Copper clad laminate

A copper clad laminate and PTFE technology, used in high-speed transmission copper clad laminates and high frequency fields, can solve the problems of low dielectric constant, low dielectric loss, high sintering temperature, reduce dielectric constant and dielectric loss, and reduce production. cost, the effect of improving product performance

Inactive Publication Date: 2014-04-16
SHANGHAI QUANKE INT TRADING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such as the Chinese invention patent (application number: 201010181737.X) fluororesin mixture, copper clad laminate made by using it and its production method. This method of producing copper clad laminate has complex process, high sintering temperature (300-380 ℃), pressing Disadvantages such as high temperature (300-380°C); Chinese invention patent (application number: 200910106385.9) preparation method of low-loss high-frequency copper-clad laminates, directly preparing copper-clad foils by direct lamination of polytetrafluoroethylene film and glass fiber cloth The laminated board replaces the traditional glass fiber cloth as the reinforcing material, and the polytetrafluoroethylene dispersion impregnation process simplifies the process, but at the same time it brings problems of poor wettability between polytetrafluoroethylene and glass fiber cloth, and poor adhesion between copper foil and the board. Disadvantages: China Invention Patent (Application No.: 201010283828.4) epoxy resin composition and the copper clad laminate made of it, using polytetrafluoroethylene powder to reduce the water absorption rate of the board, but due to the low polarity of polytetrafluoroethylene powder, it has no effect on adhesion It has an impact and also limits the amount of PTFE powder; Chinese invention patent (application number: 201210283315.2) copper clad laminate, the insulating medium layer includes at least one layer of porous PTFE film and at least one layer of thermosetting resin bonding sheet, covered The adhesion between the layers of the copper foil laminate is good, and the dielectric constant and dielectric loss of the copper clad laminate can be adjusted by the thickness and number of porous PTFE films, so that it has a low and stable dielectric strength. constant and lower dielectric loss

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Weigh 80 parts by weight of brominated bisphenol A type epoxy resin (Dow Chemical, epoxy equivalent 435, bromine content 19wt%, product name DER530), 20 parts by weight of modified cross-linked PTFE resin (Dakin, Japan, The fluorine content is more than 24wt%, the hydroxyl value is 60, and the product name is GK-570), which is dissolved in butanone solution and prepared as 65wt% glue. 2116 glass fiber cloth is impregnated in the above glue; after heating and drying, it forms a semi-cured adhesive sheet , wherein the content of 2116 glass fiber cloth is 50wt%, and the content of thermosetting resin is 50wt%. This step can be repeated to prepare multi-layer adhesive sheets, place copper foil on both sides, pressurize and heat to form a copper clad laminate.

Embodiment 2

[0036] Weigh 60 parts by weight of brominated bisphenol A type epoxy resin (Dow Chemical, epoxy equivalent 435, bromine content 19wt%, product name DER530), 40 parts by weight of modified cross-linked PTFE resin (Dakin, Japan, The fluorine content is more than 24wt%, the hydroxyl value is 60, and the product name is GK-570), which is dissolved in butanone solution and prepared as 65wt% glue. 2116 glass fiber cloth is impregnated in the above glue; after heating and drying, it forms a semi-cured adhesive sheet , wherein the content of 2116 glass fiber cloth is 50wt%, and the content of thermosetting resin is 50wt%. This step can be repeated to prepare multi-layer adhesive sheets, place copper foil on both sides, pressurize and heat to form a copper clad laminate.

Embodiment 3

[0038]Weigh 50 parts by weight of brominated bisphenol A type epoxy resin (Dow Chemical, epoxy equivalent 435, bromine content 19wt%, product name DER530), 50 parts by weight of modified cross-linked PTFE resin (Dakin, Japan, The fluorine content is more than 24wt%, the hydroxyl value is 60, and the product name is GK-570), which is dissolved in butanone solution and prepared as 65wt% glue. 2116 glass fiber cloth is impregnated in the above glue; after heating and drying, a prepreg adhesive sheet is formed. , wherein the content of 2116 glass fiber cloth is 50wt%, and the content of thermosetting resin is 50wt%. This step can be repeated to prepare multi-layer adhesive sheets, and copper foil sheets are placed on both sides, and pressurized and heated to form a copper clad laminate.

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Abstract

The invention discloses a copper clad laminate. The copper clad laminate comprises two conductor layers and a plurality of insulating medium layers which are arranged between the two conductor layers, wherein the plurality of insulating medium layers comprise at least one layer of modified crosslinking type PTFE (Polytetrafluoroethylene) resin combination bonding sheet, and a modified crosslinking type PTFE resin combination comprises modified crosslinking type PTFE resin containing a hydroxyl group and a resin containing a carbamate group, an amino group and/or an epoxy group. With the adoption of the copper clad laminate, as the dielectric constant and the dielectric loss of the copper clad laminate can be controlled by changing the content of the modified crosslinking type PTFE resin, the copper clad laminate has low and stable dielectric constant and lower dielectric loss; the copper clad laminate has the advantages that the manufacturing is simple, the process is feasible, and the cost is low.

Description

technical field [0001] The invention relates to the field of copper-clad laminates, in particular to a copper-clad laminate suitable for high-frequency and high-speed transmission. Background technique [0002] Copper Clad Laminate (CCL for short) is made of wood pulp paper or glass fiber cloth as a reinforcing material, impregnated with epoxy or phenolic resin, covered with copper foil on one or both sides, and cured by hot pressing. product. [0003] Copper clad laminates are the basic materials of the electronics industry, mainly used for processing and manufacturing printed circuit boards (PCBs), and are widely used in electronic products such as televisions, radios, computers, computers, and mobile communications. [0004] The development of high-frequency and high-speed transmission technology of electronic product signals depends on two important properties of printed circuit board substrate materials: low and stable dielectric constant (Dk) and as low as possible di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H05K1/03B32B15/08B32B15/092C09J7/00C09J163/00C09J127/18
Inventor 常晋元姚敏
Owner SHANGHAI QUANKE INT TRADING CO LTD
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