The invention belongs to the technical field of resin materials, and particularly relates to alkaline phenolic resin as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing
phenol,
bisphenol A and a
solvent, adding an alkali liquor A and an alkali liquor B, carrying out a first reaction, adding
formaldehyde, carrying out a second reaction, adding the alkali liquor A and the alkali liquor B, and carrying out a third reaction to obtain a product a; adding
formaldehyde into the product a, carrying out a fourth reaction, adding alkali liquor A and alkali liquor B, carrying out a fifth reaction, adding
formaldehyde, carrying out a sixth reaction, adding alkali liquor A and alkali liquor B, and carrying out a seventh reaction to obtain a product b; adding alkali liquor A into the product b, reacting for the eighth time, cooling, adding
urea for reacting for the ninth time, adding an
alcohol polymer and a
silane coupling agent, and mixing to obtain alkaline phenolic resin; the alkali liquor A and the alkali liquor B respectively and independently represent a
potassium hydroxide solution or a
sodium hydroxide solution. The tensile strength of the alkaline phenolic resin prepared by the preparation method is 1.29-1.36 MPa.