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Low-viscosity nitrile resin monomer, copolymer, cured material and preparation method thereof

A technology of viscosity nitrile-based resin and base resin, applied in the field of organic polymer materials, can solve the problems of affecting the performance of the resin system, reducing the viscosity of the system, poor heat resistance, etc., achieving low melt viscosity, simple and controllable method, and good flow sexual effect

Inactive Publication Date: 2014-04-23
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The low-viscosity resin currently used is epoxy resin, but due to the poor heat resistance of epoxy resin itself, it will seriously affect the performance of the resin system. Therefore, our laboratory has developed a low-viscosity nitrile-based resin. , reduce the viscosity of the system on the basis of ensuring the heat resistance of the system

Method used

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  • Low-viscosity nitrile resin monomer, copolymer, cured material and preparation method thereof
  • Low-viscosity nitrile resin monomer, copolymer, cured material and preparation method thereof
  • Low-viscosity nitrile resin monomer, copolymer, cured material and preparation method thereof

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Experimental program
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Embodiment example

[0065] (1) Preparation of low viscosity and low melting point nitrile resin monomer:

[0066] Step 1: Add 4-nonylphenol, 4-nitrophthalonitrile, anhydrous potassium carbonate and N,N-dimethylformamide into a reaction vessel with a condensing reflux device and heat to 60°C The reaction was carried out for 8 hours.

[0067] Step 2: filter the reaction mixture in step 1, and collect the filtrate.

[0068] Step 3: Pour the filtrate obtained in Step 2 into clear water for precipitation and decantation, and the obtained oily product is washed with a large amount of distilled water and then fully dried to obtain the final product low-viscosity nitrile resin monomer.

[0069] Wherein, the molar volume ratio of 4-nonylphenol, 4-nitrophthalonitrile, anhydrous potassium carbonate and N,N-dimethylformamide is as follows:

[0070] 4-Nonylphenol 1 4-Nitrophthalonitrile 2 Anhydrous Potassium Carbonate 1 N,N-Dimethylformamide (ml) 50

[0071] The resulting l...

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Abstract

A low-viscosity nitrile resin monomer, a polymer and a preparation method thereof belong to the technical field of organic polymer materials. The low-viscosity nitrile resin monomer is a 4-nonyl phenoxyl-1,2-phthalonitrile resin monomer, and the nitrile resin cured material is a product obtained by heating polymerization of the nitrile resin monomer and benzoxazine-containing nitrile resin monomers. The nitrile resin monomer has good fluidity at low temperature, and is applicable to viscosity modification of general thermosetting resin. Melt blending of the nitrile resin monomer and the benzoxazine-containing nitrile resin is performed to prepare 4-nonyl phenoxyl-1,2-phthalonitrile / benzoxazine-containing nitrile resin copolymer and cured materials. The obtained 4-nonyl phenoxyl-1,2-phthalonitrile / benzoxazine-containing nitrile resin copolymer has low melting viscosity and processing temperature, and is well applicable to composite material preparation by RTM technology. The 4-nonyl phenoxyl-1,2-phthalonitrile / benzoxazine-containing nitrile resin cured material has good curing performance such as self-flame resistance, adhesion performance, heat stability, and the like, and is applicable to fields of paint, bonding agents, electronic packaging materials, aviation, aerospace, ships and resin-based composite materials. The preparation method is simple, easy to control, low in reaction temperature, energy-saving, and suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of organic polymer materials, and relates to 4-nonylphenoxy-1,2-phthalonitrile resin monomer and 4-nonylphenoxy-1,2-phthalonitrile resin Monomer / benzoxazine-containing bis-phthalonitrile copolymer, cured product and preparation method thereof. Background technique [0002] In recent years, polymer composite materials have been widely used in aerospace machinery and ships, and resin transfer molding technology (RTM) has been widely used in laboratories and industrial production because of its high efficiency and low cost. use. However, because RTM technology has strict requirements on resin melt viscosity and fluidity, most thermosetting resins cannot meet the requirements of this processing technology. Although unsaturated polyesters, vinyl esters, and acrylates can meet the requirements of low viscosity (<1.0Pa.s) and long-term storage at injection temperature, these resins cannot meet the requirements...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C255/54C07C253/30C08G73/06C08J3/24
Inventor 刘孝波徐明珍邹兴强
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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