Inverted top emission organic electroluminescence device and preparation method thereof
A luminescence and top emission technology, applied in the field of electric light sources, can solve the problems of inconvenient heat supply and speed adjustment, uneven structure of the transport doped layer, and influence on carrier injection efficiency, etc., so as to improve electron transport efficiency and luminescence Efficiency, the effect of improving uniform performance and stable performance
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[0032] Correspondingly, an embodiment of the present invention also provides a method for manufacturing the above-mentioned inverted top emission organic electroluminescence device. The process of the preparation method is as follows image 3 shown, see also figure 1 , 2 , including the following steps:
[0033] S01. Obtain the substrate: obtain the substrate of the required size according to actual needs as the substrate layer 1;
[0034] S02. Prepare the cathode layer 2: plate the cathode layer 2 on one surface of the substrate layer 1;
[0035] S03. Prepare the organic functional layer 3: the surface of the cathode layer 2 prepared in step S02 opposite to the substrate layer 1 is coated with an organic functional layer 3, wherein the organic functional layer 3 includes an electron transport layer 31 and is driven by an external power supply. The light-emitting layer 33 that emits light from the bottom, and the electron transport layer 31 is stacked and combined between ...
Embodiment 1
[0061] An organic electroluminescent device with inverted top emission, its structure is glass substrate / Al(70nm) / electron transport layer / TPBi(10nm) / DPVBi(20nm) / TPD(10nm) / F4-TCNQ:MeO-TPD (25nm) / Al(18nm); wherein the precursor structure of the electron transport layer is LiF(0.5nm) / TPBi(10nm) / LiF(0.5nm) / TPBi(10nm), the electron transport layer is composed of the electron transport layer The precursor is obtained through the following heat treatment in Example 1.
[0062] The preparation method of the inverted top emission organic electroluminescence device comprises the following steps:
[0063] Step S11. Provide a glass substrate: place the glass substrate in deionized water containing detergent for ultrasonic cleaning, and after cleaning, use isopropanol and acetone in ultrasonic treatment for 20 minutes, and then dry it with nitrogen for use;
[0064] Step S12. At a vacuum degree of 5×10 -4 In the coating system of Pa, the Al cathode layer is prepared on the glass substra...
Embodiment 2
[0075] An organic electroluminescent device with inverted top emission, its structure is glass substrate / Ag(100nm) / electron transport layer / TPBi(10nm) / DPVBi(20nm) / TPD(10nm) / F4-TCNQ:CuPc(25nm ) / Ag(20nm); the precursor structure of the electron transport layer is Li 2 CO 3 (1nm) / Alq 3 (9nm) / Li 2 CO 3 (1nm) / Alq 3 (9nm), the electron transport layer is formed by the electron transport layer precursor through the following heat treatment in Example 1.
[0076] The preparation method of the inverted top emission organic electroluminescence device comprises the following steps:
[0077] Step S21. Provide a glass substrate: perform cleaning treatment with reference to the treatment method in Example 1;
[0078] Step S22. When the degree of vacuum is 5×10 -4 In the coating system of Pa, the Ag cathode layer is prepared on the glass substrate in step S21, and the evaporation speed of the Ag cathode layer is 0.5nm / s;
[0079] Step S23. When the degree of vacuum is 5×10 -4 In the...
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