Method for measuring niobium content in iron steel through beryllium hydroxide separating sulfochlorophenol S spectrophotometric method

A technology of chlorosulfonol and beryllium hydroxide, which is applied in the direction of color/spectral characteristic measurement, analysis through chemical reaction of materials, material analysis through observation of the influence on chemical indicators, etc., which can solve the problem of long separation steps, Complicated operation, poor masking effect and poor stability of the method to achieve high stability, fast detection speed and high accuracy

Active Publication Date: 2014-10-15
PANGANG GROUP JIANGYOU CHANGCHENG SPECIAL STEEL
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Problems solved by technology

The separation steps of the gravimetric method are long, generally needing 10h to 12h; the operation of the ion exchange separation method is complicated; the method of EDTA-ascorbic acid reduction masking molybdenum has poor masking effect and method stability

Method used

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  • Method for measuring niobium content in iron steel through beryllium hydroxide separating sulfochlorophenol S spectrophotometric method
  • Method for measuring niobium content in iron steel through beryllium hydroxide separating sulfochlorophenol S spectrophotometric method
  • Method for measuring niobium content in iron steel through beryllium hydroxide separating sulfochlorophenol S spectrophotometric method

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Embodiment Construction

[0018] The present invention aims at the problems of long measurement time, poor measurement stability, poor measurement accuracy and narrow measurement range existing in the method for determining the content of niobium in iron and steel in the prior art, and provides a method that can measure the content of niobium in the range of 0.005wt% to 10wt A method for the determination of niobium content in iron and steel by separation of beryllium hydroxide in the range of chlorosulfonol S spectrophotometry. The method has high determination stability, fast determination speed and high determination accuracy and precision.

[0019] The present invention dissolves the sample with acid, uses perchloric acid to fume to remove the residual acid of the dissolved sample in the solution and oxidizes chromium to positive hexavalent, and uses ethylenediaminetetraacetic acid disodium diamine solution and / or ethylenediamine Tetraammonium tetraacetate solution to mask iron, nickel, copper, cob...

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Abstract

The invention discloses a method for measuring niobium content in iron steel through a beryllium hydroxide separating sulfochlorophenol S spectrophotometric method. The method comprises the following steps: (1) weighing a sample, and dissolving into a first container with acid; (2) adding perchloric acid; (3) adding an ethylenediamine tetraacetic acid tetramine solution and/or an ethylenediamine tetraacetic acid disodium diamine solution; (4), adding ammonia water, a beryllium sulfate solution and oxalic acid; (5) filtering; (6) dissolving precipitation into a second container through acid; (7) after the precipitation is dissolved, adding tartaric acid so as to obtain a to-be-measured solution; (8) moving quantitative to-be-measured solution into a second container, and adding a sulfochlorophenol S solution, an ethylenediamine tetraacetic acid disodium diamine solution and hydrochloric acid so as to obtain a color developing liquid; (9) adding the color developing liquid into an absorption vessel, preparing a reference liquid, adding the reference liquid into the absorption vessel, and measuring the absorbency of the color developing liquid by comparison with the reference liquid at the position with the wavelength of 652 or 654; (10) calculating the niobium content in the sample according to a niobium working curve. According to the method, the measuring precision of the niobium content in the measured iron steel can be obviously improved.

Description

technical field [0001] The invention relates to a photometric method for determining niobium content in iron and steel by separating chlorosulfonol S from beryllium hydroxide. Background technique [0002] The methods for determining the content of niobium in iron and steel in the prior art mainly include the gravimetric method and the chlorosulfonol S photometric method, wherein the gravimetric method mainly includes the paper chromatography gravimetric method and the tannic acid decomposition gravimetric method, and the chlorosulfonol S Photometric methods mainly include ion exchange separation method and EDTA-ascorbic acid reduction method for masking molybdenum. The separation steps of the gravimetric method are long, generally needing 10h to 12h; the operation of the ion exchange separation method is complicated; the method of EDTA-ascorbic acid reduction masking molybdenum has poor masking effect and method stability. Contents of the invention [0003] The object of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31G01N21/78
Inventor 杨道兴
Owner PANGANG GROUP JIANGYOU CHANGCHENG SPECIAL STEEL
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