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An alkali-free chloride-free liquid accelerator

An accelerator and liquid technology, applied in the field of alkali-free and chlorine-free liquid accelerators, can solve the problems of internal structure damage of concrete, cracks or cracks on the surface of concrete, reduction of durability and service life of concrete, etc. The effect of changing, preventing corrosion of steel bars, and not losing strength

Inactive Publication Date: 2014-10-22
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, most of the accelerators used in shotcrete produced in China are accelerators with high alkali content. The biggest disadvantages of this accelerator are: first, the durability and service life of concrete are reduced due to the incorporation of a large amount of alkali; The introduction of a large amount of alkali leads to a decrease in the 28d strength of the concrete in the later stage, and practice has proved that the decrease can reach 25-51%
In addition, because strong alkali is highly corrosive and has a pungent smell, it will seriously affect the personal health of construction workers and cause pollution to the environment
The second is that these quick-setting agents contain a large amount of Cl. The introduction of chloride ions has serious corrosion to the steel bars. Cavitation and erosion will destroy the internal structure of the concrete, resulting in cracks or cracks on the concrete surface, which will affect the durability and quality of the concrete. service life

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A non-alkali and chlorine-free liquid quick-setting agent, which is prepared from the following raw materials in parts by weight:

[0035] Polyaluminum sulfate: 35%, magnesium oxide: 5%, citrate salt: 15% of polyaluminum sulfate, phosphoric acid: 1%, salicylic acid: 1%, defoamer: 1%, succinic acid: 1% , Cadmium sulfate: 1%, the balance is water, and the total weight is supplemented by 100%.

Embodiment 2

[0037] A non-alkali and chlorine-free liquid quick-setting agent, which is prepared from the following raw materials in parts by weight:

[0038] Polyaluminum sulfate: 55%, magnesium oxide: 25%, citrate salt: 30% of polyaluminum sulfate, phosphoric acid: 5%, EDTA: 5%, defoamer: 5%, β-ketoglutaric acid: 2%, mercury sulfate: 3%, the balance is water, and the total weight makes up 100%.

Embodiment 3

[0040] A non-alkali and chlorine-free liquid quick-setting agent, which is prepared from the following raw materials in parts by weight:

[0041] Polyaluminum sulfate: 45%, magnesium oxide: 15%, citrate salt: 22.5% of polyaluminum sulfate, hydrofluoric acid: 3%, sulfosalicylic acid: 3%, defoamer: 5%, β - Ketoglutaric acid: 2%, cadmium sulfate: 3%, the balance is water, and the total weight makes up 100%

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Abstract

An alkali-free chloride-free liquid accelerator is disclosed. The liquid accelerator is prepared from following raw materials by weight: 35-55% of polyaluminium sulfate, 5-25% of magnesium oxide, a citrate type salt accounting for 15-30% by weight of the polyaluminium sulfate, 1-5% of an inorganic acid, 1-5% of a stabilizing agent, 1-5% of a defoaming agent and 1-5% of an antichlor, with the balance being water and the total weight percentage being 100%. The alkali content of the liquid accelerator is less than 1%, and the chlorine ion content is less than 1.1%, so that the liquid accelerator belongs to alkali-free chloride-free liquid accelerators. By using the liquid accelerator into concrete, the possibility of alkali-aggregate reactions is largely reduced, steel bar corrosion is prevented, and the durability of concrete is enhanced. The 2.28-d compressive strength ratio is higher than 111%. By using the liquid accelerator into the concrete, the early-stage strength is high, the later-stage strength does not loss lose and is increased, and the stable period is longer than 6 months.

Description

technical field [0001] The invention relates to an alkali-free and chlorine-free liquid accelerator. Background technique [0002] At present, most of the accelerators used in shotcrete produced in China are accelerators with high alkali content. The biggest disadvantages of this accelerator are: first, the durability and service life of concrete are reduced due to the incorporation of a large amount of alkali; The introduction of a large amount of alkali leads to the decrease of the 28d strength of the concrete in the later stage, and practice has proved that the decrease can reach 25-51%. Due to the existence of a large amount of alkaline substances, it will react with the active components in the aggregate inside the concrete, which will cause the alkali-aggregate reaction of the concrete. In addition, because strong alkali is highly corrosive and has a pungent smell, it will seriously affect the personal health of construction workers and cause pollution to the environm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/04C04B24/12
Inventor 刘开平熊锐田耀刚孙增智何锐从培良王振军邢明亮关博文盛艳萍
Owner CHANGAN UNIV
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