Light diffusion material

A light diffusion and light diffusion agent technology, which is applied in the field of light diffusion materials and modified polymer materials, can solve problems such as poor long-term thermal stability, and achieve good physical and mechanical properties, excellent aging resistance, and good thermal stability. Effect

Active Publication Date: 2014-04-09
余姚中国塑料城塑料研究院有限公司
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AI-Extracted Technical Summary

Problems solved by technology

The high flame-retardant transparent light-diffusing PC made by this invention has good light diffusivity and flame...
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Abstract

The invention belongs to the technical field of high molecular materials and particularly relates to a light diffusion technique. A light diffusion material is prepared by the step of with polycarbonate resin as a matrix material, matching a light diffusant, a composite antioxidant, a composite flame retardant and other auxiliary agents by virtue of a melt extrusion process. The light diffusion material at least comprises the following materials in parts by weight: 100 parts of polycarbonate resin, 2-10 parts of the light diffusant, 0.2-6 parts of light stabilizers, 0.3-9 parts of the composite antioxidant and 0.5-10 parts of the composite flame retardant. The light diffusion material has the advantages of good physical and mechanical properties, fire resistance, excellent ageing resistance, high light transmissivity and good light diffusion performance, thermal stability and manufacturability, and the failure time is remarkably prolonged, so that the service life is effectively prolonged; the light diffusion material is suitable for the machining forming of lamp products of lamp tubes and the like and particularly suitable for thin-wall abnormal-shaped lamp tubes of which the wall thickness are less than 3mm.

Technology Topic

AntioxidantAging resistance +12

Image

  • Light diffusion material

Examples

  • Experimental program(12)
  • Comparison scheme(1)

Example Embodiment

[0034] Example 1
[0035] Polycarbonate resin (Taiwan Chi Mei 110U, melt index MFI 10g/10min) 100 parts, light diffusing agent (Japan Shin-Etsu KMP-590, Japan Nakabuchi MP-90 according to 3:1 compounding, particle size 0.2-10μm) 2 parts, light stabilizer (Cytec UV-5411) 1 part, composite antioxidant 2.1 parts (tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester, three [2.4-Di-tert-butylphenyl] phosphite, triethylene glycol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl) propionate], 4,4 '-Thiobis(6-tert-butyl-3-methylphenol compounded according to 1.2:1:1:1:1), 5 parts of composite flame retardant (perfluorobutanesulfonic acid, potassium benzophenol sulfonate) 、P-biphenylene tetraphenyl bisphosphate is compounded at 3:1:1), 0.2 part of white oil, 0.1 part of fluorescent whitening agent, 0.2 part of toner, put into the high-speed mixing container, and the speed is high and low at room temperature. Mix for 3 to 5 minutes. After that, add the mixed materials into the hopper of the twin-screw extruder. The processing temperature of each zone of the screw is set as follows: the temperature of the first zone is 240~260℃, the temperature of the second zone is 260~270℃, and the temperature of the third zone 270~280℃, four zone temperature 270~280℃, five zone temperature 270~280℃, six zone temperature 270~280℃, seven zone temperature 270~280℃, eight zone temperature 270~280℃, nine zone temperature 270~280 ℃, the head temperature is 280-290℃, the screw speed is 300-600r/min, the light diffusion material involved in the present invention is obtained through melt blending, extrusion granulation, and its performance is listed in the attached table.

Example Embodiment

[0036] Example 2
[0037] 100 parts of polycarbonate resin (Taiwan Chi Mei 110L, MFI of 10g/10min), 3 parts of light diffusing agent (Japan Shin-Etsu KMP-590, Japan Nakabuchi MP-90 in 1:1 compound, particle size 0.2~ 10μm), 0.2 parts of light stabilizer (Taiwan Yongguang Chemical EV72), 0.8 parts of composite antioxidant (tetra [β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester, double ( 2,4-Di-tert-butylphenol) pentaerythritol diphosphite, triethylene glycol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl) propionate], 4 ,4'-thiobis(6-tert-butyl-3-methylphenol according to 1.2:1:1:1:1 compounding), 0.5 part of composite flame retardant (perfluorobutanesulfonic acid, benzophenone Potassium acid and p-biphenylene tetraphenyl bisphosphate are compounded at 2.7:1:1), 0.2 part of white oil, 0.1 part of fluorescent whitening agent, 0.2 part of toner, and processed according to the process given in Example 1. , Extrusion granulation to obtain the light diffusion material composite material of the present invention, the performance is listed in the attached table.

Example Embodiment

[0038] Example 3
[0039] Polycarbonate resin (Bayer 2407, melt index MFI is 20g/10min) 100 parts, light diffusing agent 4 parts (methyl methacrylate resin particles, particle size 0.2-10μm), light stabilizer 2 parts (Cytec UV -5411), 0.3 parts of composite antioxidant (tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester, tris[2.4-di-tert-butylphenyl] phosphorous acid Ester, triethylene glycol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate], 2,6-di-tert-butyl-4-methylphenol 1:1:1:1 compound), 3.1 parts of composite flame retardant (perfluorobutane sulfonic acid, potassium benzophenol sulfonate, p-biphenylene tetraphenyl bisphosphate according to 2:1:1 Compound), 0.2 part of white oil, 0.1 part of fluorescent whitening agent, 0.2 part of toner, processed according to the process given in Example 1, and extrusion granulated to obtain the light diffusion material composite material of the present invention. The properties are listed in the attachment table.

PUM

PropertyMeasurementUnit
Melt index10.0g/10min
Melt index20.0g/10min
Melt index7.0g/10min

Description & Claims & Application Information

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