The invention discloses a preparation method of an upright double-
metal hydroxide film on the surface of
alloy steel and a product. The preparation method comprises the following steps: 1) firstly removing oily substances on the surface of
alloy steel, cleaning and
drying for later use; (2) adding the electro-deposition precursor solution into a three-
electrode tank, taking an
alloy steel substrate as a
working electrode, Ag / AgCl as a
reference electrode and a
platinum sheet as a counter
electrode, carrying out deposition by adopting a multi-potential
step method, firstly applying
anode potential to the surface of the steel substrate to carry out oxidation
dissolution to generate corresponding
metal ions, and then immediately applying
cathode potential to carry out deposition; and (3) cleaning and
drying the
working electrode after deposition is completed, so as to obtain the lamellar double-
metal hydroxide film with vertically grown lamellar
layers on the surface of the aluminum-
zinc-
magnesium plated steel. According to the LDHs prepared by the method, film-forming metal ions do not need to be obtained from the outside, and the obtained film is vertical to the surface of a substrate in a lamellar manner, so that the limitation of film forming is greatly solved, and the production steps and raw materials are greatly simplified.