Nano cellulose extracted from shuck of xanthoceras sorbifolia and extraction method

A technology of nano-cellulose and cellulose fibers, which can be used in the fields of fiber raw material processing, textiles and papermaking, and can solve the problem of resource utilization of sorbiflora sorbifolium residues

Active Publication Date: 2014-05-28
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a method for extracting nano-cellulose

Method used

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  • Nano cellulose extracted from shuck of xanthoceras sorbifolia and extraction method
  • Nano cellulose extracted from shuck of xanthoceras sorbifolia and extraction method
  • Nano cellulose extracted from shuck of xanthoceras sorbifolia and extraction method

Examples

Experimental program
Comparison scheme
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Example Embodiment

[0017] Example 1

[0018] Take 100g of the broken husk of Aralia elata, immerse it in a 5% sodium hydroxide solution for 12 hours, then wash it repeatedly until the pH is neutral, and finally put it in an oven and dry it at 60°C. The husk of the treated Aronia chinensis was immersed in a mixed solution of toluene and ethanol with a volume ratio of 1:1, heated to make the solution in a slightly boiling state, and kept for 6 hours. The remainder was repeatedly washed with ethanol, put in an oven, and dried at 60°C.

[0019] Put the treated husk of Aronia vulgaris into a 1:1 volume ratio of hydrogen peroxide (30%) and acetic acid mixed solution, heat it to 60°C and keep it under stirring for 7 hours to remove lignin. The remainder was rinsed with deionized water and filtered with suction until the filtrate was neutral. To ensure that the reaction is complete, repeat the above delignification step once, then heat the resulting product in a 5% sodium hydroxide solution to 80°C for 2 h...

Example Embodiment

[0021] Example 2

[0022] Take 200g of the broken husk of Aralia elata, immerse it in a 3% sodium hydroxide solution for 24 hours, then wash it repeatedly until the pH is neutral, and finally put it in an oven and dry it at 50°C. The husk of the treated Aronia chinensis was immersed in a mixed solution of toluene and ethanol with a volume ratio of 1:0.5, heated to make the solution in a slightly boiling state, and kept for 12 hours. The residue was repeatedly washed with ethanol, put into an oven, and dried at a temperature of 50°C.

[0023] Put the processed Xanthoceras sorbifolia husk into a 1:1 volume ratio of hydrogen peroxide (30%) and acetic acid mixed solution, heat it to 50°C and keep it under stirring for 9 hours to remove lignin. The remainder was rinsed with deionized water and filtered with suction until the filtrate was neutral. To ensure that the reaction is complete, repeat the above delignification step twice, and then heat the resulting product in a 3% sodium hyd...

Example Embodiment

[0025] Example 3

[0026] Take 300g of the broken husk of Aralia elata, immerse it in a 10% sodium hydroxide solution for 8 hours, and then wash it repeatedly until the pH is neutral, and finally put it in an oven and dry it at 80°C. The husk of the treated Aronia chinensis was immersed in a mixed solution of toluene and ethanol with a volume ratio of 1:2, heated to make the solution in a slightly boiling state, and kept for 12 hours. After repeated washing with ethanol, the residue is put into an oven and dried at 80°C.

[0027] Put the treated husk of Aronia vulgaris into a mixed solution of hydrogen peroxide (30%) and acetic acid with a volume ratio of 1:2, heat it to 60°C and keep it under stirring for 12 hours to remove lignin. The remainder was rinsed with deionized water and filtered with suction until the filtrate was neutral. To ensure that the reaction is complete, repeat the above delignification step 3 times, then heat the resulting product in 8% sodium hydroxide solu...

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Abstract

The invention relates to a method for extracting nano cellulose from shuck of xanthoceras sorbifolia, which comprises the steps of alkali treatment, wax removal treatment, lignin removal treatment and hydrolysis. The method comprises the following steps: immersing the crushed shuck of xanthoceras sorbifolia, washing to neutrality and drying; immersing the product in a mixed solution of toluene and ethanol, heating and keeping for a while, cleaning the residues by ethanol and drying; placing in a mixed solution of hydrogen peroxide and acetic acid, stirring and keeping for a while under heating condition, flushing the residues after a reaction is finished, pumping filtration until a filtrate presents neutral; heating the product in a sodium hydroxide solution, heating and reacting, pumping filtration and flushing until the filtrate presents neutral and then drying; adding in a sulfate solution, stirring and keeping for a while under heating condition, adding deionized water in a reaction container; placing the obtained fluid suspension in a high speed centrifuge for multitime separation, adding an aqueous alkali drop by drop for neutralizing if the fluid suspension is acidic, and finally drying through a freezing mode to obtain the nano cellulose powder extracted from shuck of xanthoceras sorbifolia.

Description

technical field [0001] The invention relates to the field of natural biological materials, and in particular provides nano cellulose of Xantho sorbifolium husk and a preparation method thereof. Background technique [0002] With the depletion of resources brought about by the development of human society and the increasingly prominent problems of environmental pollution, natural biomaterials have attracted widespread attention due to their renewability and biodegradability. [0003] Nanocellulose is a natural material with a nanoscale that is ubiquitous in cellulose-containing plants. The diameter of nanocellulose is generally below 100nm, and the length varies from 100nm to several microns. The morphology and properties of nanocellulose depend on the plant fibers from which nanocellulose is extracted. Nanocellulose has high hardness and modulus (Mandal and Chakrabarty2011), and the Young's modulus of crystal structure nanocellulose can even reach 138GPa (Nishino et al.199...

Claims

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Application Information

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IPC IPC(8): D21C5/00
Inventor 隋国鑫马娜刘冬艳林国明
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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