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Flotation method for micro-fine particle complicated jamesonite

A brittle sulphur antimony lead ore and fine particle technology is applied in the flotation field of lead antimony ore, which can solve the problems of easy adsorption of chemicals, influence on the recovery of brittle sulphur antimony lead ore, low lead and antimony lead ore recovery rate, etc. Concentrate grade, flotation process is simple and practical, and the effect of improving concentrate grade

Active Publication Date: 2013-12-11
广西华锡矿业有限公司铜坑矿业分公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The lead-antimony coarse concentrate has a high carbon content of 8.45%. Carbon is very easy to adsorb chemicals and cover the mineral surface to hinder the action of minerals and chemicals, resulting in large consumption of chemicals and low recovery rate and grade of lead and antimony.
[0008] (3) The process fails to achieve effective separation of ore and mud
[0009] Due to the influence of the main process and equipment factors, the brittle antimony lead ore has serious sliming, and the -10μm particle size exceeds 40%, so it is impossible to remove the slime through conventional gravity separation and desliming measures
In flotation, the finer the particle size, the smaller the difference in buoyancy between the ore and the gangue, and the ore mud gangue is easy to absorb chemicals due to its large specific surface area and is easy to cover the mineral surface to hinder the action of minerals and chemicals, thus affecting Brittle pyrotite recovery
In production, the method of reducing the concentrate yield can only be adopted to ensure the quality of the concentrate, but this method leads to a low recovery rate of lead and antimony
[0010] (4) The process fails to achieve effective separation of lead and antimony from other sulfide ores
This method has improved the concentrate grade of brittle pyrotite to a certain extent, but there are still some deficiencies, such as under weakly alkaline conditions, although iron-containing minerals such as pyrite and pyrrhotite are suppressed, the same It also has a certain inhibitory effect on brittle styrofoam and lead ore, and at the same time accelerates the hydrolysis of ethionyl nitrogen, so the recovery rate of lead and antimony is low, the yield of lead and antimony concentrate is low, and the loss of lead and antimony metal in tailings is relatively large

Method used

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  • Flotation method for micro-fine particle complicated jamesonite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Such as figure 1As shown, a kind of flotation method of fine-grained and complex brittle pyrostibite includes carbon-lead separation, lead slime separation, and lead-sulfur separation; it is characterized in that: the recovery process of the method includes the following steps:

[0042] (1) Add 2# oil to the carbon-lead separation roughing tank to carry out carbon-lead separation and roughing for the raw ore liquid, and then the ore liquid flows out in two ways, and the ore liquid with high carbon concentrate content flows into the carbon-lead separation and concentration pool, and the other All the way, the ore liquid with high lead ore content flows into the lead slime separation rougher;

[0043] (2) Sodium carbonate and collectors are added to the lead slime separation roughing tank to conduct lead slime separation and roughing for the ore liquid with high lead ore content, and then the ore liquid flows out in two ways, and the ore liquid with high lead and sulfur c...

Embodiment 2

[0054] The difference between this embodiment and Example 1 is: the addition of 2# oil in the step (1) is 13g / t; the addition of sodium carbonate in the step (2) is 40g / t, and the amount of collector The addition amount is 70g / t; the addition amount of the pH regulator in the step (3) is 450g / t, the addition amount of the zinc inhibitor is 300g / t, and the addition amount of the collector is 50g / t; The amount of collector added to the separation and scavenging pool is 15g / t; in the step (4), the amount of collector added to the first-stage purification pool is 40g / t, and zinc is added to the first-stage scavenging pool The amount of inhibitor is 40g / t, and the amount of collector added in the primary sweep pool is 15g / t; the amount of zinc inhibitor added in the secondary sweep pool in the step (5) is 40g / t t, the amount of collector added in the secondary sweep pool is 15g / t.

Embodiment 3

[0056] The difference between this embodiment and Example 1 is: the addition of 2# oil in the step (1) is 18g / t; the addition of sodium carbonate in the step (2) is 60g / t, and the amount of collector The addition amount is 90g / t; the addition amount of the pH regulator in the step (3) is 550g / t, the addition amount of the zinc inhibitor is 400g / t, and the addition amount of the collector is 70g / t; The amount of collector added to the separation and scavenging pool is 25g / t; in the step (4), the amount of collector added to the first-stage purification pool is 60g / t, and zinc is added to the first-stage scavenging pool The amount of inhibitor is 60g / t, and the amount of collector added in the primary sweep pool is 25g / t; the amount of zinc inhibitor added in the secondary sweep pool in the step (5) is 60g / t t, the amount of collector added to the secondary sweep pool is 25g / t.

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Abstract

The invention discloses a flotation method for micro-fine particle complicated jamesonite. The flotation method comprises the steps of carbon-lead separation, lead-mud separation, lead-sulfur separation and the like; sulfuric acid is used as a pH regulator; a mixture of sodium carbonate, zinc sulfate and sodium sulfite is used as a zinc inhibitor; a mixture of ammonium dibutyl dithiophosphate and sodium butyl xanthogenate is used as a collector. The flotation method has simple and practical technology, and a small amount of medicament is used; the production is performed under weak-acid condition, and the recovery rate and concentrate grade of the jamesonite are improved.

Description

technical field [0001] The invention belongs to the technical field of mineral processing, and relates to a flotation method of lead-antimony ore. Background technique [0002] Brittle pyrotite is a special type of mineral, its main feature is that it is dispersed in zinc-sulfur and other polymetallic deposits, it is brittle and muddy, and it is closely symbiotic with carbon in the minerals, and the lead-antimony coarse concentrate The particle size is extremely fine, so it is extremely difficult to separate the minerals by gravity separation, and it is also impossible to remove the fine-grained gangue by grading desliming. In the normal mineral processing process, it is very easy to be lost in the overflow through the floating state, and it is difficult to recover; If it is not recycled, it will seriously interfere with the recovery of other minerals and destroy the overall beneficiation process because of its strong adsorption to chemicals. [0003] At present, the recove...

Claims

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Application Information

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IPC IPC(8): B03D1/00
Inventor 吴伯增陈建明余忠保梁增永王万忠黄承波胡明振张甦张佳宇孙翊州吴其聪朱文涛
Owner 广西华锡矿业有限公司铜坑矿业分公司
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