A high-recovery, pollution-resistant reverse osmosis membrane water treatment method
A technology of reverse osmosis membrane and high recovery rate, applied in water/sewage multi-stage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc. Deal with complex problems to achieve the effect of low-cost continuous operation, pollution reduction, and recovery rate increase
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Embodiment 1
[0032] The comprehensive wastewater of a coal chemical plant is composed of circulating water sewage and biochemically treated gas washing water. Among them, the COD is about 50ppm, the total silicon is about 50ppm, the total hardness is about 800ppm, and the conductivity is about 3000us. The wastewater is first chemically softened and clarified, with a total hardness of 120 ppm, and then filtered through sand filtration and continuous ultrafiltration. The turbidity of the effluent is 0.1NTU, and the SDI is 2. The water then passes through the automatic acid addition adjustment system and enters the first stage. For RO treatment, the concentrated water pH control period is 2 hours, and the PH-time curve within the 2-hour period is a step curve, where PH=5 takes 30 minutes, PH=6 takes 30 minutes, PH=9 takes 30 minutes, and PH=10.5 Go through 30 minutes. The water production rate of the reverse osmosis system is 83%, the conductivity of the product water is about 80us, and the COD...
Embodiment 2
[0034] The concentrated water produced in Example 1 was collected in the concentrated water tank, slightly turbid, with a pH of about 8. After sand filtration, the pH was adjusted to 10.5 with caustic soda. It was found that a small amount of flocs appeared. After ultrafiltration, The indicators measured are: COD is about 200ppm, total hardness is about 200ppm, conductance is about 15000us, total silicon is about 120ppm, and pH is about 10.5. The water then passes through the automatic acid-adding adjustment system and enters the second-stage RO treatment. The PH control period of the concentrated water is 2 hours, and the PH-time curve within the 2-hour period is a step curve, in which it takes 40 minutes at PH=5, and PH=6 For 20 minutes, PH=9 for 20 minutes, and PH=10.5 for 40 minutes. The water production rate of the reverse osmosis system is 70%, the conductivity of the product water is about 900us, and the COD of the product water is about 10. It has been running continu...
Embodiment 3
[0036] The comprehensive wastewater of a refinery chemical plant is composed of circulating water sewage and biochemically treated domestic sewage, of which COD is about 30ppm, total silicon is about 50ppm, total hardness is about 500ppm, and conductivity is about 2800us. The wastewater is chemically softened and clarified first, with a total hardness of 110 ppm, and then filtered through sand filtration and continuous ultrafiltration. The turbidity of the effluent is 0.1NTU, and the SDI is 2. The water then passes through the automatic acid addition adjustment system and enters the first stage. For RO treatment, the PH control period of the concentrated water is 4 hours, and the PH-time curve within the 4-hour period is a sinusoidal curve, where the bottom of the valley is PH=5, the peak of the valley is PH=11, and the median is PH=8. The reverse osmosis system produces The water rate is 85%, the conductivity of the produced water is about 60us, and the COD of the produced wat...
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