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A kind of method that uses bagasse as raw material to prepare high-performance lithium-ion battery negative electrode material

A technology for lithium ion batteries and negative electrode materials, which is applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of unused bagasse, low actual utilization rate, backward technology, etc., and achieves low cost, excellent rate cycle performance, Simple preparation process

Active Publication Date: 2016-08-17
深圳市依卓尔能源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the backward application and development technology, bagasse is often discarded traditionally, and the actual utilization rate is very low, which not only causes waste of resources, but also brings environmental pollution

Method used

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  • A kind of method that uses bagasse as raw material to prepare high-performance lithium-ion battery negative electrode material
  • A kind of method that uses bagasse as raw material to prepare high-performance lithium-ion battery negative electrode material
  • A kind of method that uses bagasse as raw material to prepare high-performance lithium-ion battery negative electrode material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of method using bagasse as raw material to prepare lithium ion battery negative electrode material, its steps are as follows:

[0026] Put bagasse, a by-product of fruit cane eaten daily, into deionized water, first stir for 30 minutes, then ultrasonically vibrate for 1 hour, and after suction filtration, put the bagasse in an oven at 60°C to dry it. Put the dried bagasse into the reaction furnace of the fixed-bed reactor, raise the temperature from room temperature to 800°C under a nitrogen atmosphere (the heating rate is 5°C / min), and keep it at 800°C for 2 hours, and then cool it with the furnace Get the first product. The initial product was ball milled in a ball mill for 2 hours (ball milling speed 250r / min), and after passing through a 200 mesh sieve, the lithium ion battery negative electrode material was obtained (see figure 2 ).

Embodiment 2

[0028] A kind of method using bagasse as raw material to prepare lithium ion battery negative electrode material, its steps are as follows:

[0029] Put the bagasse left after the sugar cane from the sugar factory is squeezed into deionized water, first stir for 30 minutes, then ultrasonically vibrate for 1 hour, and after suction filtration, put the bagasse in an oven at 80°C to dry it. Put the dried bagasse into the reaction furnace of the fixed-bed reactor, raise the temperature from room temperature to 900°C in an argon atmosphere (the heating rate is 5°C / min), and keep it at 900°C for 2 hours, then cool with the furnace After getting the first product. The initial product was ball milled in a ball mill for 2 hours (ball milling speed 250r / min), and after passing through a 200 mesh sieve, the lithium ion battery negative electrode material was obtained (see image 3 ).

Embodiment 3

[0031] A kind of method using bagasse as raw material to prepare lithium ion battery negative electrode material, its steps are as follows:

[0032] Put bagasse, a by-product of fruit cane eaten daily, into deionized water, first stir for 30 minutes, then ultrasonically vibrate for 1 hour, and after suction filtration, put the bagasse in an oven at 100°C to dry it. Put the dried bagasse into the reaction furnace of the fixed-bed reactor, raise the temperature from room temperature to 1000°C under a nitrogen atmosphere (the heating rate is 5°C / min), and keep it at 1000°C for 2 hours. After cooling with the furnace, Get the first product. The initial product was ball milled in a ball mill for 2 hours (ball milling speed 250r / min), and after passing through a 200 mesh sieve, the lithium ion battery negative electrode material was obtained (see Figure 4 ).

[0033] The negative electrode materials of lithium ion batteries obtained in Examples 1 to 3 were made into half cells fo...

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Abstract

The invention relates to the technical field of preparation of electrode materials of a lithium ion battery and particularly discloses a method for preparing a high-performance lithium ion battery anode material with bagasse as a raw material. The method includes following steps: washing the bagasse in deionized water, performing suction filtration and a drying process; performing calcination in an inert atmosphere; and carrying out a ball milling and sieving process to obtain the high-performance lithium ion battery anode material. The method is abundant in raw material source and is simple in processes. The prepared anode material is high in a reversible capacity and is excellent in a high-rate-circulation performance.

Description

technical field [0001] The invention relates to the technical field of preparation of lithium-ion battery electrode materials, in particular to a method for preparing a high-performance lithium-ion battery negative electrode material using bagasse as a raw material. Background technique [0002] As a new type of high-energy battery, lithium-ion battery has been widely used in people's daily life. As the main component of the lithium battery, the negative electrode material directly affects the performance of the lithium battery. At present, graphite is the most widely used carbon-based lithium battery negative electrode material, and its highest theoretical specific capacity is only 372mAh g -1 , the actual specific capacity is lower, and the cycle stability is difficult to effectively improve. Although our country is rich in graphite, if it is not protected, it will be exhausted sooner or later. Finding suitable new carbon-based materials to replace the current commercia...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36
CPCH01M4/5835H01M10/0525Y02E60/10
Inventor 杜军王锋丁瑜程雪娟覃彩芹
Owner 深圳市依卓尔能源有限公司