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A batch manufacturing method and equipment for ultra-fine magnesium wire

A manufacturing method and technology for manufacturing equipment, applied in the field of metal materials, can solve the problems of high cytotoxicity, increase the risk of oxidation defects, reduce the processing efficiency of magnesium metal wire, etc., achieve high mechanical strength, meet the requirements of purity and stability, corrosion resistance Degradation is uniform and controllable

Active Publication Date: 2016-05-11
CHANGSHU MICROTUBE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] China Invention Patent Application No. 200910001699.2 discloses a magnesium-based alloy wire. In order to improve the mechanical properties of the magnesium wire, 0.1-12.0% Al and 0.1-1.0% Mn are added in this patent. Al has high cytotoxicity and cannot meet the requirements of medical magnesium. The biocompatibility requirements of the wire, and its manufacturing process is the same as the traditional processing method, requiring multi-step drawing and intermediate multi-pass annealing treatment, which greatly reduces the processing efficiency of magnesium metal wire and increases the risk of oxidation defect formation
[0007] Chinese patent application number 201220166881.0 discloses an annealing control device for a continuous annealing large drawing machine. This patent mainly anneals the processed material by changing its direct current. There is no protective gas to protect the material during the drawing process. Manufacturing During the process, the material contacts and reacts with oxygen and moisture in the air, resulting in adverse consequences such as oxidation or pitting corrosion
In this regard, there is no public report in the prior art

Method used

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  • A batch manufacturing method and equipment for ultra-fine magnesium wire
  • A batch manufacturing method and equipment for ultra-fine magnesium wire

Examples

Experimental program
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Embodiment 1

[0048] Such as Figure 1-2 As shown, the pure magnesium wire (magnesium content above 99.99%) with a length of 20m and a diameter of 1.5mm is drawn according to the technical solution provided by the present invention, and the single-pass deformation is controlled at 2%-3%. Helium is used as an inert protective gas, and the protective gas is heated to 180°C to 200°C to perform low-temperature stress relief annealing on the drawn and deformed magnesium wire.

[0049] In this embodiment: the magnesium wire with a diameter of 1.5 mm is drawn through the first drawing die with an outer diameter of 40 mm and an inner diameter of 1.47 mm, and the drawn magnesium wire is annealed at a low temperature of 190° C. The drawing power is provided by the power wheel, and the drawing and low-temperature annealing are repeated many times, and the magnesium wire with a diameter of 0.15mm is processed to the required specification, and the length of the magnesium wire is increased to 2000m. Fin...

Embodiment 2

[0052] The pure magnesium wire with a length of 50m and a diameter of 1.0mm is drawn according to the technical scheme provided by the present invention, and the amount of deformation in a single pass is controlled at 1%-2%, using argon as an inert protective gas, and The shielding gas is heated to 160°-180° to perform low-temperature annealing on the drawn and deformed wire.

[0053] In this embodiment: the magnesium wire with a diameter of 1.0 mm is drawn through the first drawing die with an outer diameter of 30 mm and an inner diameter of 0.99 mm, and the drawn magnesium wire is annealed at a low temperature of 170° C. The drawing power is provided by the power wheel. After repeated drawing and low-temperature annealing for many times, it is processed to the required specification of 0.06mm and the length is 13800m. Finally, the degradable polymer coating solution is used as the anti-corrosion coating solution to treat the magnesium wire. After coating treatment and storag...

Embodiment 3

[0056] The pure magnesium wire that is 30m in length and 2.0mm in diameter is drawn according to the technical scheme provided by the present invention, and the single-pass deformation is controlled at 3%-4%, using krypton as an inert protective gas, and The shielding gas is heated to 220°-250° to perform low-temperature annealing on the drawn and deformed wire, and undergoes multiple drawing and low-temperature annealing.

[0057] In this embodiment: the magnesium wire with a diameter of 2.0 mm is drawn through the first drawing die with an outer diameter of 50 mm and an inner diameter of 1.96 mm, and the drawn magnesium wire is annealed at a low temperature of 230° C. The drawing power is provided by the power wheel, and after repeated drawing and low-temperature annealing for many times, it is processed to the required specification of 0.1mm and the length is 12000m. Finally, the Ca-P coating solution is used as the anti-corrosion coating solution to coat the magnesium wire....

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Abstract

The invention provides a method and equipment for batch manufacturing of superfine magnesium wires. The method comprises the following steps: changing original large diameters of pure magnesium wires into required small diameters through multi-step continuous drawing; performing annealing treatment of in-situ injection on the magnesium wires by heated inert gas in the drawing process, wherein an anti-oxidation protection effect is achieved in the drawing process; finally after processing, performing coating protection treatment on the surfaces of the magnesium wires, and taking the process as an anti-oxidation measure for long storage. The equipment comprises a continuous diameter-changing and drawing device, an in-situ annealing device and a coating protection treatment device. According to the invention, the safety and the stability of the magnesium wires are guaranteed, the inert gas is adopted for protection in the whole manufacturing process, an anti-oxidation protection coating is used for coating in the end, and the long-term storage problem of the magnesium wires is solved.

Description

technical field [0001] The invention relates to a manufacturing method in the technical field of metal materials, in particular to a batch manufacturing method and equipment for superfine-diameter magnesium wires. Background technique [0002] Metal wire is a very important raw material in the field of medical devices. It can be used to weave various types of implantable stents and other device products. However, the production of magnesium wire is relatively difficult, mainly because magnesium and magnesium alloys and other metals After the material is processed, severe work hardening will occur. If the work hardening cannot be effectively removed, fracture will occur in subsequent processing. Magnesium wire with a small diameter (for example, less than 0.3mm) can be obtained by drawing, but there is also a serious problem of work hardening. It is necessary to effectively remove the processing stress and soften the material so that the processing can be continued and stably...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22F1/06C22F1/02
Inventor 刘静怡张绍翔孙录分张元壮姜曼赵常利张小农
Owner CHANGSHU MICROTUBE TECH