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Solar selective absorbing coating and preparation method thereof

An absorption coating and selective technology, applied in solar thermal power generation, coatings, solar thermal devices, etc., can solve the problems of poor thermal stability, low operating temperature, complex preparation process, etc., to achieve good thermal stability, selective absorption good effect

Inactive Publication Date: 2013-11-13
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The purpose of the present invention is to overcome the defects of existing solar selective absorbing coatings with complex preparation process, low service temperature and poor thermal stability, and provide a solar selective absorbing coating with simple preparation process and good comprehensive heat absorption effect and its preparation method

Method used

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  • Solar selective absorbing coating and preparation method thereof

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Effect test

preparation example Construction

[0049] Preparation of solar selective absorbing coating of the present invention

[0050] Copper sheet was used as the base material, ultrasonically cleaned with metal cleaning agent for 15 minutes, then rinsed with water, then ultrasonically cleaned with ethanol and acetone for 15 minutes, dried and placed in the tungsten target sputtering chamber of the sputtering equipment chamber.

[0051] Use mechanical pump and molecular pump to vacuumize the chamber, when the vacuum degree of the chamber reaches 7×10 -4 Finally, high-purity argon gas is introduced into the chamber, and the target is pre-sputtered with high-purity argon gas for 5 minutes before sputtering. The tungsten target is used, the sputtering pressure is 0.05Pa-3Pa, and the sputtering power is 50W- 150W, sputtering time is 5-15 minutes, forming a tungsten film on the substrate.

[0052] Close the argon valve, evacuate the chamber, and feed high-purity argon and high-purity oxygen into the chamber; the ratio of ar...

Embodiment 1

[0056] Copper sheet was used as the base material, ultrasonically cleaned with metal cleaning agent for 15 minutes, then rinsed with water, then ultrasonically cleaned with ethanol and acetone for 15 minutes, dried and placed in the tungsten target sputtering chamber of the sputtering equipment chamber.

[0057] Use mechanical pump and molecular pump to vacuumize the chamber, when the vacuum degree of the chamber reaches 7×10 -4 Finally, high-purity argon gas was introduced into the chamber, and the target was pre-sputtered with high-purity argon gas for 5 minutes before sputtering. Using a tungsten target, the sputtering pressure was 0.5Pa, and the sputtering power was 80W. The time is 8 minutes, and a tungsten thin film, that is, an infrared reflection layer, is formed on the substrate.

[0058] Close the argon valve, vacuumize the chamber, and feed high-purity argon and high-purity oxygen into the chamber; the argon flow rate is 30 sccm, the oxygen flow rate is 6 sccm, the ...

Embodiment 2

[0063] Copper sheet was used as the base material, ultrasonically cleaned with metal cleaning agent for 15 minutes, then rinsed with water, then ultrasonically cleaned with ethanol and acetone for 15 minutes, dried and placed in the tungsten target sputtering chamber of the sputtering equipment chamber.

[0064] Use mechanical pump and molecular pump to vacuumize the chamber, when the vacuum degree of the chamber reaches 7×10 -4 Afterwards, high-purity argon gas was introduced into the chamber, and the target was pre-sputtered with high-purity argon gas for 5 minutes before sputtering. Using a tungsten target, the sputtering pressure was 3Pa, the sputtering power was 50W, and the sputtering time was For 5 minutes, a tungsten thin film, that is, an infrared reflective layer, is formed on the substrate.

[0065] Close the argon gas valve, evacuate the chamber, and feed high-purity argon and high-purity oxygen into the chamber; the argon flow rate is 40 sccm, the oxygen flow rate...

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Abstract

The invention relates to a solar selective absorbing coating, which sequentially comprises a substrate layer, an infrared reflection layer, a first absorption layer, a second absorption layer and a reflection reducing layer from bottom to top, and is characterized in that the infrared reflection layer is a tungsten thin film layer, the first absorption layer adopts a film made of tungsten and tungsten oxide and has high tungsten content, the second absorption layer adopts a film made of tungsten and tungsten oxide and has low tungsten content, and the reflection reducing layer is an Al2O3 thin film layer. The coating has better heat stability, can be applied to a heat absorbing body of a flat plate solar collector, and is good in selective heat absorbing effect. The structure and the process method of the coating are both simpler, the preparation time is short, the controllability is good, the production cost is low, and the coating is available for industrial production.

Description

technical field [0001] The invention belongs to the field of solar photothermal application materials, and in particular relates to a solar selective absorption coating and a preparation method thereof. Background technique [0002] The energy problem is one of the most prominent problems facing the world at present, and solar energy has become a research hotspot because of its remarkable advantages such as continuous supply, safety and cleanliness. Among them, photothermal conversion technology is the key technology in solar thermal utilization. In the research and utilization of solar light-to-heat conversion, the technology of solar spectrum selective absorption materials, especially the technology of solar selective absorption coating is an extremely important key technology in the research of solar collectors, and it is also the key to improve the efficiency of light-to-heat conversion. important research direction. [0003] Solar selective absorbing coatings can be r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F24J2/48B32B9/04B32B15/04C23C14/35
CPCY02E10/40F24S70/25F24S70/225
Inventor 宫建红王凯陈巧玲张修齐
Owner SHANDONG UNIV