The invention relates to the technical field of
solid-state batteries, in particular to a
porous silicon carbon-
metal composite negative
electrode material and a
solid-state battery. The
porous carbon skeleton comprises a first hole, a second hole and a third hole; the aperture d1 of the first hole is greater than or equal to 5nm and less than or equal to 20nm; the aperture of the second hole is d2, and d2 is more than 25nm and less than or equal to 50nm; the aperture of the third hole is d3, and d3 is more than 80nm and less than or equal to 200nm; at least nanometer
silicon particles are arranged in the first holes, and at least
metal particles are arranged in the second holes and the third holes. According to the
porous silicon carbon-
metal composite negative
electrode material, through the partition design of the gradient porous framework, the
silicon locking function is achieved through the first holes, the stress buffer area effect is achieved through the second holes / third holes, the problem that the volume of a negative
electrode with the large
silicon loading capacity is seriously expanded can be remarkably solved, the silicon loading limit of a traditional single micropore structure is broken through, and the service life of the negative electrode is prolonged. And the
energy density and the
cycling stability of the battery are obviously improved.