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Electromagnetic-wave absorbing material with interstitial modulation characteristics and production method of electromagnetic-wave absorbing material

A technology for absorbing materials and electromagnetic waves, applied in the field of electromagnetic wave materials, can solve the problems of small bandwidth range, low absorption rate, and difficulty in achieving effective absorption strength, etc., and achieve the effect of wide operating frequency band, strong absorption capacity, and meeting the needs of electromagnetic wave absorption.

Inactive Publication Date: 2014-09-10
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the existing technology still has the disadvantages of the following aspects: 1. The absorption rate is not high, especially in the frequency bands above 5 and 6 GHz, it is difficult to achieve effective absorption strength; 2. The working frequency range is narrow, especially to achieve effective absorption. The bandwidth range of the absorption rate (<-20dB) is smaller; 3. The matching thickness is too large. Usually, in order to achieve the absorption strength that meets the basic work needs, the matching thickness needs to be more than 3mm, and even up to 6-7mm
This situation makes the existing absorbing materials almost impossible to apply in some special fields, especially in the military.

Method used

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  • Electromagnetic-wave absorbing material with interstitial modulation characteristics and production method of electromagnetic-wave absorbing material
  • Electromagnetic-wave absorbing material with interstitial modulation characteristics and production method of electromagnetic-wave absorbing material
  • Electromagnetic-wave absorbing material with interstitial modulation characteristics and production method of electromagnetic-wave absorbing material

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Experimental program
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Effect test

Embodiment 1

[0024] Weigh 250g of rare earth Nd and 750g of iron to prepare a master alloy with complete planar anisotropy, which is rapidly solidified into alloy thin strips (1-2cm wide, 0.2-0.4mm thick) by melting, heat-treated at 1000°C for 2 days, and broken into granules Coarse powder with a diameter of 50-100 microns, in N 2 Nitriding at 480°C for 5 hours in an atmosphere, and determining the nitrogen content by weighing method, to obtain Nd 2 Fe 17 N 3.3 . After nitriding, the powder was ball milled for 12 hours in a solution of gasoline and grinding aid (oleic acid 3% Vol). Drain the liquid after the ball mill is discharged, dry the magnetic powder, mix the magnetic powder and paraffin wax evenly at a mass ratio of 4:1, bond and press mold it into a cylindrical ring with an inner diameter of 3.04 mm and an outer diameter of 7.00 mm. Electromagnetic properties were measured on an Agilent vector network analyzer. According to the measured electromagnetic parameters, the absorpti...

Embodiment 2

[0026] Weigh 220g of rare earth Nd, 30g of rare earth Sm and 750g of iron to prepare a master alloy with partial cone anisotropy, which is rapidly solidified into an alloy ingot by smelting, heat-treated at 1100°C for 5 days, and broken into coarse particles with a particle size of 50-100 microns. Powder, in NH 3 Nitriding at 460°C for 8 hours in an atmosphere, and determining the nitrogen content by weighing method to obtain Nd 1.75 SM 0.25 Fe 17 N 3.5 . After nitriding, the powder was ball milled for 15 hours in a solution of gasoline and grinding aid (oleic acid 3% Vol). Drain the liquid after the ball mill is discharged, dry the magnetic powder, mix the magnetic powder and paraffin wax evenly at a mass ratio of 4:1, bond and press mold it into a cylindrical ring with an inner diameter of 3.04 mm and an outer diameter of 7.00 mm. Electromagnetic properties were measured on an Agilent vector network analyzer. According to the measured electromagnetic parameters, the ab...

Embodiment 3

[0028] Weigh 190g of rare earth Nd, 50g of rare earth Sm, and 750g of iron to prepare a master alloy with partial cone anisotropy, which is rapidly solidified into an alloy ingot by smelting, heat-treated at 1050°C for 7 days, and broken into particles with a particle size of 50-100 microns Meal, in CH 4 Carburize at 460°C for 8 hours in an atmosphere, and determine the carbon content by weighing method to obtain Nd 1.65 SM 0.35 Fe 17 C 2.5 . After carbonization, the powder was ball-milled for 15 hours in a solution of gasoline and grinding aid (oleic acid 3% Vol). Drain the liquid after the ball mill is discharged, dry the magnetic powder, mix the magnetic powder and paraffin wax evenly at a mass ratio of 4:1, bond and press mold it into a cylindrical ring with an inner diameter of 3.04 mm and an outer diameter of 7.00 mm. Electromagnetic properties were measured on an Agilent vector network analyzer. According to the measured electromagnetic parameters, the absorption ...

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Abstract

The invention discloses an electromagnetic-wave absorbing material with the interstitial modulation characteristics and a production method of the electromagnetic-wave absorbing material. The general formula of the electromagnetic-wave absorbing material is R<2>Fe<17>N<x>C<y>, wherein the R refers to combination of any one or multiple rare earth elements of Y, Ce, Nd, Pr, Sm, Gd, Tb, Dy, Ho, Er, Tm and Lu, the x and the y respectively refer to nitrogen and carbon content entering the lattice gap position, 0< / =<x>+<y>< / =9, and the x and the y are not equal to 0 at the same time; the electromagnetic-wave absorbing material is an R<2>Fe<17>-type master alloy billet formed by mixing and melting the rare earth element R and an iron element and is obtained by subjecting the master alloy billet coarse crushing prior to being introduced into clearance carbon atoms and / or nitrogen atoms to have magnetism of a master alloy crystal modulated. The electromagnetic-wave absorbing material has high absorbing capability on high-frequency electromagnetic waves ranging from 1GHz to 100GHz in smaller matching thickness, and the characteristics of accurate operation frequency modulation can be realized by the production method and according to different use conditions.

Description

technical field [0001] The present invention relates to an electromagnetic wave absorbing material, in particular to an electromagnetic wave material specially suitable for working in a high-frequency and wide-band environment higher than 1G Hz after the material properties are precisely modulated by using interstitial atoms (C, N, etc.). Background technique [0002] With the continuous expansion and improvement of the application fields and frequency bands of electromagnetic waves in modern society, it has become increasingly important for researchers to develop new and efficient electromagnetic wave absorbing materials (referred to as wave absorbing materials) for the purpose of radiation protection and energy absorption of electromagnetic waves. pressing challenge. From electromagnetic pollution control and electromagnetic radiation protection for civilian use; to military applications, stealth technology for radar signals; and in the field of scientific research, electr...

Claims

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Application Information

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IPC IPC(8): H05K9/00C22C1/03C22C1/10
Inventor 刘顺荃王常生杨金波韩景智杜红林杨应昌
Owner PEKING UNIV
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