In situ repair agent for sediments contaminated by polycyclic aromatic hydrocarbon compounds and repair method thereof
An in-situ remediation agent and polycyclic aromatic hydrocarbon technology, which is applied in water pollutants, chemical instruments and methods, biological sludge treatment, etc., can solve the problem of lack of microbial electron acceptor concentration, low dissolved oxygen concentration, and the impact of PAHs biodegradation Efficiency and other issues, to achieve the effects of low cost of treatment, broad application prospects, increased abundance and degradation activity
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Embodiment 1
[0012] Example 1: In-situ restoration of a black and smelly river sediment in Foshan City, Guangdong Province
[0013] Sixteen kinds of PAHs prioritized by the U.S. Environmental Protection Agency (EPA), namely naphthalene (Nap), acenaphthylene (Acy), acenaphthylene ( Ace), fluorene (Flu), phenanthrene (Phe), anthracene (Ant), fluoranthene (Fla), pyrene (Pyr), benzo[a]anthracene (Baa), lettuce (Chr), benzo[b]fluorine Anthracene (Bbf), benzo[ik]fluoranthene (Bkf), benzo[a]pyrene (Bap), indeno(1,2,3-cd)pyrene [In(1,2,3-cd)p ], dibenzo(a,h)anthracene [D(a,h)a], benzo(g,h,i)perylene (perylene) [B(g,h,i)p]. The total content of PAHs in the sediments of these two monitoring points was more than 2000μg / kg, of which 2# was 2589.366μg / kg, and 3# was 3187.358μg / kg, which was quite serious.
[0014] Ca(NO 3 ) 2 4H 2 O, C 6 h 5 o 7 Fe·5H 2 O, polyacrylamide and water are uniformly mixed according to the mass ratio of 100:200:1:2000 to obtain an in-situ restoration agent for polyc...
Embodiment 2
[0018] Example 2: In-situ restoration of a black and odorous river sediment in Shanghai
[0019] Sixteen PAHs prioritized by the U.S. Environmental Protection Agency (EPA) were detected in a black and odorous river sediment in Shanghai, with an average total PAHs content of 1800.345 μg / kg. Mainly ik]fluoranthene, benzo[a]pyrene, indeno(1,2,3-cd)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene]arene.
[0020] Ca(NO 3 ) 2 4H 2 O, C 6 h 5 o 7 Fe·5H 2 O, polyacrylamide and water are uniformly mixed according to the mass ratio of 1000:2000:10:100 to obtain an in-situ remediation agent for polycyclic aromatic hydrocarbon compound polluted deposits.
[0021] In every cubic meter of sediment, 5L of in-situ remediation agent for polycyclic aromatic hydrocarbons polluted sediment is injected each time, divided into five parts and injected at 40cm below the surface of the mud layer, and injected once a month. The removal rate of PAHs in the material reached 88.3%.
[0022] W...
Embodiment 3
[0024] Example 3: In-situ restoration of a black and odorous river sediment in Guangzhou
[0025] Sixteen PAHs prioritized by the U.S. Environmental Protection Agency (EPA) were detected in a black and odorous river sediment in Guangzhou, with an average total PAHs content of 2830.215 μg / kg. ) mainly aromatics.
[0026] Ca(NO 3 ) 2 4H 2 O, C 6 h 5 o 7 Fe·5H 2 O, polyacrylamide and water are uniformly mixed according to the mass ratio of 100:180:1:190 to obtain an in-situ remediation agent for polycyclic aromatic hydrocarbon compound polluted deposits.
[0027] In every cubic meter of sediment, 2.5L of in-situ remediation agent for polycyclic aromatic hydrocarbons polluted sediment is injected each time, divided into five parts and injected at 40cm below the surface of the mud layer, injected once a month, after two months of treatment, The removal rate of PAHs in sediment reached 95.3%.
[0028]When the total content of PAHs is lower than 200 μg / kg, inject 0.5 L of in...
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