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Method for preparing activated carbon with large specific surface area through rapid activation

A high specific surface area, activated carbon technology, used in chemical instruments and methods, inorganic chemistry, carbon compounds, etc., can solve the problems of high energy consumption, long activation time, and high activation temperature, and achieve reduced production costs, short activation time, and high activation. low temperature effect

Inactive Publication Date: 2014-05-07
DALIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The above-mentioned patent method has the following disadvantages in the production process: (1) The activation yield is low, the carbon consumption is large, and the production cost is high; (2) The activation temperature is high, the activation time is long, the energy consumption is large, and the production cost is high ; (3) The alkali carbon used is relatively high, so the production cost is high and the pollution is serious

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Spray 1ml of 5% hydrogen peroxide evenly into 2g of petroleum coke, grind 5g of potassium hydroxide and mix it with petroleum coke, put it into the reactor, and activate it in an argon atmosphere (heating rate is 80°C / min, the final The temperature is 730°C, the activation time is 5 minutes), after cooling to room temperature, the activated product is taken out, the excess alkaline medium and product are washed away with water, and activated carbon can be obtained after drying. Its yield is 75.67%, and its specific surface area is 2316m 2 / g.

Embodiment 2

[0020] Heat and mix 2ml of 3% ethylene glycol solution with 5g of potassium hydroxide and 2g of petroleum coke and put it into the reactor, activate it in an argon atmosphere (heating rate is 80°C / min, final temperature is 750°C, The activation time is 20 minutes), after cooling to room temperature, the activated product is taken out, the excess alkaline medium and product are washed away with water, and activated carbon can be obtained after drying. Its yield is 68.21%, and its specific surface area is 2552m 2 / g.

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PUM

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Abstract

The invention relates to a method for preparing activated carbon with a large specific surface area through rapid activation. The activated carbon with a large specific surface area is prepared through rapidly activating high-carbon raw materials, such as anthracite, petroleum coke and the like, by auxiliaries and alkali together. The method comprises the steps of uniformly mixing the high-carbon raw materials, the activating auxiliaries and KOH, so as to obtain an alkali-carbon mixture, and heating the alkali-carbon mixture under the protection of an inert atmosphere, so as to obtain an activation product; quickly cooling the activation product to room temperature under the protection of the inert atmosphere; washing the activation product with water, and drying, thereby preparing the activated carbon with a large specific surface area. According to the method, the activation temperature is low, the activation time is short, a relatively high yield of activated carbon with a large specific surface area is obtained under the condition of a lower alkali / carbon ratio, the utilization ratio of alkali, carbon and energy is increased, the production cost is reduced, and the pollution is reduced.

Description

technical field [0001] The invention relates to a method for rapidly activating and preparing activated carbon with high specific surface area. The method uses high-carbon raw materials such as anthracite and petroleum coke to be rapidly activated by additives and alkali. Background technique [0002] Activated carbon is an adsorbent with excellent performance, which is widely used in various industries because of its dual characteristics of physical adsorption and chemical adsorption. my country is the largest producer of activated carbon in the world. The output of activated carbon accounts for one-third of the world's output. However, the activated carbon it produces is mainly medium and low-grade products, and the overall product added value is not high. The expansion of the application field of activated carbon puts forward new and higher requirements for the adsorption performance. Under the general requirements of "high adsorption, multi-function and high strength...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/12C01B32/33C01B32/348
Inventor 卢春兰朱波詹世平侯维敏
Owner DALIAN UNIV
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