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Synergistic flame retardant metal ion treated montmorillonoid PC/ABS (polycarbonate/polyacrylonitrile) alloy material and preparation method of alloy material

A technology of metal ions and alloy materials, applied in the field of testing, can solve problems such as poor compatibility, affecting the performance of matrix materials, and dispersibility limitations, and achieve the effects of ensuring flame retardant performance, simple and easy processing methods, and obvious effects

Inactive Publication Date: 2014-07-16
宁波泛塑新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the compatibility of metal oxide and metal salt particles with polymers is poor, their dispersion in the polymer matrix is ​​limited, and the metal ions that can play a role are limited to the surface of the filler particles, which will seriously affect the matrix material. performance

Method used

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  • Synergistic flame retardant metal ion treated montmorillonoid PC/ABS (polycarbonate/polyacrylonitrile) alloy material and preparation method of alloy material
  • Synergistic flame retardant metal ion treated montmorillonoid PC/ABS (polycarbonate/polyacrylonitrile) alloy material and preparation method of alloy material
  • Synergistic flame retardant metal ion treated montmorillonoid PC/ABS (polycarbonate/polyacrylonitrile) alloy material and preparation method of alloy material

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Experimental program
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Embodiment

[0033] Example thermal stability

[0034] Take 5-10 mg of powder sample, and use SDTQ600 thermogravimetric analyzer (TA, USA) to measure the thermal stability of the material in air atmosphere, the heating rate is 10 °C / min, and the temperature range is 50-700 °C. After taking the average value of three parallel experiments, the experimental data obtained are shown in Table 2.

[0035] Table 2 Thermal stability of material embodiments of the present invention

[0036]

[0037] a T onset Expressed as the temperature when the sample thermal weight loss is 5wt%; T max Refers to the temperature at the maximum thermal weight loss rate, max1, max2, and max3 correspond to the first, second, and third maximum thermal decomposition rates, respectively.

[0038] Examples Flame retardant properties

[0039] The flame retardant performance test of this embodiment includes limiting oxygen index, vertical combustion and micro-cone calorimetry, and the specific implementation process...

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Abstract

The invention discloses a synergistic flame retardant metal ion treated montmorillonoid PC / ABS (polycarbonate / polyacrylonitrile) alloy material and a preparation method of the alloy material. The alloy material is prepared from the following components by weight percent: (1) 60%-75% of polycarbonate, (2) 5%-25% of ABS (acrylonitrile-butadiene-styrene) resin, (3) 2%-5% of a compatibilizer, (4) 10%-15% of a fire retardant and (5) 1%-5% of metal ion treated montmorillonoid. The alloy material has the advantages that metal ions are replaced to the surface of a sheet layer of the montmorillonoid, so that the problem that metal oxides and metal salt particles are not easily dispersed in polymer materials is well solved; the dispersity of the montmorillonoid in a polymer matrix is improved, so that the contact between the metal ions and the polymer matrix is greatly improved, the synergistic flame retardant effect of the metal ions and the flame retardant is enhanced, and the heat performance and the flame retardant property of polymers are improved.

Description

technical field [0001] The invention relates to processes such as organic synthesis, blending of polymer composite materials, material flame retardancy and mechanical performance testing, that is, the preparation of a metal ion-treated montmorillonite, the compound flame retardant PC of montmorillonite and flame retardant / ABS alloy treatment preparation and performance testing, specifically a metal ion treatment montmorillonite synergistic flame-retardant PC / ABS alloy material and its preparation method. technical background [0002] Polycarbonate (PC for short) is an amorphous, odorless, non-toxic, highly transparent colorless or slightly yellow thermoplastic engineering plastic, and is a general term for polymers containing carbonate groups in their molecular chains. PC has excellent physical and mechanical properties, excellent heat resistance and impact resistance, high refractive index, good flame retardant performance, good processing performance, high dimensional sta...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L55/02C08K9/02C08K9/04C08K3/34
Inventor 郭正虹秦彬彬潘帅许远远
Owner 宁波泛塑新材料科技有限公司
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