Modification filling material and preparation method thereof, and slurry adopting modification filling material
A modified and dry-quality technology, applied in the direction of fibrous fillers, chemical instruments and methods, inorganic pigment treatment, etc., can solve the problems of paper becoming brittle, paper tearing, etc., to increase the binding force and improve the cleanliness , Improve the effect of retention and filtration
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[0024] The preparation method of this modified filler, it comprises the steps:
[0025] (1) Prepare filler suspension.
[0026] Take a certain amount of filler main agent and add water to prepare a filler suspension with a concentration of 15%-60% by mass. The filler main agent is one or more of diatomite, zeolite, bentonite, talc, calcium carbonate, kaolin, sericite, natural calcium metasilicate, gypsum, barite and pyrophyllite.
[0027] (2) Add carboxymethyl cellulose.
[0028] Add carboxymethyl cellulose with an absolute dry mass of 0.5%-1% of the dry mass of the filler main agent to the above filler suspension, and mix well. The carboxymethylcellulose is preferably added as a solution.
[0029] (3) Add charge neutralizer.
[0030] Add a charge neutralizer with a mass of 0.2%-0.4% of the dry weight of the filler main agent to the above filler suspension, and mix well. Preferably, the charge neutralizer is added under a stirring state of 300-1000 rpm. The charge neutra...
Embodiment 1
[0035] Preparation of modified filler: take the dispersed suspension containing 100 g of dry ground GCC, the mass percent concentration of the suspension is 18%, add 50 g of carboxymethyl cellulose solution with a mass percent concentration of 1%, Stir well to disperse evenly, then add 0.2g of PAC to it under stirring, after stirring for 10 minutes, add 10g of amphoteric polyacrylamide solution with a mass percent concentration of 0.5%, and stir for 20 minutes to obtain a modified filler with a particle size of 35-40μm.
[0036] Preparation of pulp: Take softwood bleached kraft pulp (freeness is 380ml), hardwood bleached kraft pulp (freeness is 400ml) and alkaline hydrogen peroxide mechanical pulp (freeness is 250ml) according to 20%: 60% : 20% ratio is mixed to obtain a mixed slurry, and the mass percentage concentration of the mixed slurry is 1%. Take 2000g of mixed slurry, add 39.5g of the above-mentioned modified filler under stirring, add 5g of cationic polyacrylamide re...
Embodiment 2
[0038] Preparation of modified filler: take the dispersed suspension containing 100 g of dry ground GCC, the mass percent concentration of the suspension is 18%, add 100 g of carboxymethyl cellulose solution with a mass percent concentration of 1%, Stir well to disperse evenly, then add 0.4g of PAC to it under stirring, and after stirring for 10 minutes, add 5g of polyamide-epichlorohydrin resin solution with a concentration of 10% by mass, and stir for 20 minutes to obtain a modified filler The particle size is 20-25μm.
[0039] Preparation of slurry: prepared by referring to the method in Example 1, wherein the mass of the modified filler prepared in Example 2 was 39.7 g.
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