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Chloroacetic acid chlorination mother solution treatment method

A treatment method, the technology of chloroacetic acid, which is applied in the field of treatment of chloroacetic acid chlorination mother liquor, can solve the problems of high unit consumption of acetic anhydride, increase of by-products of hydrogenation reaction, expensive raw materials, etc., and achieve saving of acetic anhydride consumption and reduction of by-products , the effect of reducing the likelihood

Active Publication Date: 2014-07-16
CHINA TIANCHEN ENG +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The trichlorethylene hydrolysis method has been developed due to its relatively simple process and high product purity. This process was used to build industrial production plants in Europe, but it has been eliminated in recent years due to expensive raw materials.
But this method has following shortcoming: 1) acetyl chloride content is higher in the chlorination mother liquor, after directly adding water and hydrolyzing, finally cause the unit consumption of acetic anhydride to be high; The by-products of the hydrogenation reaction increase and the product yield decreases; 3) The chlorination mother liquor contains high HCL, which affects the efficiency of the hydrogenation reaction and leads to an increase in catalyst consumption

Method used

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  • Chloroacetic acid chlorination mother solution treatment method

Examples

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Embodiment 1

[0024] The chlorination mother liquor is heated by the heater 1; the heated chlorination mother liquor and water enter the hydrolysis reactor 2 respectively, and the temperature of the mother liquor increases, and part of the acetyl chloride evaporates; the unevaporated acetyl chloride and water are hydrolyzed with the water in the hydrolysis reactor 2 Reaction; after the hydrolysis reaction, the chlorinated mother liquor enters the secondary hydrolysis reactor 4 for flash evaporation, and separates HCL into the absorption device; the flashed mother liquor is pumped into the hydrogenation reactor 7 through the pump 6, and reacts under the action of the catalyst. The latter HCL enters the absorption device, and the chlorinated mother liquor enters the distillation or crystallization process.

Embodiment 2

[0026] The chlorination mother liquor is heated by the heater 1; the heated chlorination mother liquor and water enter the hydrolysis reactor 2 respectively, and the temperature of the mother liquor increases, and part of the acetyl chloride evaporates; the unevaporated acetyl chloride and water are hydrolyzed with the water in the hydrolysis reactor 2 Reaction; The steam jacket 3 is installed outside the hydrolysis reactor 2 to further increase the temperature of the chlorination mother liquor and reduce the saturation content of acetyl chloride; after the hydrolysis reaction, the chlorination mother liquor enters the secondary hydrolysis reactor 4 for flash evaporation, and separates HCL into the absorption device; The flashed mother liquor is pumped into the hydrogenation reactor 7 through the pump 6 and reacted under the action of the catalyst. The reacted HCL enters the absorption device, and the chlorinated mother liquor enters the distillation or crystallization process.

Embodiment 3

[0028] The chlorination mother liquor is heated by the heater 1; the heated chlorination mother liquor and water enter the hydrolysis reactor 2 respectively, and the temperature of the mother liquor increases, and part of the acetyl chloride evaporates; the unevaporated acetyl chloride and water are hydrolyzed with the water in the hydrolysis reactor 2 Reaction: The steam jacket 3 is installed outside the hydrolysis reactor 2 to further increase the temperature of the chlorination mother liquor and reduce the saturation content of acetyl chloride; after the hydrolysis reaction, the chlorination mother liquor enters the secondary hydrolysis reactor 4 for flash evaporation, and the secondary hydrolysis reactor 4 is equipped with stirring To promote the full progress of the hydrolysis reaction, separate HCL and enter the absorption device; the mother liquor after flashing is pumped into the hydrogenation reactor 7 through the pump 6 and reacts under the action of the catalyst. The r...

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Abstract

The invention discloses a chloroacetic acid chlorination mother solution treatment method, comprising the following steps of heating a chlorination mother solution through a heater; delivering the heated chlorination mother solution and water into a hydrolysis reactor respectively, and evaporating a part of acetyl chloride; reacting the other part of acetyl chloride with water; delivering the hydrolyzed chlorination mother solution into a secondary hydrolysis reactor, and performing flash evaporation to separate HCL out; pumping the mother solution subjected to the flash evaporation into a hydrogenation reactor through a pump, reacting in the presence of a catalyst, delivering HCL after reacting into an absorption device, and performing a distillation or crystallization process on the mother solution. The method has the advantages that acetyl chloride in the chlorination mother solution is recycled, so that the consumption of acetic anhydride in production is finally reduced, the HCL content of the chlorination mother solution is reduced, and the hydrogenation reaction efficiency is improved.

Description

Technical field [0001] The invention relates to a production method of chloroacetic acid, in particular to a processing method of chloroacetic acid chlorination mother liquor. Background technique [0002] There are only two industrial production methods for chloroacetic acid: trichloroethylene hydrolysis and acetic acid catalytic chlorination. The hydrolysis of trichloroethylene uses concentrated sulfuric acid as a catalyst to carry out the addition and hydrolysis of water at the same time. The hydrolysis of trichloroethylene has been developed due to its simple process and high product purity. Europe used this process to build industrial production equipment, but it has been eliminated in recent years due to expensive raw materials. The acetic acid catalytic chlorination method is under the action of a catalyst (such as iodine, phosphorus, sulfur or sulfur and phosphorus halides and acetic anhydride, etc.), glacial acetic acid and chlorine are in one or several series reactors...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C51/377C07C51/64C07C53/16C07C53/40
CPCC07C51/377C07C51/64C07C53/16C07C53/40
Inventor 张猛赵兵王国亮张进治董强孙顺平张树晨杨晋松
Owner CHINA TIANCHEN ENG
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