The invention provides a super-weather resistant alkali-activated-fly ash-slag bicomponent outer wall inorganic coating. In the coating, sodium water glass and water are selected as base materials, and pulverized fuel ash, high-aluminum cement, slag, titanium white powder, pigment, talcum powder, redispersable latex powder, hydroxyethylcellulose, a naphthalene-based water reducing agent and a powdery antifoaming agent are used as padding. By testing the washing resistance of the coating of the invention, a specimen is washed 25,000 times without bubbling or cracking or dropping; by testing the water resistance, the specimen is soaked for 4,320 hours without bubbling or cracking or dropping; by testing acid rain resistance, the specimen is soaked in a solution, of which the pH is equal to 3 and is adjusted every day to be maintained to be 3, for 960 hours without bubbling or cracking or dropping; by testing salt resistance and alkali resistance, the specimen is soaked in 0.2mol/L of KOH solution of 5 percent of NaCl for 960 hours without bubbling or cracking or dropping; by testing bonding strength, the specimen has the bonding strength of 1.14MPa; and by testing flexibility, the specimen is qualified by 100 percent by being inspected through a grid scoring method of 1mm.