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Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

A technology for electric mopeds and lead-acid batteries, which is applied to battery electrodes, circuits, electrical components, etc., can solve the problems of insufficient battery charge acceptance performance, poor low temperature performance, low efficiency, etc., to improve discharge capacity and service life, Effect of improving low temperature discharge performance

Active Publication Date: 2016-01-27
河北超威电源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002]At present, the low-temperature performance of lead-acid batteries used in electric mopeds is not good, and generally can only meet or slightly exceed the national standard: the low-temperature capacity at -15°C reaches 0.7C 2, and at present, domestic batteries with better low-temperature performance can reach: -20°C low-temperature capacity of 0.75C2; but their charging and receiving performance is relatively poor, generally only Slightly exceeds the national standard value: Ica / I0≥2 (Ica is the charging current, I0 is the discharge current: 0.1C2) , generally can reach: 2.0~2.3
It cannot meet the requirements of low temperature environment below -20°C, especially in the northeast and northwestern regions of our country, some of which can reach -30°C in winter
Therefore, in the cold northern regions of our country, there are common phenomena that the batteries of electric mopeds are undercharged (poor charging acceptance) and short travel distances (low discharge capacity).
[0003] At present, the commonly used methods to improve the low-temperature discharge performance of lead-acid batteries in China are: 1. Thinning the electrode and increasing the specific surface area of ​​the electrode, but the production control quality cost is high and the efficiency is low; 2. Adding sulfate with good conductivity to the electrolyte, The electrical conductivity of the battery electrode is improved, but it only increases the low-temperature capacity in the early stage and cannot be maintained continuously; 3. The concentration of the electrolyte is reduced, but the battery capacity is generally low; 4. The negative electrode is increased to increase the capacity of the negative electrode, but the cost is too high high

Method used

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  • Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof
  • Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Example 1 Preparation of expansion agent

[0049] (1) Add 12.0L of sulfuric acid into the lead bucket (density 1.40±0.05g / cm at 15°C 3 ), the lead skin barrel is heated by steam.

[0050] (2) Open the valve of the heating steam on the lead drum, and when the sulfuric acid is heated to 80°C, adjust the steam valve to keep the temperature of the sulfuric acid between 80°C and 100°C.

[0051] (3) Put 3.0Kg of cotton (pure seedless cotton) into the lead bucket within 10 minutes, and at the same time, keep stirring with a plastic rod until all the cotton is semi-carbonized into a yellow-brown slurry (not carbonized and blackened) , close the steam valve.

[0052] (4) The expansion agent can only be used when the temperature drops to no higher than room temperature by 5°C. The storage period of the prepared expansion agent shall not exceed 3 days.

Embodiment 2

[0053] Example 2 Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

[0054] Low-temperature-resistant lead-acid battery lead paste for electric mopeds, including positive lead paste and negative lead paste:

[0055] The ratio of parts by weight of each component in the positive lead paste is: lead powder 960Kg, concentration 1.3-1.4g / cm 3Sulfuric acid 80Kg, pure water 110Kg, colloidal graphite 4.0Kg, red lead 50Kg, stannous sulfate 1.0Kg, sodium sulfate 0.5Kg; short fiber 0.9Kg;

[0056] The ratio of parts by weight of each component in the negative lead paste is: lead powder 1000Kg, concentration 1.3-1.4g / cm 3 75Kg of sulfuric acid, 105Kg of pure water, 0.6Kg of short fibers, 7.0Kg of barium sulfate, 1.0Kg of Norwegian lignin, 5.0Kg of humic acid, 3.0Kg of acetylene black, 1.5K of semi-carbonized wood chips, and 8L of swelling agent in Example 1.

[0057] (1) Ingredients

[0058] 1.1 Weigh each raw material according...

Embodiment 3

[0070] Example 3 Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

[0071] Low-temperature-resistant lead-acid battery lead paste for electric mopeds, including positive lead paste and negative lead paste:

[0072] The ratio of parts by weight of each component in the positive lead paste is: lead powder 950Kg, concentration 1.4g / cm 3 Sulfuric acid 80Kg, pure water 110Kg, colloidal graphite 3.0Kg, red lead 50Kg, stannous sulfate 1.5Kg, sodium sulfate 1.0Kg; short fiber 0.7Kg;

[0073] The ratio of parts by weight of each component in the negative lead paste is: lead powder 1000Kg, concentration 1.4g / cm 3 75Kg of sulfuric acid, 105Kg of pure water, 0.6Kg of short fiber, 7.0Kg of barium sulfate, 1.5Kg of Norwegian lignin, 5.0Kg of humic acid, 2.5Kg of acetylene black, 1K of semi-carbonized wood chips, and 12L of swelling agent in Example 1.

[0074] (1) Ingredients

[0075] 1.1 Weigh each raw material according to the r...

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Abstract

The invention relates to a low-temperature-resistant lead storage battery lead paste for electric bicycles and a preparation method thereof. 1.3-1.4g / cm3 sulfuric acid 80-86 parts, pure water 110-125 parts, colloidal graphite 3.0-4.0 parts, red lead 30-50 parts, stannous sulfate 1.0-1.5 parts, sodium sulfate 0.5-1.0 parts; short 0.7-0.9 parts of fiber; the ratio of parts by weight of each component in the negative electrode paste is: 1000 parts of lead powder, 75-81 parts of sulfuric acid with a concentration of 1.3-1.4g / cm3, 105-120 parts of pure water, and 0.6-0.8 parts of short fiber Parts, 6.0-7.0 parts of barium sulfate, 1.0-1.5 parts of Norway lignin, 4.0-5.0 parts of humic acid, 3.0-5.0 parts of acetylene black, 1.0-1.5 parts of semi-carbonized wood chips; improve the charge acceptance performance of the battery at low temperature and increase The discharge capacity is suitable for use in low temperature environments. Especially in the Northeast and Northwest of my country.

Description

technical field [0001] The invention relates to a storage battery material and a preparation method thereof, in particular to a low-temperature-resistant lead storage battery lead paste for electric bicycles and a preparation method thereof. Background technique [0002] At present, the low-temperature performance of lead-acid batteries for electric mopeds is not good, and generally can only meet or slightly exceed the national standard: the low-temperature capacity at -15°C reaches 0.7C 2 , and at present, domestic batteries with better low-temperature performance can reach: -20°C low-temperature capacity of 0.75C 2 ; but its charging and receiving performance is relatively poor, generally only slightly exceeding the national standard value: Ica / I 0 ≥2 (Ica is the receiving current for charging, I 0 For discharge current: 0.1C 2 ), generally can reach: 2.0 ~ 2.3. It cannot meet the requirements for the use of environments with low temperatures below -20°C, especially in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/56
CPCH01M4/57H01M4/62H01M4/624H01M4/627Y02E60/10
Inventor 钟维禄
Owner 河北超威电源有限公司