Carbon porous electrode preparing method

A porous electrode and electrode technology, applied in the field of electrochemistry, can solve the problems of reducing the effective area and pore volume of carbon materials, hindering the transfer of electrons in carbon materials and current collectors, reducing the surface area and pore volume of activated carbon materials, etc. The effect of reaction area, improvement of practical work performance, and ease of large-scale application

Active Publication Date: 2014-07-23
陆艾珍
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  • Abstract
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  • Application Information

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Problems solved by technology

The disadvantage of this method is that the binder components remain in the carbon porous electrode, and these binders are usually organic polymer substances, which will be adsorbed on the surface of the carbon material, hindering the interaction between the carbon material and the electrolyte. contact; for activated carbon carbon materials, the remaining binder substances will still exist in the pores of the activated carbon, thereby greatly reducing the surface area and pore volume of the activated carbon material, and reducing the performance of the activated carbon material during the electrode operation; at the same time, almost The non-conductive binder is between the carbon material particles and the carbon material particles and the current collector, which hinders the transfer of electrons between the carbon material and the current collector, and reduces the electronic conductivity of the carbon porous electrode; at the same time, for some bonding During the long-term use of the agent, there will be slow dissolution or failure, and the electrode strength will gradually decrease during long-term use.
This method requires press equipment, and because the binder component remains in the electrode, it has the same disadvantages as the first carb

Method used

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Effect test

preparation example Construction

[0031] The carbon porous electrode preparation method provided by the present invention includes two major steps: the first step—slurry coating to shape the electrode sheet. Firstly, the electrode raw materials for preparing the carbon porous electrode are mixed, and after mixing evenly, they are coated on the surface of the current collector, and the coated sheet is dried to form an electrode sheet with a certain thickness. The above-mentioned electrode raw materials include: carbon materials such as carbon particles or carbon powder, binders, conductive agents, and may further include additives. At the same time, considering the requirements of the subsequent coating process, in order to improve the coating process and make it easier to operate, an appropriate amount of solvent, such as water or ethanol, can be added during the mixing process of the electrode raw materials. The specific solvent type can be determined according to the selected binder.

[0032] The carbon par...

Embodiment 1

[0056] Activated carbon powder with a particle size of 100 mesh (specific surface area 800m 2 / g), water-based polyacrylate is the first type of binding agent (mixed into 0.5% glue), and ethylene-vinyl acetate copolymer EVA is the second type of binding agent. According to the weight ratio of activated carbon powder: the first type of binder: the second type of binder = 50:5:45, the above materials are evenly mixed. An appropriate amount of water was added to adjust the viscosity of the slurry, and then the slurry was coated on the stainless steel foil by a knife coating method; the coated electrode was placed in an oven and dried at a constant temperature of 40°C.

[0057] Put the dried electrode sheet into the atmosphere protective furnace, use Ar as the protective gas, raise the temperature to 1000°C at a rate of 3°C / min, and keep it at 1000°C for 5 hours, then stop heating, and cool down to room temperature with the furnace , that is, the prepared carbon porous electrode ...

Embodiment 2

[0059] Graphite powder with a particle size of 300 meshes, polytetrafluoroethylene PTFE emulsion as the first type of binder (commercialized emulsion with a solid content of 60%), and polyethyl acetate as the second type of binder. According to the weight ratio of activated carbon powder: the first type of binder: the second type of binder = 80:10:10, the above materials are evenly mixed. An appropriate amount of ethanol was added to adjust the viscosity of the slurry, and then the slurry was coated on the nickel foil by scraping; the coated electrode was placed in a fume hood to dry naturally.

[0060] Put the dried electrode sheet into the atmosphere protective furnace, use Ar as the protective gas, raise the temperature to 600°C at a rate of 1°C / min, and keep it at 600°C for 5 hours, then stop heating, and cool down to room temperature with the furnace. That is, the prepared carbon porous electrode was obtained.

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Abstract

The invention provides a novel carbon porous electrode preparing method. According to the method, a simple preparing technology is realized while the excellent performance of a carbon porous electrode is guaranteed. The carbon porous electrode preparing method comprises the steps that the surface of a current collector is coated with an electrode material containing carbon materials, binders and conductive agents, drying is conducted, and then an electrode plate in a specified thickness is formed; carbonizing treatment is conducted on the electrode plate at a temperature higher than or equal to 400 DEG C in an inert atmosphere, and then the carbon porous electrode is formed. By the adoption of the method, the obtained carbon porous electrode is better is conductive performance, resistance among carbon granules is reduced, ohmic drop on the carbon electrode in usage is reduced, actual working performance of the electrode is improved, the structural strength of the obtained carbon porous electrode is high, and the effective reaction area of the carbon electrode material is increased.

Description

technical field [0001] The invention belongs to the field of electrochemical technology, in particular to the electrochemical technology using carbon porous electrodes. The invention relates to a method for preparing a carbon porous electrode, in particular to a method for preparing a carbon porous electrode by using carbon with a high specific surface area. Background technique [0002] Carbon electrodes are commonly used electrodes in electrochemical technology. Carbon electrodes are used in many electrochemical technologies and devices, such as capacitors, electrosorption devices and other technologies and devices. Carbon electrodes have relatively stable electrochemical properties and are not easily oxidized or reduced. Moreover, carbon materials are generally low in cost and have many applications in industry. In practical applications, the carbon electrode is generally in the form of a carbon porous electrode (also called a porous carbon electrode), which has a high...

Claims

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Application Information

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IPC IPC(8): H01G11/86H01M4/04
CPCY02E60/10
Inventor 陆艾珍
Owner 陆艾珍
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