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A method for improving the electrical conductivity of graphene films

A technology of graphene film and conductive properties, which is applied in the manufacture of circuits, electrical components, cables/conductors, etc., can solve the problems of lower transmittance of graphene film, affect patterning process, high square resistance of graphene film, etc., and achieve convenience Patterning and other treatments, promote wide application, and improve the effect of conductive performance

Active Publication Date: 2017-03-29
CHONGQING GRAPHENE TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the ITO film produced according to the existing process has high conductivity and transparency, which can basically meet the technical index requirements of some electronic products, there are still many problems that are difficult to overcome: (1) ITO is highly brittle and easy to wear or appear when it is bent. Cracks, shedding, etc.; (2) After ITO film formation, high temperature treatment is required to achieve high conductivity; (3) Indium in ITO is a rare earth element with limited reserves
[0004] At present, the preparation methods of graphene film mainly include mechanical exfoliation method, silicon carbide epitaxial growth method, redox method and chemical vapor deposition method. Unstable, after one day at room temperature, the square resistance will rise sharply, which will affect the subsequent patterning process and other processes. If the graphene film is stacked in multiple layers, although the square resistance can be effectively reduced, the superposition of graphene film At the same time, the transmittance of graphene films will also decrease, which limits the application of graphene films in industrial fields such as display technology that require high square resistance and light transmittance of transparent conductive films.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Take a graphene film (square resistance 575 Ω / sq, light transmittance 92%) and transfer it to the substrate; irradiate it with ultraviolet light with a power of 1 W and a wavelength of 100 nm for 10 minutes; The graphene film on the substrate was immersed in a 5% nitric acid solution for 30 min, the surface of the graphene film attached to the substrate was washed with deionized water, dried, and the graphite attached to the substrate was tested with a four-probe electrode. The square resistance of the graphene film is 162 Ω / sq, and the light transmittance is 91%. The resistance rises to 167 Ω / sq, a 3% increase.

Embodiment 2

[0040] Take a graphene film (square resistance 569 Ω / sq, light transmittance 92%), and transfer it to the substrate; irradiate with ultraviolet light with a power of 300 W and a wavelength of 300 nm for 1 min; The graphene film on the substrate was soaked in 68% nitric acid solution for 1 min, the surface of the graphene film attached to the substrate was washed with deionized water, dried, and the four-probe electrode was used to test the surface of the graphene film attached to the substrate. The square resistance of the graphene film is 115Ω / sq, and the light transmittance is 91%. The resistance rises to 121Ω / sq, an increase of 5%.

Embodiment 3

[0042]Take a graphene film (square resistance 583 Ω / sq, light transmittance 92%) and transfer it to the substrate; irradiate it with ultraviolet light with a power of 150 W and a wavelength of 150 nm for 5 minutes; The graphene film on the substrate is immersed in a 30% nitric acid solution for 16 minutes, the surface of the graphene film attached to the substrate is washed with deionized water, dried, and the graphene attached to the substrate is tested with a four-probe electrode. The square resistance of the film is 142Ω / sq, and the light transmittance is 91%. The graphene film attached to the substrate is placed under normal temperature and pressure for 6 months, and then the square resistance is tested with four-probe electrodes, and the square resistance increases. to 147 Ω / sq, an increase of 4%.

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PUM

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Abstract

The invention discloses a method for improving conductivity of a grapheme film. Firstly, the grapheme film attached to a substrate is processed through ozone or ultraviolet light and ozone, and then the grapheme film attached to the substrate is processed through non-metal inorganic acid. Sheet resistance of the grapheme film processed in the method can be reduced. More importantly, the sheet resistance of the grapheme film keeps stable for a long time and does not change much at high temperature. Accordingly, later patterning and other processing are facilitated, and wide application of the grapheme film in the display technology and other industrial fields with high requirements for sheet resistance and light transmittance of transparent conductive films is promoted.

Description

technical field [0001] The invention relates to a graphene film processing method, in particular to a method for improving the electrical conductivity of the graphene film. Background technique [0002] ITO (indium tin oxide) film is the most widely used transparent conductive film on the market. It is synthesized from indium oxide and tin oxide at a ratio of 9:1, and is usually deposited on hard (glass) or soft ( plastic) substrates. Although the ITO film produced according to the existing process has high conductivity and transparency, which can basically meet the technical index requirements of some electronic products, there are still many problems that are difficult to overcome: (1) ITO is highly brittle and easy to wear or appear when it is bent. (2) After ITO film formation, high temperature treatment is required to achieve high conductivity; (3) Indium in ITO is a rare earth element with limited reserves. The above technical defects plus the market's demand for lig...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B13/00
Inventor 黄德萍姜浩朱鹏史浩飞崔华亭钟达
Owner CHONGQING GRAPHENE TECH
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