The invention belongs to the field of water treatment, and particularly relates to an environmentally friendly phosphorus-free scale inhibitor for seawater desalination reverse osmosis membranes, and a preparation method thereof, wherein the environmentally friendly phosphorus-free scale inhibitor comprises, by weight, 20-30% of a maleic acid-acrylic acid copolymer, 40-60% of polyepoxysuccinic acid, 10-30% of an acrylic acid-2-acrylamide-2-methylpropanesulfonic acid copolymer, 1-5% of citric acid, 0.5-1% of a surfactant, and the balance of deionized water. According to the present invention, the environmentally friendly phosphorus-free scale inhibitor is especially suitable for the seawater desalination reverse osmosis system, can effectively solve the membrane pollution problem caused by the deposition of CaCO3, CaSO4, BaSO4, SrSO4, iron oxide and silicon scale on the reverse osmosis membrane, can prevent the membrane scale from fouling, can prevent the reverse osmosis membrane from pollution and clogging, can improve the working efficiency of the reverse osmosis system, can prolong the service life of the reverse osmosis membrane, does not contain phosphorus, can discharge the pollution-free concentrated water, and is the environmentally friendly water treatment agent.