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Surface treatment method of glass flakes for flake resin paint and flake resin paint

A technology for glass flakes and flake resin, which is applied to the surface treatment of glass flakes for flake resin coatings, and the field of flake resin coatings, which can solve problems such as limited effect and so on.

Active Publication Date: 2015-08-19
NINGBO DADA CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the effect of the above method is limited, because the glass flakes are stacked on each other in the flake resin coating, and it is inevitable to form gaps, which provide favorable channels for water molecules to infiltrate.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] In this embodiment, a coupling agent is used to pretreat the surface of the glass flakes. The coupling agent is composed of a coupling agent A and a coupling agent B, the coupling agent A is vinyltrialkoxysilane, and the coupling agent B is n-dodecyltrichlorosilane. The specific process is as follows:

[0040] (1) Add coupling agent A to the ethanol solution and mix evenly to form a treatment solution A with a mass percentage concentration of 8%; add coupling agent B to the ethanol solution and mix evenly to form a treatment solution with a mass percentage concentration of 8%. Liquid B;

[0041] (2) Mix perchloric acid and concentrated nitric acid according to the mass ratio of perchloric acid: concentrated nitric acid = 1:1, dilute with deionized water to a concentration of 20% to 60% and stir evenly to form an acid solution. Immerse the glass scales in The acid solution was cleaned and treated for 2 hours, filtered and washed with a large amount of deionized water, ...

Embodiment 2

[0058] In this embodiment, a coupling agent is used to pretreat the surface of the glass flakes. The coupling agent is composed of a coupling agent A and a coupling agent B, the coupling agent A is γ-glycidyl etheroxypropyltrialkoxysilane, and the coupling agent B is octadecyltrichlorosilane. The specific process is as follows:

[0059] (1) Add 1mL of coupling agent A and 1mL of coupling agent B to 120mL of butyl ether solution in turn, mix well to form a mixed treatment solution;

[0060] (2) Mix concentrated sulfuric acid, concentrated nitric acid and water according to the mass ratio of concentrated sulfuric acid: concentrated nitric acid: water = 2:1:2, stir evenly to form an acid solution, and immerse the glass scales in the acid solution for cleaning treatment for 2 hours. After filtering, wash with a large amount of deionized water, then blow dry with nitrogen or put it in a 60-degree oven to dry;

[0061] (3) Slowly pour the mixed treatment solution prepared in step ...

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Abstract

The invention provides a method for the surface functionalization treatment of a glass flake. The method adopts two silane coupling agents to carry out dual modification treatment on the surface of the glass flake so that the surface of the glass flake simultaneously contains a hydrophilic group and a hydrophobic group, wherein one of the silane coupling agents is a short-carbon chain silane coupling agent which contains a reactive group, and the other one of the silane coupling agents is a silane coupling agent with long-carbon chain hydrophobic property. Experiments prove that on the one hand, the method provided by the invention enlarges the binding force between the glass flake and a resin base body and enhances the compactness of a flake resin coating, and on the other hand, the method provided by the invention has capillary hydrophobic effect by forming a gap between mutually superposed glass flakes, thereby effectively preventing the permeation of water molecules. Thus, the flake resin coating formed by the glass flake modified by utilizing the method is greatly reduced in water absorption and effectively enhanced in anti-corrosion property and permeation resistant property and has good application prospect in the field of heavy anti-corrosion, such as the anti-corrosion of a chimney with a flue gas desulfurization device, the anti-corrosion of a petrochemical industrial pipeline, the anti-corrosion of ocean, and the like.

Description

technical field [0001] The invention belongs to the technical field of anti-corrosion coatings, and in particular relates to a surface treatment method for glass flakes used in flake resin coatings and a scale resin coating prepared by using the glass flakes. Background technique [0002] my country is a country whose energy structure is dominated by coal combustion, and air pollution is mainly caused by soot, dust, sulfide, nitrogen oxides and other pollution. As the world pays more and more attention to environmental protection, as early as the 1980s, many countries in Europe have mandated the use of desulfurization devices (FGD) in combustion power plants. my country also started thermal power desulfurization projects at the end of the 20th century. Therefore, this The 10-20 years at the beginning of the century will be a critical period for the desulfurization of thermal power plants in my country. [0003] At present, thermal power desulfurization mostly adopts wet trea...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C23/00C09D5/08C09D7/12C09D201/02
Inventor 张昕丁示波乌学东李红良李群杨群燕刘谦唐燕凤陈旭杰
Owner NINGBO DADA CHEM CO LTD