Preparation method of lightning arrester zinc oxide pressure-sensitive valve plate ceramic precursor
A technology of ceramic precursor and pressure-sensitive valve sheet, which is applied in the direction of varistor core, varistor, manufacturing resistor chip, etc. The effect of improving structural performance and good absorbing performance
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Embodiment 1
[0025] Firstly, the ceramic precursor of the arrester zinc oxide varistor valve is prepared, including the following steps:
[0026] 1. In parts by weight, 90 parts of oxidation, 7 parts of bismuth trioxide whiskers, and 23 parts of polycarbosilane are dispersed in 91 parts of a mixed solvent composed of tetrahydrofuran and xylene at a volume ratio of 1:1, and magnetically stirred at a uniform speed for 15 minutes , to make it evenly mixed, and then slowly dropwise add 0.1 parts of cumene hydroperoxide and 1.6 parts of tetramethyltetravinylcyclotetrasiloxane, keep continuous magnetic stirring at a constant speed, and react at 80°C for 6h, After the reaction is over, remove tetrahydrofuran and xylene solvents in the mixture by cooling, filtering, and distillation under reduced pressure to obtain a mixture of zinc oxide and polycarbosilane; 2. polycarbosilane, trimethoxyvinylsilane, nickel triacetylacetonate, Triallyl cyanurate is uniformly mixed and transferred to the reactor a...
Embodiment 2
[0029] Firstly, the ceramic precursor of the arrester zinc oxide varistor valve is prepared, including the following steps:
[0030] 1. In parts by weight, 4 parts of bismuth trioxide whiskers, 19 parts of polycarbosilane and 85 parts of zinc oxide are dispersed in 85 parts of a mixed solvent composed of tetrahydrofuran and xylene in a volume ratio of 1:1, and magnetically stirred at a uniform speed Mix well for 15 minutes, then slowly add 0.05 parts of cumene hydroperoxide and 0.8 parts of tetramethyltetravinylcyclotetrasiloxane dropwise, keep continuous magnetic stirring at a constant speed, and react for 4 hours at 65°C , after the reaction is over, remove tetrahydrofuran and xylene solvents in the mixture by cooling, filtering, and distillation under reduced pressure, and combine to obtain a mixture of zinc oxide and polycarbosilane; Nickel acetone and triallyl cyanurate were evenly mixed and transferred to the reaction kettle according to the ratio of parts by weight of 7...
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