0326]On the periphery of one surface of soda lime glass with a length of 100 mm, a width of 100 mm, and a thickness of 3 mm, a black-pigmented ceramic printing is used to form a light-shielding printed part in the shape of a picture frame, so that the length of the light-transmitting part is 68 mm and the width is 68mm. Next, an antireflection film (REALOOK X4001 manufactured by NOF Corporation (NOF Corporation)) was bonded to the entire back surface of the light-shielding printed part in a state where the protective film was attached to prepare a protective sheet A.
[0327] (support surface material)
[0328] On one side of a transparent plate made of soda lime glass with a length of 100 mm, a width of 100 mm, and a thickness of 3 mm, a protective film with a length of 130 mm, a width of 130 mm, and a thickness of 0.075 mm was attached with a rubber roller so that the adhesive surface of the protective film was in contact with the gl...
example 1~7
[0336] (Photocurable resin composition for layered portion formation)
[0337] By mixing bifunctional polypropylene glycol (number-average molecular weight calculated from hydroxyl value: 4000) and isophorone diisocyanate in a molar ratio of 4 to 5 with molecular terminals modified by ethylene oxide, in the presence of a tin compound catalyst In the presence of a reaction at 70°C, 2-hydroxyethyl acrylate was added to the resulting prepolymer at a molar ratio of approximately 1:2 and reacted at 70°C to obtain a urethane acrylate oligomer object (hereinafter referred to as UA-1). UA-1 has two curable groups, a number average molecular weight of about 24,000, and a viscosity of about 830 Pa·s at 25°C.
[0338] 40 parts by mass of UA-1, 30 parts by mass of 2-hydroxybutyl methacrylate (manufactured by Kyoeisha Chemical Co., Ltd., Light Ester HOB), and 30 parts by mass of n-dodecyl methacrylate were uniformly Mixed, 0.5 mass parts of bis (2,4,6-trimethylbenzoyl) phenyl phosphine o...
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